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化学进展 1998, Vol. 10 Issue (04): 362- 前一篇   后一篇

• 综述与评论 •

银团簇的形成及性质研究*

彭必先; 崔卫东;赵翔   

  1. 中国科学院感光化学研究所 北京 100101
  • 收稿日期:1997-12-01 修回日期:1998-04-01 出版日期:1998-11-24 发布日期:1998-11-24
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Formation and Properties of Silver Clusters

Peng Bixian;Cui Weidong;Zhao Xiang   

  1. Institute of Photographic Chemistry, Chinese Academy of Sciences,Beijing 100101, China
  • Received:1997-12-01 Revised:1998-04-01 Online:1998-11-24 Published:1998-11-24

本文综述了在固相、液相和气相中形成银团簇的方法, 银团簇的主要性质如吸收光谱、ESR、氧还电位、电子亲和势与电离能, 以及银团簇在光解水和照相显影过程中的催化作用。总结了银团簇的理论计算方法及计算得到的主要性质如稳定几何结构、电子亲和势与电离能。最后展望了今后的发展趋势。

关键词： 银团簇, 幻数, 奇偶振荡, 理论计算

This paper describes the methods to form silver clusters in solid, liquid and gas phases; the properties of clusters such as absorption bands, ESR, redox potential, EA and IP, and their catalytic behaviours in photo-splitting water and photographic development processes. The theoretical calculation methods, the calculated properties such as geometry, EA and IP of silver clusters are also discussed. The trends of research on this subject are prospected.

Key words: silver clusters, magic numbers, odd-eveno scillation, theoretical calcu lat ion

中图分类号: 

