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化学进展 2000, Vol. 12 Issue (03): 282- 前一篇   后一篇

• 综述与评论 •

烯烃不对称催化环丙烷化反应进展评述

姚小泉;陈惠麟;郑卓*   

  1. 中国科学院大连化学物理研究所 大连 116023

  • 收稿日期:1999-07-01 修回日期:1999-11-01 出版日期:2000-08-24 发布日期:2000-08-24
  • 通讯作者: 郑卓
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导出 被引次数 ( 20 | 4 )

Review of Asymmetric Cyclopropanat ion of Olefins

Yao Xiaoquan;Chen Huilin;Zheng Zhuo*   

  1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
  • Received:1999-07-01 Revised:1999-11-01 Online:2000-08-24 Published:2000-08-24
  • Contact: Zheng Zhuo
本文从手性配体的发展出发, 综述了烯烃不对称环丙烷化反应近10 年来的研究进展, 对半咕啉、双　唑啉等C2 轴手性配体在该反应中的应用做了详细论述, 介绍了反应机理研究的最新进展, 并探讨了该反应在走向工业应用过程中所面临的主要问题。
关键词： 烯烃, 不对称环丙烷化, C2轴手性配体
In this article, the progress on asymmetric cyclopropanation of olefins during the last decade was reviewed. The application of chiral C2-symmetrical ligands in the reaction, such as bis2oxazoline and semicorrin, were discussed in detail. The new development of research on mechanism was in troduced. Some major difficulties in the industrial application of the reaction were summarized.
Key words: olefin, asymmetric cyclop ropanation, C2-symmetrical ligands

中图分类号: 

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