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化学进展 1999, Vol. 11 Issue (04): 376- 前一篇   后一篇

• 综述与评论 •

氨合成催化剂及其催化反应机理研究进展

廖代伟;王丽华;陈守正;蔡启瑞   

  1. 福建师范大学化学系;厦门大学物理化学所
  • 收稿日期:1998-03-01 修回日期:1998-11-01 出版日期:1999-11-24 发布日期:1999-11-24
  • 通讯作者: 廖代伟

Advances in the Catalysts and Mechanism for Ammonia Synthesis

Wang Lihua;Chen Shouzheng;Liao Daiwei;Cai Qirui   

  1. Department of Chemistry, Fu jian Normal University, Fuzhou 350007, China Institute of Physical Chemistry, Department of Chemistry and The State Key Laboratory of Physical Chemistry on Surfaces, Xiamen University, Xiamen 361005, China"
  • Received:1998-03-01 Revised:1998-11-01 Online:1999-11-24 Published:1999-11-24
  • Contact: Liao Daiwei

本文综述了氨合成这一最重要的工业多相催化过程80 多年来的研究进展。介绍了氨合成熔铁催化剂、氨合成钌催化剂的发展以及对氨合成催化反应机理的不同看法。

The advances in ammonia synthesis as is one of the most important industrial heterogeneous catalytic processes are reviewed. The developments of both fused iron catalysts and ruthenium catalysts and the different opinions on catalytic mechanism for ammonia synthesis are discussed.

中图分类号: 