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[1 ] Maerk T D, Int. J. Mass Spectrom. Ion Process, 1987, 79, 1.
[2 ] 王广厚, 窦烈, 庞锦忠, 邹南之, 龚昌德, 物理学进展, 1987, 7, 1.
[3 ] Cassady C J , WeilD A , McElvaney S W , J. Chem. Phys. , 1992, 96, 691.
[4 ] Clustersof Atomsand Molecules: é. Theory , Experiment,and Clustersof Atoms; ê. Solvation and Chemistry of Free Clusters,and Embedded , Supportedand Compressed Clusters (ed. Haberland H ) ,Spring-Verlag, Berlin, Heidelberg, 1994.
[5 ] Tani T , Photographic Sensitivity , Oxford University Press, Oxford, 1995.
[6 ] Sheppard S E, TrivelliA P H, Loveland R P, J. Franklin Inst. , 1925, 200, 51.
[7 ] Peng B X, Cui W D, Yu Z D et al. , Sci.in China: B , 1997, 40, 309.
[8 ] Cui W D, Peng B X, Liu P et al. , Sci.in China: B , 1998, 41, 182.
[ 9 ] Cui W D, Peng B X, Liu P et al. , IS &T /S PS EJ ’s Intern. Symp.on Silver Halide Imaging , Oct.27—30, 1997, IS&T , Springerfield , 175.
[10 ] Ozin G A , Hugues F, Mc Intosh D F et al. , A CS Symp. Ser. , 1983, 218, 409.
[11 ] Henglein A , Chem. Rev. , 1989, 89, 186;
[12 ] Henglein A , Top. Curr. Chem. , 1988, 143, 113.
[13 ] Sun T , Seff K, Chem. Rev. , 1994, 94, 857.
[14 ] Ozin G A , Gil C J , Chem. Rev. , 1989, 89, 1749.
[15 ] Ozin G A , Cupperman A , Stein A , Angew. Chem. Int. Ed. Engl. , 1989, 28, 359.
[16 ] Stucky G D, MacDougall J E, Science, 1990, 247, 669.
[17 ] Kim Y, Serf K, J. Am. Chem. Soc. , 1977, 99, 7055; 1977, 100, 6989.
[18 ] Norman I, Porter G, Nature, 1954, 174, 508.
[19 ] Whittle E, Dows D A , Pimentel G C, J. Chem. Phys. , 1954, 22, 1943.
[20 ] The Theoryof Photographic Process, 4thed. (ed. James T H ) , MacMillan Publishing Co. , New York, 1977.
[21 ] Fayet P, Granzer F, Hegenbart G et al. , Phys. Rev. Lett. , 1985, 55, 3002.
[22 ] Henglein A , Ber. Bunsenges. Phys. Chem. , 1977, 81, 556.
[23 ] Henglein A , Chem. Phys. Lett. , 1989, 154, 473.
[24 ] Henglein A , Linnert T , Mulvaney P, Ber. Bunsenges. Phys. Chem. , 1990, 94, 1449.
[25 ] Mulvaney P, Henglein A , Chem. Phys. Lett. , 1990, 168, 391.
[26 ] Mulvaney P, Henglein A , J. Phys. Chem. , 1990, 94, 4182.
[27 ] Ershov B G, Janata E, Henglein A , J. Phys. Chem. , 1993, 97, 339.
[28 ] Ershov B G, Janata E, Henglein A et al. , J. Phys. Chem. , 1993, 97, 4589.
[29 ] Henglein A , J. Phys. Chem. , 1993, 97, 5457.
[30 ] Mostafavi M , Keghouche N , Delcourt M O et al. , Chem. Phys. Lett. , 1990, 167, 193.
[31 ] Remita S, Orts J M , Feliu J M , Chem. Phys. Lett. , 1994, 218, 115.
[32 ] Marignier J L , Belloni J , Delcourt M O , Nature, 1985, 317, 344.
[33 ] Remita H, Khtouri J , Treguer M et al. , Z. Phys. D , 1997, 40, 127.
[34 ] Kobayashi M , Sato H, Chem. Lett. , 1993, 10, 1659.
[35 ] 崔卫东, 彭必先, 感光科学与光化学, 1997, 15, 193.
[36 ] Linnert T , Mulvaney P, Henglein A et al. , J. Am. Chem. Soc. , 1990, 112, 4657.
[37 ] Sydow M , Stolle T H, Karsch B, J. Inf . Rec. Mats. , 1995, 22, 279.
[38 ] Fendler J H, Chem. Rev. , 1987, 87, 877.
[39 ] Luisi P L , Magid L J , CRC Crit. Rev. Biochem. , 1986, 20, 409.
[40 ] Barnickel P, Wokaun A , Mol. Phys. , 1990, 69, 1.
[41 ] Barnickel P, Wokaun A , Sager W et al. , J. Colloid Interface Sci. , 1992, 148, 80.
[42 ] Christophe P, Patricia L , Pileni M P, J. Phys. Chem. , 1993, 97, 12974.
[43 ] Brucat P J , Ahane L S, Smalley R E et al. , J. Chem. Phys. , 1986, 84, 3078.
[44 ] Schrittenlacher W , Rotermund H H, Schroeder W et al. , Surf . Sci. , 1985, 156, 777.
[45 ] Kolb D M , Barnes A J , Orville-Thomas W J et al. ,in Matrix Isolation Spectroscopy , Reidel,Dordrecht, 1981, 347and 447.
[46 ] Ozin G A , Appl. Spectroscopy , 1976, 30, 573.
[47 ] Ozin G A , Huber H, Mc Intosh D, J. Am. Chem. Soc. , 1979, 101, 3504.
[48 ] Mitchell S A , Ozin G A , J. Am. Chem. Soc. , 1978, 100, 6776.
[49 ] Ozin G A , Huber H, Inorg. Chem. , 1978, 17, 155.
[50 ] Ozin G A , Klotzbucher W E, Inorg. Chem. , 1979, 18, 2101.
[51 ] Mitchell S A , Ozin G A , J. Phys. Chem. , 1984, 88, 1425.
[52 ] Klotzbucher W E, Inorg. Chem. , 1980, 19, 3776.
[53 ] Howard J A , Preston K F, Mile B, J. Am. Chem. Soc. , 1981, 103, 6226.
[54 ] Howard J A , Preston K F, Sutcliffe R, J. Phys. Chem. , 1983, 87, 536.
[55 ] Howard J A , Preston K F, Sutcliffe R et al. , J. Chem. Soc. , Chem. Commun. , 1983, 1449.
