English
往期目录
新闻公告
More
化学进展 1999, Vol. 11 Issue (01): 30- 前一篇   后一篇

• 综述与评论 •

混合导体透氧膜及其在甲烷部分氧化制合成气反应中的应用

邵宗平;熊国兴*   

  1. 中国科学院大连化学物理研究所 大连 116023
  • 收稿日期:1998-03-01 修回日期:1998-09-01 出版日期:1999-02-24 发布日期:1999-02-24
  • 通讯作者: 熊国兴
下载PDF ( 1935 ) 引用
导出 被引次数 ( 41 | 9 )

Mixed Conducting Oxygen Permeative Membranes and Their Applications in Partial Oxidation of Methane to Syngas Process

Shao Zongping;Xiong Guoxing*   

  1. State Key Lab of Catalysis, Dalian Institute of Chemical Physics Chinese Academy of Sciences, Dalian 116023, China
  • Received:1998-03-01 Revised:1998-09-01 Online:1999-02-24 Published:1999-02-24
  • Contact: Xiong Guoxing

本文介绍了混合导体透氧膜材料的种类及最新研究进展, 对透氧机理进行了阐述, 对氧透量的理论公式进行了推导, 并对其在甲烷部分氧化制合成气(POM ) 膜反应过程中的应用、材料的要求及膜反应器的构造进行了概述与讨论。

关键词： 混合导体, 透氧膜, 机理和公式, POM膜反应器

The types and recent development of mixed conducting oxygen permeative membranes are introduced. The mechanism of oxygen permeation is given and the oxygen theoritical permeation equation is derivated. Their applications in POM and the requiremnet of materials are reviewed and the structure of reactors are proposed.

Key words: mixed conductor, oxygen permeation, membrane, mechanism and formulas, POM reactor

中图分类号: 

()

