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化学进展 1997, Vol. 9 Issue (02): 111-   后一篇

• 综述与评论 •

两相催化--均相催化多相化新进展*

郑晓来;蒋景阳;王兵**;金子林***   

  1. （大连理工大学化工学院精细化工国家重点实验室 大连 116012）
  • 收稿日期:1996-04-01 修回日期:1996-10-01 出版日期:1997-06-24 发布日期:1997-06-24
  • 通讯作者: 金子林
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Two-Phase Catalysis Recent Advances in the Heterogenization of Homogeneous Catalysis

Zheng Xiaolai;Jiang Jingyang;Wang Bing;Jin Zilin   

  1. (State Key Laboratory of Fine Chemicals, School of Chemical Engineering,Dalian University of Technology, Dalian 116012, China)
  • Received:1996-04-01 Revised:1996-10-01 Online:1997-06-24 Published:1997-06-24
  • Contact: Jin Zilin

评述了水溶性膦配体和两相催化研究领域的进展, 探讨了固载水相催化、温控相转移催化和氟两相体系等新型两相催化体系。两相催化在烯烃的氢甲酰化反应、不饱和化合物的加氢反应以及其它有机反应中获得了广泛的应用。

关键词： 两相催化, 水溶性膦配体, 金属有机配合物, 加氢甲酰化, 加氢反应

Recent developments in the chemistry of watersoluble phosphines and two-phase catalysis are discussed, including several novel two-phase catalytic systems that are supported aqueous phase catalysis, thermoregulated phase transfer catalysis, and fluorous biphase system. Numerous applications of two-phase catalysis to hydroformylation,hydrogenation and other organic reactions are also described.

Key words: two-phase catalysis, water-soluble phosphines, organometallic complexes, hydroformylation, hydrogenation

中图分类号: 

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