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[1 ] 南京化工研究院译, 合成氨催化剂手册(Hand book of Catalysts for Ammonia Synthesis) , 石油化学工业出版社, 北京, 1977, 136- 155.
[2 ] Tamaru K, J. Phys. Chem. , 1968, 75, 1739.
[3 ] Ozaki A , B ull. Chem. Soc. Jpn. , 1971, 44, 3216.
[4 ] 林伟忠(Lin W Z) , 刘化章(Liu H Z) , 现代化工(Modern Chem. Ind. ) , 1994, 14 (7) , 12- 17.
[5 ] 石天宝(Shi T B) , 化工进展(Prog. Chem. Eng. ) , 1993, 6, 46- 51.
[6 ] 刘化章(Liu H Z) , 胡樟能(Hu Z N ) , 李小年(Li X N ) 等, 化工学报(J. Chem. Eng. ) , 1994,45 (4) , 385- 392.
[7 ] 刘化章(Liu H Z) , 胡樟能(Hu Z N ) , 李小年(Li X N ) 等, 工业催化( Ind. Catal. ) , 1994, 2(2) , 19- 26.
[8 ] 刘化章(Liu H Z) , 胡樟能(Hu Z N ) , 李小年(Li X N ) 等, 浙江工学院学报(J. Zhejiang Univ.Technol. ) , 1994, 1, 27- 35.
[9 ] 胡樟能(Hu Z N ) , 刘化章(Liu H Z) , 蒋祖荣(Giang Z R) 等, 浙江化工(Zhejiang Chem. Ind. ) ,1994, 25 (2) , 32- 37.
[10 ] 刘化章(Liu H Z) , 1986, CN 86 108 528.
[11 ] 刘化章(Liu H Z) , 胡樟能(Hu Z N ) , 李小年(Li X N ) 等, 浙江工学院学报(J. Zhejiang Univ.Technol. ) , 1993, 2, 15- 23.
[12 ] 刘化章(Liu H Z) , 李小年(Li X N ) , 中国科学(B 辑) (Sci. China B ) , 1995, 25 (1) , 1- 6.
[13 ] Streltsov O A , Fedun O S, Artyukh Yu N et al. , Tezisy Dokl-Ukr Resp Konf Fiz Khim , 1977, 12,159- 160.
[14 ] Kalenczuk R J. , Catal. Lett. , 1995, 33 (3- 4) , 331- 338.
[15 ] Kalenczuk R J , J. Chem. Tech. Biot. , 1995, 64 (4) , 398- 406.
[16 ] Kalenczuk R J , Appl. Catal. A-Gener. , 1994, 112 (2) , 149- 160.
[17 ] Wang W X, Zhao H Q , Du B S et al. , Appl. Catal. A-Gener, 1995, 122 (1) , 5- 20.
[18 ] Kalenczwk R J , J. Chem. Tech. Biot. , 1994, 59 (1) , 73- 81.
[19 ] Ageeva I V , Kryliva A V , J. Appl. Chem. US S R , 1992, 65 (9) , 1758- 1760.
[20 ] Yastimirskii V K, Ischenko E V , React. Kinet. Catal. Lett. , 1992, 48 (2) , 385- 389.
[21 ] Kalenczuk R J , J. Chem. Tech. Biot. , 1992, 54 (4) , 349- 357.
[22 ] 仰华胃(Yang H W ) , 化肥工业(Fertilizer Ind. ) , 1995, 22 (4) , 26.
[23 ] 王文祥(Wang W X) , 刘照穹(Liu Z Q ) , 张元珍(Zhang Y Z) 等, 化学通报(Chemistry Bull. ) ,1996, 9, 51- 53.
[24 ] 李基涛(Li J T ) , 蔡丽芬(Cai L F) , 化肥与催化(Fertilizerand Catal. ) , 1991, 2, 30.
[25 ] 赵合全(Zhao H Q ) , 王文祥(Wang W X) , 化肥与催化(Fertilizerand Ctal. ) , 1989, 2, 11.
[26 ] 魏可镁(Wei K M ) , 俞秀金(Yu X J ) , 王榕(Wang R ) 等, 工业催化( Ind. Catal. ) , 1995, 3(3) , 14- 20.
[27 ] 许清准(Xu Q Z) , 四川化工(Sichuan Chem. Ind. ) , 1992, 4, 35- 37.
[28 ] 邱国涛(Qiu G T ) , 化肥与催化(Fertilizerand Catal. ) , 1991, 1, 13- 15.
[29 ] 刘望生(Liu W S) , 湖南化工(Hunan Chem. Ind. ) , 1990, 2, 41- 42.
[30 ] Uchida H, Ishikawa K, Suzuki T , Inoue T , Uchida H H, J. Alloys. Comp. , 1995, 222, 153- 159.
[31 ] Wang X K, Shan N F, Han S H, Gu H G, Acta Chim. Sin. , 1994, 52 (6) , 613- 619.
[32 ] Homann K, Kuchlenbeck H, Freund H J , Z. Phys. Chem. : Inter. J. Res. Phys. Chem. & Chem.Phys. , 1997, 198 (1- 2) , 135- 147.
[33 ] Kowalczyk Z, Sentek J , Jodizis S et al. , J. Catal. , 1997, 169 (2) , 407- 414.
[34 ] Kowalczyk Z, Catal. Lett. , 1996, 37 (3- 4) , 173- 179.
[35 ] Pattek janczyk A , Miczko B, Morawski A W , Appl. Catal. A-Gener. , 1996, 141 (1- 2) , 1- 16.
[36 ] Vacini C A , Synthesis of Ammonia, Macmillan, London, 1971, Chap. 5.
[37 ] 余祖熙等编著(eds. Yu Z X et al. ) , 化肥催化剂使用技术(Tech.of Fertilizer Catalyst) , 化学工业出版社(Chemical Industry Press) , 北京(Beijing) , 1988.
[38 ] Waugh K C, Butler D, Hayden B E, Catal. Lett. , 1994, 24 (1- 2) , 197- 210.
[39 ] Fastrup B, Nielson H N , Catal. Lett. , 1992, 14 (2) , 233- 239.
