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化学进展 1997, Vol. 9 Issue (04): 361- 前一篇   后一篇

• 综述与评论 •

非均匀体系介电研究的现状与展望*

赵孔双   

  1. （厦门大学化学系 固体表面物理化学国家重点实验室 厦门 361005）
  • 收稿日期:1996-12-01 修回日期:1997-05-01 出版日期:1997-11-24 发布日期:1997-11-24
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Present Situation and Prospects of Dielectric Study on Heterogeneous Systems

Zhao Kongshuang   

  1. State Key Laboratory for Physical Chemistry of Solid Surface,Department of Chemistry, Xiamen University, Xiamen 361005, China
  • Received:1996-12-01 Revised:1997-05-01 Online:1997-11-24 Published:1997-11-24

用介电谱方法讨论化学中的非均匀体系是近十几年发展起来的交叉性新领域, 它在分散体系、高分子膜以及生物细胞体系的研究中占有重要地位。本文从理论和应用两方面综述该领域的发展过程及研究现状, 并结合实例阐述了构造和介电弛豫模式的关系以及该方法的特点。在对遗留问题和最新进展给予评述性讨论的同时, 指出了进一步的研究方向。

关键词： 非均匀体系, 介电弛豫, 乳状液, 生物细胞, 高分子膜

Dielectric spectro scopymethod (DSM ) for studying chemistry systems with heterogeneous structure is an interdisciplinary area developed in recent 10 years. The method is very important in the studies for disperse systems, membranes and biological cells systems. This paper reviews the history and current research on the DSM for heterogeneous systems in both theoretical and practical aspects. In presenting the features of the method, the emphases are laid on the relation between the structures of heterogeneous systems and relaxation patterns with examples illustrated. The problems remained and recent progress are introduced, and some research aspects for further work are proposed.

Key words: heterogeneous systems, dielectric relaxation, emulsion, biological cells, polymer membranes

中图分类号: 

