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化学进展 1998, Vol. 10 Issue (04): 381- 前一篇   后一篇

• 综述与评论 •

催化新材料——钛硅分子筛合成及应用研究*

周继承; 王祥生   

  1. 大连理工大学碳资源综合利用开放实验室 大连 116012
  • 收稿日期:1997-08-01 修回日期:1998-03-01 出版日期:1998-11-24 发布日期:1998-11-24
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The Syntheses and Applications of Titanium Silicalite Molecular Sieves as a New Kind of Catalytic Materials

Zhou Jicheng;Wang Xiangsheng   

  1. Open Laboratory of Comprehensive Utilization for Carbon Resources,Dalian University of Technology, Dalian 116012, China
  • Received:1997-08-01 Revised:1998-03-01 Online:1998-11-24 Published:1998-11-24

评述了钛硅分子筛新催化材料的合成及其催化应用的研究进展, 包括钛硅分子筛(TS21) 的水热合成方法、原料、模板剂、影响因素、TS21 同晶取代法合成、表征、活性中心、钛硅分子筛双氧水体系的应用研究及近年中孔钛硅分子筛的进展。对未来的研究提出了建议。

关键词： 钛硅, 苯酚羟基化, 环氧化, 催化氧化, 双氧水, 分子筛

Recent developments in the applications and syntheses of titanium silicalite molecular sieves as a new kind of catalytic materials were reviewed, including developments of TS21 hydro thermal synthesis methods, raw materials, templating agents,affecting factors, TS21 synthesis by isomorphous replacement, charaterization, active sites, application softitanium silicalite catalytic oxidation system using hydrogen peroxide, and research of mesoporous titanium silicalite molecular sieves. Suggestions for further research were proposed.

Key words: titanium silicalite, hydroxylation of phenol, epoxidation, catalytic oxidation, hydrogen peroxide, molecular sieves

中图分类号: 

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