[1 ] Steele B C H, Solid State Ionics, 1996, 86- 88, 1223—1234.
[2 ] Yamanura Y, Ninomiya Y, Sekido S,in Proceedingsofthe International Meetingon Chemical Sensors (ed. Seiyama T ) , Kodansha/Elsevierand Tokyo/Amsterdam , 1983, 187.
[3 ] ten Elshof J E , Van HasselB A , Bouwmeester H J M , Catalysis Today , 1997, 25, 397—402.
[4 ] ten Elshof J E, Bouwmeester H J M , Verweij H, Appl. Catal A : Gen. , 1995, 130, 195—212.
[5 ] Lin Y S, Zeng Y, J. Catal. , 1996, 164, 220—231.
[6 ] Balachandran U , Mieville R L , Ma B, Udovich C ,in Abstracts of Papers Presentedat the Fourth International Conferenceon InorganicMembrane, 1996, Gatlinburg, Tennessee U SA.
[7 ] Tsai C Y, Ma Y H, Moser W R, Dixon A G,in Abstracts of Papers Presentedat the Fourth International Conferenceon InorganicMembrane, 1996, Gatlinburg, Tennessee U SA.
[8 ] Balachandran U , Dusek J T , Mieville R L , Poeppel R B et al. , Appl. Catal A : Gen. , 1995, 133, 19—29.
[9 ] Bernard Cales, Jean Francois Baumard, High Temp-High Pressures, 1982, 14, 681—686.
[10 ] Itoh N , Sanchez C, Marco A , Xu W C et al. , J. Membr. Sci. , 1993, 77, 245—253.
[11 ] Nigara Y, Watanabe K, Kawamura K et al. , J. Electrochem. Soc. , 1997, 144 (3) , 1050—1055.
[12 ] Keller G E, Bhasin M M , J. Catal. , 1982, 73, 9.
[13 ] Hutchings G J , Scurrel M S, Woodhowe J R, Chem. Soc. Rev. , 1989, 18, 251.
[14 ] Gesser H D, Hunter N R, Drakash C B, Chem. Rev. , 1985, 85, 235.
[15 ] Spencer N D, Pereiva C J , J. Catal. , 1989, 116, 399.
[16 ] Henrici-Olive G, Olive S, Angew. Chem. Int. Engl. , 1976, 15, 136.
[17 ] Mazanec Terry J , VelenyiLouis J , US 5 160 713, 1992.
[18 ] Thorogood R M , Srinivasan R, Yee T F, Drake M P, US 5 240 480, 1993.
[19 ] Liu Meilin, Joshi Ashokv, Shen Yousheng, Krist Kevin, Virkar Anil V , US 5 478 444, 1995.
[20 ] Balachandran U , Kleefisch M , Kobylinski T P et al. , International Patent W O 94/24065, 1994.
[21 ] 李思温(Li S W ) , 杨维慎(Yang W S) , 林励吾(Lin L W ) , Chinese Science Bulletin, 1997, 42, 615—617.
[22 ] Bose Arun C, Stiegel Gary J , Malone Rodney D et al. ,in Abstracts of Papers Presentedat the Fourth International Conferenceon Inorganic Membrane, 1996, Gatlinburg, Tennessee, U SA.
[23 ] Chen C S, Boukamp B A , Bouwmeester H J , Cao G Z, Kruidh of H, Winnubst A J , Burggraaf A J ,Proceedings of 9th Conference of Solid State Ionics , Den Haag, Nertherlands, 1993.
[24 ] Costa A D S, Labrincha J A , Marques F M B, Electroceramics IV (eds. Waser R, Hoffmann S,Bonnenberg D, Hoffmann C) , Aachen, Germany; Augustinus, Buchhandlung, 1994, 12, 781—784
[25 ] Mazanec T J , Cable T L , Frye J G, Solid State Ionics, 1992, 53—56, 111.
[26 ] Chen C S, Boukamp B A , Bouwmeester H J M et al. , Solid State Ionics, 1995, 76, 23—28.
[27 ] Arashi H, Naito H, Solid State Ionics, 1992, 53—56, 431—435.
[28 ] Cales B, Baumard J F, J. Electrochem. Soc. , 1984, 131, 2407—2413.
[29 ] Nigara Y, Mizusaki J , Ishigame M , Solid State Ionics, 1995, 79, 208—211.
[30 ] Nigara Y, Kosaka Y, Kawamura K et al. , Solid State Ionics, 1996, 86—88, 739—744.
