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化学进展 1997, Vol. 9 Issue (01): 59- 前一篇   后一篇

• 综述与评论 •

非线性化学反应动力学*

高庆宇;蔡遵生;赵学庄**   

  1. （南开大学化学系 天津 300071）
  • 收稿日期:1995-01-01 修回日期:1996-10-01 出版日期:1997-03-24 发布日期:1997-03-24
  • 通讯作者: 赵学庄
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Nonlinear Kinetics in Chemical Reactions

Gao Qingyu;Cai Zunsheng;Zhao Xuezhuang**   

  1. (Department of Chemistry, Nankai University, Tian jin 300071, China)
  • Received:1995-01-01 Revised:1996-10-01 Online:1997-03-24 Published:1997-03-24
  • Contact: Zhao Xuezhuang

本文从实验和理论的角度综述非线性化学反应动力学。介绍了若干非线性化学反应动力学现象如时钟反应、反馈、混合振荡、化学混沌及反应扩散图案等; 对时空序列、功率谱、Lyapunov 指数、吸引子及其维数、Poincare 截面及分叉理论等常用于分析非线性动力学特征的手段作了介绍; 探讨了对非线性化学反应的实验装置、测试方法、机理和模型研究的方法; 简要回顾了非线性化学反应动力学的发展历史, 并展望了其发展趋势。

关键词： 非线性动力学, 反馈, 机理与模型, 动力学的发展

The nonlinear chemical reaction kineticsis comprehensively reviewed experimentally and theoretically. Many nonlinear chemical kinetics phenomena such as the clock reaction, feedback, mixed oscillation, chemical chaos and chemical patterns are introduced. The methods of time space series, power spectrum , Lyapunov index, at tractors and their dimensions, Poincare section, bifurcation theorem are also discussed. The reactors, measurement, mechanisms and models in nonlinear chemical reaction research are described.

Key words: nonlinear kinetics, feedback, mechanism and model, development of kinetics

中图分类号: 

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非线性化学反应动力学*