[40 ] Arabczyk W , Narkiewicz U , Moszynski D, Appl. Catal. A-Gener. , 1996, 134 (2) , 661- 668.
[41 ] Murata S, Aika K, Appl. Catal. A-Gener. , 1992, 82 (1) , 1- 12.
[42 ] Aika A , Hori H, Ozaki A , J. Catal. , 1972, 27, 424.
[43 ] Chao K J , Lin L H, Yang M H, Catal. Lett. , 1996, 38, 279- 282.
[44 ] 林治田(Lin Z T ) , 化肥工业译丛(Translated Series of Chem. Ind. ) , 1991, 1, 110.
[45 ] Izumi Y, Hoshikawa M , Aika K, B ull. Chem. Soc. Jpn. , 1994, 67 (12) , 3191- 3200.
[46 ] Kubota J , Aika K, J. Phys. Chem. , 1994, 98 (44) , 11293- 11300.
[47 ] Kadowvaki Y, Aika K, J. Catal, 1996, 161 (1) , 178- 185.
[48 ] Kowalczyk Z, Sectek J , Jodzis S et al. , Carbon, 1996, 34 (3) , 403- 409.
[49 ] Zheng Z H, Aika K, Chem. Comm u. , 1997, 13, 1223- 1224.
[50 ] Kowalczyk Z, Sentek J , Jodzis S, Mizera E et al. , Catal. Lett. , 1997, 45 (1- 2) , 65- 72.
[51 ] Masthan S K, Prasad P S S, Rao K S R, Rao K, Indian. J. Chem. Sect. A-Inorg. Phys. Theo. & Anal. Chem. , 1995, 34 (2) , 146- 147.
[52 ] Masthan S K, Rao K S R, Rao P K, Indian. J. Chem. Sect. A-Inorg. Bio-Inorg , Phys. Theo & Anal. Chem. , 1993, 32 (5) , 383- 386.
[53 ] Fishel C T , Davia R J , Gares J M , J. Catal. , 1996, 163 (1) , 148- 157.
[54 ] Fishel C T , Davia R J , Gares J M , Chem. Commu. , 1996, 5, 649- 650.
[55 ] GucziL , Sundararajan R, Koppany Z, Zsoldos Z, Schay Z, Mizukani. F, Niwa S, J. Catal, 1997. ,167 (2) , 482- 494.
[56 ] Niwa Y, Aika K, J. Catal. , 1996, 162 (1) , 138- 142.
[57 ] Niwa Y, Aika K, Chem. Lett. , 1996, 1, 3- 4.
[58 ] Masthan S K, Indian. J. Chem. Sect. A-Inorg. Bio-Inorg. Phys. Theo. &Anal. Chem. , 1996, 35(1) , 31- 36.
[59 ] Izumi Y, Iwata Y, Aika K, J. Phys. Chem. , 1996, 100 (22) , 9421- 9428.
[60 ] Izumi Y, Aika K, J. Phys. Chem. , 1995, 99 (25) , 10346- 10353.
[61 ] Izumi Y, Aika K, Chem. Lett. , 1995, 2, 137- 138.
[62 ] Masthan S K, Rao K S R, Kaluschnyaya L , Yunusov S M , Shur V B, Volpin M E, Indian . J.Chem. Sect. A -Inorg. Bio. -Inorg. Phys. Theo. &Anal. Chem. , 1994, 33 (9) , 816- 819.
[63 ] Boudart M , Catal. Rev. Sci. Eng. , 1981, 23, 1.
[64 ] Fastrup B, J. Catal. , 1997, 168 (2) , 235- 244.
[65 ] Katz G, Kosloff R, J. Chem. Phys. , 1995, 103 (21) , 9475- 9481.
[66 ] Kuchaev V L , Shaptina E N , A vetisov A K, Kinet. Catal. , 1995, 36 (5) , 668- 672.
[67 ] Mckee C S, Appl. Catal. A-Gener. , 1995, 127 (1- 2) , N 4- N 5.
[68 ] Tsai K R, Paper Presentedat the Post Congress Symposiumon Nitrogen Fixation after the 7th ICC,Tokyo, 1980.
[69 ] 朱龙根(Zhu L G) , 戴安邦(Dai A B) , 固氮通讯(Commu. Nitrogen Fixation) , 1981, 1, 12.
[70 ] 黄开辉(Huang K H) , 厦门大学学报(自然科学版) (J. Xiamen Univ. ) , 1978, 3, 130.
[71 ] Huang K H,in New Horizonsin Catalysis (eds. Seiyama T , Tanabe K) , Kodansha-Elsevier, Tokyo Amsterdam , 1981.
[72 ] Wei T C, Phillips J , Adv. Catal. , 1996, 41, 359- 421.
[73 ] 廖代伟(Liao D W ) , 王仲权(Wang Z Q ) , 张鸿斌(Zhang H B) , 蔡启瑞(CaiQ R) , Scientia Sinica(Science in China B ) , 1987, 30 (3) , 246- 255.
[74 ] 廖代伟(Liao D W ) , 林种玉(Lin Z Y) , 蔡启瑞(CaiQ R) , 厦门大学学报(自然科学版) (J. Xiamen Univ. ) , 1996, 35 (5) , 734- 738.
[75 ] Chen H B, Liao Y Y, Zhang H B, Tsai K R, Chin. Chem. Lett. , 1993, 4 (5) , 457.
[76 ] Zhang H B, Schrader G L , J. Catal. , 1986, 99, 461- 471.
[77 ] Liao D W , J. Mol. Struc. , 1985, 121, 101- 107.
[78 ] 黑美军(Hei M J ) , 陈鸿博(Chen H B) , 林贻基(Lin Y J ) 等, 厦门大学学报(自然科学版) (J.Xiamen Univ. ) , 1997, 6, 879- 885.

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