[31 ] Cao G Z, Liu X Q , Brinkman H W et al. ,in Science and Technology of Zirconia V (eds. Badual S P S, BannisterM J , Hannink R H J ) Technomic Publishing Company Inc. , Lancaster, Pa, 1993, 576.
[32 ] Han P, Worrell W L , J. Electrochem. Soc. , 1995, 142, 4235—4245.
[33 ] 刘杏芹(Liu X Q ) , 孟广辉(Meng G H ) , Cao G Z et al. , 中国科技大学学报(Journal of China University of Science and Technology ) , 1994, 24, 317—323.
[34 ] Iwahara H, Esaka T , Takada K, Advancesin Ceramics, 1988, 24, 907.
[35 ] Van Dijk M P,de Vries K J , Burggraaf A J , Solid State Ionics, 1983, 9&10, 913.
[36 ] Van Dijk M P,de Vries K J , Burggraaf A J , Solid State Ionics, 1985, 16, 211.
[37 ] Han J , Zeng Y, Lin Y S,in Abstracts of Papers Presentedat the Fourth International Conferenceon Inorganic Membrane, 1996, Gatlinburg, Tennessee, U SA.
[38 ] Bouwmeester H J M , Kruidhof H, Burggraaf A J et al. , Solid State Ionics, 1992, 53—56, 460—468.
[39 ] Iwahara H, J P 56-92103, 1981.
[40 ] Teraoka Y, Zhang H M , Furukawa S, Yamazoe N , Chem. Lett. , 1985, 1743—1746.
[41 ] Teraoka Y, Nobanaga Y, Yamazoe N , Chem. Lett. , 1988, 503—506.
[42 ] Teraoka Y, Solid State Ionics, 1991, 48, 207—212.
[43 ] Kharton V V , Noumovich E N , Nikolaev A V , J. Membr. Sci. , 1996, 111, 149—157.
[44 ] Zhang H, Li Z, Yu G, Yang N , Proceedings of the Fifth International Conferenceon Inorganic Membranes, 1998, 196—199.
[45 ] Steele B C H, Journal of Power Sources, 1994, 49, 1—14.
[46 ] Ishigaki T , Yamauchi S, Kishio K et al. , J. Solid State Chem. , 1988, 73, 179—187.
[47 ] WarrenWilliam L , Vanheusden Karel et al. , J. Am. Ceram. Soc. , 1996, 79 (2) , 536—38.
[48 ] Gui Hong, Gu B L , Zhang X W , J. Am. Ceram. Soc. , 1996, 79 (2) , 381—384.
[49 ] Tuller Harry L , J. P hys. Chem. Solid , 1994, 55 (12) , 1393—1404.
[50 ] Cherry M , Islam M S, Catlow C R A , J. Solid State Chem. , 1995, 118, 125—132.
[51 ] Van Roosmalen J A M , Cordfunke E H P, J. Solid State Chem. , 1991, 93, 212—219.
[52 ] Kweon H J , Kuk S T , Park H B et al. , J. Mat. Sci. Lett. , 1996, 15, 428—430.
[53 ] Taguchi H, Yoshioka H, Nagao M , J. Mat. Sci. Lett. , 1994, 13, 891—892.
[54 ] Zhang H M , Teraoka Y, Yamazoe N , Chem. Lett. , 1987, 665—668.
[55 ] Nakayama S, Sakamoto M , Matsuki K et al. , Chem. Lett. , 1992, 2145—2148.
[56 ] Taguchi H, Shimada M , Koizumi M , J. Solid State Chem. , 1980, 33, 169—172.
[57 ] Tai L W , Nasrallah M M , Anderson H U , J. Solid State Chem. , 1995, 118, 117—124.
[58 ] Tai L W , Nasrallah M M , Anderson H U et al. , Solid State Ionics, 1995, 76, 259—271.
[59 ] Stevenson J W , Armstrong T R, Carneim R D et al. , J. Electrochem. Chem. , 1996, 143, 2722—2729.
[60 ] Mizusaki J , Yoshihiro M , Yamauchi S, Fueki K, J. Solid State Chem. , 1987, 67, 1—8.
[61 ] Mizusaki J , Yoshihiro M , Yamauchi S, Fueki K, J. Solid State Chem. , 1987, 58, 257—266.
[62 ] Mizusaki J , Mima Y, Yamauchi S, Fueki K, J. Solid State Chem. , 1989, 80, 102—111.
[63 ] Ishigaki T , Yamauchi S, Mizusaki J , Fueki K, J. Solid State Chem. , 1984, 54, 100—107.
[64 ] Lane J A , Middleton P H, Fox H et al. , Electrochem Society Processings, 1994, 489—504.