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[1 ] Maxwell J C,in Electricityand Magnetism , Clarendon Press, Oxford, 1892,p. 452.
[2 ] Wagner K W , Arch. Elektrotech. , 1914, 2, 371.
[3 ] Trukhan E M , Phys. Solid State, 1967, 4, 2560.
[4 ] Garcia A , Grosse C, Brito P, J. Phys. , D : Appl. Phys. , 1985, 18, 738.
[5 ] Pauly H, Schwan H P, Z. Naturf . B , 1959, 14, 125.
[6 ] Takashima S, Gabriel C, Sheppard R J , Grant E H, Biophys. J. , 1984, 46, 29. 　
[7 ] Hanai T , Kolloid Z. , 1960, 171, 23.
[8 ] Hanai T , Imakita T , Koizumi N , Colloidand Polymer Sci. , 1982, 260, 1029.
[9 ] Ishikawa A , Hanai T , Koizumi N , Colloidand Polymer Sci. , 1984, 262, 477.
[10 ] Asami K, Hanai T , Koizumi N , Biophys. J. , 1980, 31, 215.
[11 ] Asami K, Irimajiri A , Hanai T , Shiraishi N , Utsumi K, Biochim. Biophys. Acta, 1984, 778,559.
[12 ] Zhang H, Sekine K, Hanai T , Koizumi N , Colloidand Polymer Sci. , 1983, 261, 381.
[13 ] Irimajiri A , Hanai T , Ynoye A , J. Theor. Biol. , 1979, 78, 251.
[14 ] Asami K, Irimajiri A , Biochim. Biophys. Acta, 1984, 778, 570.
[15 ] Hanai T , Sekine K, Colloidand Polymer Sci. , 1986, 264, 888.
[16 ] Zhao K S, Asaka K, Sekine K et al. , Bull. Inst. Chem. Res. , Kyoto Univ. , 1988, 66, 540.
[17 ] Zhao K S, Asaka K, Asami K, Hanai T , Bull. Inst. Chem. Res. , Kyoto Univ. , 1989, 67, 225.
[18 ] Kiyohara K, Zhao K S, Asaka K, Hanai T , Jpn. J. Appl. Phys. , 1990, 29, 1751.
[19 ] Zhao K S, Matsubara Y, Asaka K, Asami K, Hanai T , J. Membrane Sci. , 1991, 64, 163.
[20 ] Zhao K S, Hanai T , The 1st Conference for Worldwide Young Chinese Chemists, CW YCC 95,20～ 24 August, Peking, 1995, Abstracts,p. 358.
[21 ] Asaka K, Zhao K S, Asami K, Membrane (Maku) , 1994, 19 (6) , 411.
[22 ] Kubo M , Nakamura S, Bull. Chem. Soc. Japan, 1953, 26, 318.
[23 ] Rue R E D L , Tobias C W , J. Electrochem. Soc. , 1959, 106, 827.
[24 ] Hanai T , Kolloid Z. , 1961, 175, 61.
[25 ] Hanai T , Koizumi N , Gotoh R, Kolloid Z. , 1962, 184, 143.
[26 ] Hanai T , Imakita T , Koizumi N , Colloid Polymer Sci. , 1982, 260, 1029.
[27 ] Ishikawa A , Hanai T , Koizumi N , Bull. Inst. Chem. Res. , Kyoto Univ. , 1984, 62, 251.
[28 ] Sasaki S, Ishikawa A , Hanai T , Biophy. Chem. , 1981, 14, 45.
[29 ] Zhao K S, Hanai T , Bull. Inst. Chem. Res. , Kyoto Univ. , 1991, 69 (4) , 358.
[30 ] Bonincontro A , Cametti C, DiBiasio A , J. Phys. D : Appl. Phys. , 1980, 13, 1529.
[31 ] Carcia A , Crosse C, Brito P, J. Phys. D : Appl. Phys. , 1985, 18, 738.
[32 ] Hill R M , Cooper J , J. Colloid Interface Sci. , 1995, 174, 24.
[33 ] Cametti C, Codastefano P, Tartaglia P, Ber. Bunsenges. Phys. Chem. , 1990, 94, 1499.
[34 ] Hill R M , Cooper J , J. Mater. Sci. , 1992, 27, 4818.
[35 ] Hill R M , Beckford E S, Rowe R C, Jones C B, Dissado C A , J. Colloid Interface Sci. , 1990, 138(2) , 521.
[36 ] Pauly H, Schwan H P, Z. Naturf . , 1959, 14B , 125.
[37 ] Asami K, Hanai T , Koizumi N , J. Membrane Biol. , 1976, 28, 169.
[38 ] Hanai T , Koizumi N , Irimajiri A , Biophys. Struct. Mechanism , 1975, 1, 285.
[39 ] Sekine K, Hanai T , Koizumi N , Bull. Inst. Chem. Res. , Kyoto Univ. , 1983, 61 (4) , 299.
[40 ] Asami K, Hanai T , KoizumiN , J. Membrane Biol. , 1977, 34, 145.
[41 ] Asami K, Takahashi Y, Takashima S, Biochim. Biophys. Acta, 1989, 1010, 49.
[42 ] Asami K, Zhao K S, Colloid Polymer Sci. , 1994, 272, 64.
[43 ] 赵孔双, 高等学校化学学报, 1997, 18 (1) , 107.
[44 ] IrimajiriA , Hanai T , Inouye A , J. Theor. Biol. , 1979, 78, 251.
[45 ] Asami K, Hanai T , Koizumi N , Biophys. J. , 1980, 31, 215.
[46 ] Asami K, Hanai T , Koizumi N , Jpn. J. Appl. Phys. , 1980, 19 (2) , 359.
[47 ] Hanai T ,in Emulsion Science (ed. Sherman P) , Academic Press, London-New York, 1968,p. 353.
[48 ] Zhang H Z, Hanai T , KoizumiN , Bull. Inst. Chem. Res. , Kyoto Univ. , 1983, 61 (4) , 265.
[49 ] Hanai T , Haydon D A , Taylor J , Proc. Roy. Soc. , 1964, A 281, 377.
[50 ] Coster H G L , Smith J R, Biochim. Biophys. Acta, 1974, 373, 151.
[51 ] Mann B, Kuhn H, J. Appl. Phys. , 1971, 42, 4398.
[52 ] Sekine K, Hanai T , Koizumi N , Membrane (Maku) , 1984, 9 (6) , 351.
[53 ] Asaka K, J. Membrane Sci. , 1990, 50, 71.
[54 ] Hanai T , Zhao K S, Asaka K, Asami K, J. Membrane Sci. , 1991, 64, 153.
[55 ] 赵孔双, 科学通报, 1996, 41 (17) , 1583.
[56 ] Hanai T , Zhao K S, Asaka K, Asami K, Colloidand Polymer Sci. , 1993, 271 (8) , 766.
[57 ] Zhao K S, Asaka K, Asami K, Hanai T , J. Colloid Interface Sci. , 1992, 153, 562.
[58 ] 赵孔双, 花井哲也, 化学物理学报, 1996, 9 (2) , 154.
[59 ] 赵孔双, 物理化学学报, 1996, 12 (7) , 635.
[60 ] Hanai T , Zhang H Z, Sekine K, Asaka K, Asami K, Ferroelectrics, 1988, 86, 191.
[61 ] 赵孔双, 花井哲也, 电化学, 1995, 1 (3) , 319.
[62 ] Ito M , Yoshikawa S, Asami K, Hanai T , Cereal Chem. , 1992, 69 (3) , 325.
[63 ] Harris C M , Todd R W , Bungard S J , Lovitt R W , Morris G, KellD B, Enzyme Microb. Technol. , 1978, 9, 181.
[64 ] Davey C L , Davey H M , KellD B, Analytica Chimica Acta, 1993, 279, 155.
[65 ] Asami K, Yonezawa T , Biochim. Biophys. Acta, 1995, 1245, 99.
[66 ] Asami K, Meas. Sci. Technol. , 1994, 5, 589.
[67 ] Asami K, Colloidand Polymer Sci. , 1995, 273, 1095.
[68 ] Asami K, Yonezawa T , Wakamatsu H, Koyanagi N , Bioelectrochemistry and Bioenergetics, 1996,40, 141.
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