[56 ] Howard J A , Sutcliffe R, Mile B, J. Am. Chem. Soc. , 1983, 105, 1394.
[57 ] Howard J A , Sutcliffe R, Tse J S et al. , Chem. Phys. Lett. , 1983, 94, 561.
[58 ] Howard J A , Sutcliffe R, Mile B, J. Phys. Chem. , 1983, 87, 2268.
[59 ] Howard J A , Sutcliffe R, Mile B, J. Phys. Chem. , 1984, 88, 2183.
[60 ] Howard J A , Sutcliffe R, Mile B, J. Catal. , 1984, 90, 156.
[61 ] Howard J A , Sutcliffe R, Mile B, Surf . Sci. , 1985, 156, 214.
[62 ] Schulze W , Becker H U , Minkwitz R, Chem. Phys. Lett. , 1978, 55, 59.
[63 ] Bach S B H, Garland D A , Vanzee R J et al. , J. Chem. Phys. , 1987, 87, 869.
[64 ] Stevens A D, Symons M C R, Chem. Phys. Lett. , 1984, 109, 514.
[65 ] Janes R, Stevens A D, Symons M C R, J. Chem. Soc. , Chem. Commun, 1988, 1454.
[66 ] Ershov B G, Sukhov N L , Kiseleva A V et al. , Izu. Akad. Nauk. Ser. Khim. , 1996, 586.
[67 ] Stevens A D, Symons M C R, Eachus R S, Phys. Stat. Solid B , 1989, 154, 483.
[68 ] Katakuse I, Ichihara T , Fujita Y et al. , Int. J. Mass Spectr. Ion Processes, 1985, 67, 229.
[69 ] Fayet P, Woste L , Surf . Sci. , 1985, 156, 1340.
[70 ] Hilpert K, Gingerich K A , Ber. Bungense. Phys. Chem. , 1980, 84, 739.
[71 ] Henglein A , Ber. Bungense. Phys. Chem. , 1990, 94, 600.
[72 ] Bauschlicher C W , Langhoff S R, Partridge H, J. Chem. Phys. , 1990, 93, 8133.
[73 ] Smalley R E, Chem. Phys. Lett. , 1987, 138, 119.
[74 ] Smalley R E, Rev. Sci. Instrum. , 1987, 58, 2131.
[75 ] Lutz H O , Phys. Rev. A , 1988, 37, 2716.
[76 ] Lutz H O , Faraday Discussion Chem. Soc. , 1988, 86, 197.
[77 ] Handschuh A , Rev. Sci. Instrum. , 1995, 66, 3838.
[78 ] Estman D E, Phys. Rev. B , 1970, 2, 1.
[79 ] Ho J , Ervin K M , Linerberger W C, J. Chem. Phys. , 1990, 93, 6987.
[80 ] Gantefor G, Gausa M , Meiwes-Broer K H, Lutz H O , J. Chem. Soc. , Faraday Trans. , 1990, 86,2483.
[81 ] Cheshnovsky O , Taylor K J , Cinceicao J et al. , Phys. Rev. Lett. , 1990, 64, 1785.
[82 ] Wood D M , Phys. Rev. Lett. , 1981, 46, 749.
[83 ] Schumacher E, Kappes M M , Schar M et al. , Ber. Bunsenges. Phys. Chem. , 1984, 88, 220.
[84 ] Kappes M M , Schar M , Radi P, Schumacher E, J. Chem. Phys. , 1986, 84, 1863.
[85 ] Kawasaki M , Tsujimura Y, Hada H, Phys. Rev. Lett. , 1986, 57, 2796.
[86 ] Beer R, Calzaferri G, Li J W et al. , Coordination Chemistry Review , 1991, 111, 193.
[87 ] Stoll H, Fuentealba P, Dolg M et al. , J. Chem. Phys. , 1983, 79, 5532.
[88 ] Stoll H, Fuentealba P, Schwerdtfeger P et al. , J. Chem. Phys. , 1984, 81, 2732.
[89 ] Hay P J , Martin R L , J. Chem. Phys. , 1985, 83, 5174.
[90 ] LaJohn L A , Christiansen P A , Boss R B et al. , J. Chem. Phys. , 1987, 87, 2812.
[91 ] Walch S P, Bauschlicher C W Jr, Langhoff S R, J. Chem. Phys. , 1986, 85, 5900; 1987, 87, 6776.
[92 ] Basch H, J. Am. Chem. Soc. , 1981, 103, 4657.
[93 ] Bauschlicher C W Jr, Langhoff S R, Patridge H, J. Chem. Phys. , 1989, 91, 2412.
[94 ] Patridge H, Bauschlicher C W Jr, Langhoff S R, Chem. Phys. Lett. , 1990, 175, 531.
[95 ] Bauschlicher C W Jr, Langhoff S R, Patridge H, J. Chem. Phys. , 1990, 93, 8133.
[96 ] Flad J , Igel-Mann G, Preuss H et al. , Ber. Bunsenges. Phys. Chem. , 1984, 88, 241.
[97 ] Balasubramanian K, Das K K, J. Chem. Phys. , 1991, 94, 2923.
[98 ] Balasubramanian K, Feng P Y, J. Phys. Chem. , 1990, 94, 1536.
[99 ] Bauschlicher C W Jr, Langhoff S R, Patridge H, J. Phys. Chem. , 1990, 94, 8378.
[100 ] Balasubramanian K, Das K K, J. Phys. Chem. , 1990, 94, 8379.
[101 ] Balasubramanian K, Feng P Y, Chem. Phys. Lett. , 1989, 159, 452.
[102 ] Jiao D W , Balasubramanian K, J. Chem. Phys. , 1992, 97, 2548.
[103 ] Santamaria R, Kaplan I G, Novaro O , Chem. Phys. Lett. , 1994, 218, 395.
[104 ] Bonacic-Koutecky V , Cespiva L , Fantucci P et al. , J. Chem. Phys. , 1993, 98, 7981; 100, 490.
[105 ] He T J , Liu F C, J. Photogr. Sci. , 1996, 44, 102.
[106 ] Montano P A , Zhao J , Schulze W , Chem. Phys. Lett. , 1989, 164, 126.
[107 ] Binns C, Bayliss S C, Derbyshire H S, Z. Phys. D , 1991, 20, 391.
[108 ] Rabin I, Schulze W , Chem. Phys. Lett. , 1993, 201, 265.
[109 ] Kruckeberg S, Dietrich G, Lutzenkirchen K et al. , Z. Phys. D , 1997, 40, 341.
[110 ] Saupt S, Kaller J , Schooss D et al. , Z. Phys. D , 1997, 40, 331
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摘要

银团簇的形成及性质研究*