[65 ] Fullarton I C, Kilner J A , Steele B C H et al. , Electrochem Society Proceedings, 1992.
[66 ] Bouwmeester H J M , Kruidhof H, Burggraaf A J , Solid State Ionics, 1994, 72, 185—194.
[67 ] Kruidhof H, Bouwmeester H J M , Van Doorn R H E et al. , Solid State Ionics, 1993, 63—65, 816—822.
[68 ] Chen C H, Bouwmeester H J M , Van Doorn R H E et al. , Solid State Ionics, 1997, 98, 7—13.
[69 ] WeberW J , Stevenson J W , Armstrong T R, Pederson L R, Kingstey J J , Mat. Res. Soc. Symp.Proc. , 1995, 369, 395—400.
[70 ] Van HasselBart A , Kawada T , SakaiN et al. , Solid State Ionics, 1993, 16, 295—305.
[71 ] 张华民(Zhang H M ) , Teraoka Y, Yamazoe N , 无机材料学报(J.lnorg. Mater. ) , 1993, 8, 473—478.
[72 ] Zeng Y, Lin Y S,in Abstracts of Papers Presentedat the Fourth International Conferenceon Inorganic Membrane, 1996, Gatlinburg, Tennessee, U SA.
[73 ] Yang Y L , Lee T H, Qiu L et al. , Mat. Res. Soc. Symp. Proc. , 1995, 369, 383—388.
[74 ] Qiu L , Lee T H, Liu L M , Yang Y L , Jacobson A J , Solid State Ionics, 1995, 76, 321—329.
[75 ] Miura N , O kamoto Y, Tamaki T et al. , Solid State Ionics, 1995, 79, 195—200.
[76 ] Vaddorn R H E, Kruidhof H, Bouwmeester H J M , Burggraaf A J , Mat. Res. Soc. S ymp. Proc. ,1995, 369, 377—382.
[77 ] ten Elshof J E, Bouwmeester H J M , Verweij H, Solid State Ionics, 1995, 81, 97—109.
[78 ] Itoh N , Kato T , Uchida K, Haraya K, J. Membr. Sci. , 1994, 92, 239—246.
[79 ] Patrakeev M V , Leonidov IA , Kozhevnikov V L , Solid State Ionics, 1995, 82, 5—13.
[80 ] Gur Turgut M , Huggins Robert A , J. Electrochem. Soc. , 1993, 140, 1990—2000.
[81 ] Steele B C H, Materials Scienceand Engineering , 1992, B 13, 79—87.
[82 ] Steele B C H, Current Opinionin Solid State &Materials Science, 1996, 684—691.
[83 ] Kilner J A ,in-nd Int. Symp.on Ionicsand Mixed Conducting Ceramics (eds. Ramanarayanan T A ,Warrell W L , Tuller H L ) , Electrochemical Society, New jersey, 1994, 174.
[84 ] Han J , Xomeritakis G, Lin Y S, Solid State Ionics, 1997, 93, 263—272.
[85 ] Brinkman H W , Kruidhof H, Burggraaf A J , Solid State Ionics, 1994, 68, 173—176.
[86 ] Ma B, Balachandran U , Park J H et al. , J. Electrochem. Soc. , 1996, 143, 1736—44.
[87 ] Cook R L , Sammells A F, Solid State Ionics, 1991, 45, 311—321.
[88 ] Torrance J B, Lacorro P, J. Solid State Chem. , 1991, 90, 168—172.
[89 ] Heyne L , Solid Electrolytes (ed. Gellers S) , Springer-Verlag, New York, 1977, 167.
[90 ] Lin Y S, Wang W , Han J , AIChEJ , 1994, 40, 786.
[91 ] Tsai C Y, Ma Y H, Moser W R et al. , Chem. Eng. Comm. , 1995, 134, 107—132.
[92 ] Pei S, Kleefisch M S, Kobylinski T P et al. , Catal. Lett. , 1995, 30, 201—212.
[93 ] Bose A C, Stiegel G J , Sammells, Proceedings of the Fifth International Conference on Inorganic Membranes, 1998, 96—99.
[94 ] Luyten J , Buekenhoudt A , Weyten H, Adriansens W , Cooymans J , Leysen R, Proceedings of the Fifth International Conferenceon Inorganic Membranes, 1998, 6—9.
[1] 翟康, 李孔斋, 祝星, 魏永刚. 两步热化学分解水制氢用氧交换材料[J]. 化学进展, 2015, 27(10): 1481-1499.
[2] 陈婷, 赵海雷, 谢志翔, 徐景璨, 徐南生, 李福燊. 双相致密透氧膜[J]. 化学进展, 2012, 24(01): 163-172.