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化学进展 1996, Vol. 8 Issue (03): 177-   后一篇

• 综述与评论 •

柔性链高聚物的单分子链玻璃体和单晶*

钱人元; 吴立衡   

  1. （中国科学院化学研究所 北京 10080； 中国纺织科学研究院测试中心 北京 100025）
  • 收稿日期:1995-03-01 修回日期:1996-04-01 出版日期:1996-09-24 发布日期:1996-09-24
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Single-Chain Glasses and Single Crystals of Flexible Chain Polymers

Qian Renyuan;Wu Liheng   

  1. (Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China; Testing Centre of Texfile Academy, Beijing 100025, China)
  • Received:1995-03-01 Revised:1996-04-01 Online:1996-09-24 Published:1996-09-24

本文综述了高分子单链颗粒的制备方法, 包括极稀溶液喷雾法、表面扩张膜法、冷冻干燥法、微乳液聚合法等。介绍和讨论了单链和寡链聚苯乙烯玻璃体微球的性质以及聚环氧乙烷、全同立构聚苯乙烯、顺-1, 4-聚丁二稀、反-1, 4-聚异戊二烯单链单晶电子显微镜和选区电子衍射观察的最新结果。

关键词： 单分子链颗粒, 单分子链玻璃体, 单分子链单晶

A review is presented on the methods of preparation of single-chain particles, including atomizer spraying, surface film spreading, freeze-drying of very dilute solutions and microemulsion polymerization. The properties of single-chain and pauci-chain polystyrene microspheres and recent results on the electron microscopy and selected area electron diffraction of single-chain monocrystals of polyethylene oxide, isotactic polystyrene, cis-1, 4-polybutadiene and guttapercha are presented and discussed.

Key words: single-chain particles, single-chain glass, single-chain monocrystals

中图分类号: 

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[1 ] Bover R F, Heidenreich R D, J. Appl. Phys. , 1945, 16, 62.
[2 ] Barnikol I, Barnikol W K R, Beck A , Campagnari-Terbojevic′M , Jovanovic′N , Schulz G V , Makromol. Chem. , 1970, 137, 111.
[3 ] Koszterszitz G, Schulz G V , Makromol. Chem. , 1977, 178, 2437.
[4 ] Siegel B M , Johnson D H, Mark H, J. Polym. Sci. , 1950, 5, 111.
[5 ] Richardson M J , J. Polym. Sci. , 1963, C3, 21.
[6 ] Richardson M J , Proc. Roy. Soc. London, 1964, A 279, 50.
[7 ] Quayle D V , Polymer, 1967, 8, 217.
[8 ] Qian R, Macromolecules (ed. Benoit H, Rempp P) , Pergamon Press, Oxford, 1982,p. 139.
[9 ] 钱人元, 曹锑, 陈尚贤, 白凤莲, 中国科学B, 1983, 1080.
[10 ] Lohse D J , Macromolecules, 1981, 14, 1658.
[11 ] Cheng R, Yan X, J. Appl. Polym. Sci. , Appl Polym. Symp. , 1991, 48, 123.
[12 ] Wu C, J. Polym. Sci. B : Polym. Phys. , 1994, 32, 1503.
[13 ] Liu L , Li H, Jiang Z, Zhou E, Qian R, Makromol. Chem. Rapid Commun. , 1993, 14, 747.
[14 ] Schoon Th G F, Kretschmer R, Koll. Z. Z. Polym. , 1964, 197, 51.
[15 ] Kumaki J , Macromolecules, 1986, 19, 2258.
[16 ] Koszterszitz G, Barnikol W K R, Schulz G V , Makromol. Chem. , 1977, 178, 1133.
[17 ] Pouyet G, Kohler A , Dayantis J , Macromolecules, 1981, 14, 1126.
[18 ] Jachowicz J , Morawetz H, Macromolecules, 1982, 15, 828.
[19 ] Ruscher Ch, J. Polym. Sci. , 1967, C16, 2923.
[20 ] Brawn H R, Wignall G D, Macromolecules, 1990, 23, 683.
[21 ] Berlin A A , Penskaya E A , Volkova G I, J. Polym. Sci. , 1962, 56, 477.
[22 ] Patat F, Hobgner W , Makromol. Chem. , 1964, 75, 85.
[23 ] Zysman V , Nguyen T Q , Kausch H H, J. Polym. Sci. Polym. Phys. , 1994, 32, 1257.
[24 ] McGrath K J , Roland C M , Macromolecules, 1992, 25, 1366.
[25 ] Schultz A R, Young A L , Macromolecules, 1980, 13, 663.
[26 ] Dunn A S, Comprehensive Polymer Science (ed. Allen G, Bevington J C) , Pergamon Press, Oxford,1989, Vol. 4,p. 222.
[27 ] Guo J S, El-Aasser M S, Vanderhoff J W , J. Polym. Sci. Polym. Chem. , 1989, 27, 691.
[28 ] Atik S S, Thomas J K, J. Am. Chem. Soc. , 1981, 103, 4279.
[29 ] Johnson P L , Gulari E, J. Polym. Sci. Polym. Chem. , 1984, 22, 3967.
[30 ] Qian R, Wu L , Shen D, Napper D H, Mann R A , Sangster D F, Macromolecules, 1993, 26, 2950.
[31 ] Kuo P L , Turro N J , Tseng C M , El-Aasser M S, Vanderhoff J W , Macromolecules, 1987, 20,1216.
[32 ] Antonietti M , Bremser W , Musechenborn D, Rosenauer C, Schupp B, Schmidt M , Macromolecules,1991, 24, 6636.
[33 ] Candau F, Leong Y S, Fitch R M , J. Polym. Sci. Polym Chem. , 1985, 23, 193.
[34 ] Wu D, Zhao D, Qian R, Polymer, 1986, 27, 1087.
[35 ] Volkenstein M V , Sharonov Yu A , Vysokomol. Soed. , 1961, 3, 1739.
[36 ] Gaur U , Wunderich B, Macromolecules, 1980, 13, 1618.
[37 ] Illers K H, Makromol. Chem. , 1969, 127, 1.
[38 ] Wu C, Chan K K, Woo K F, Qian R, Li X, Chen L , Napper D H, Tan G, Hill A J , Macromolecules, 1955, 28, 1592.
[39 ] Chalesby A , Rad. Phys. Chem. , 1979, 14, 919.
[40 ] Chalesby A , Jaroszkiewicz E M , Eur. Polym. J. , 1985, 21, 55.
[41 ] Groseclose B C, Loper G D, Phys. Rev. , 1965, 137, A 939.
[42 ] Kasbekar A D, Jones P L , Crowson A , J. Polym. Sci. Polym. Phys. , 1989, 27, 1373.
[43 ] McGervey J , Panigrahi N , Simha R, Jamieson A , Positron Annihilation (eds. Jain P C, Singru R M ,Gopinathan K P) , World Scientific Publ. Co. , Singapore, 1985,p. 690.
[44 ] O ′Connor P J , Kocher CW , LandesB G, Anderson S L , Delassus P T , Gruike E A , Polym. Prepr.A CS , 1992, 33, 308.
[45 ] Deng Q , Jean Y C, Macromolecules, 1993, 26, 30.
[46 ] Bittiger H, Husemann E, Makromol. Chem. , 1966, 96, 92.
[47 ] Bu H, Pang Y, Song D, Yu T , Voll T M , Czornyj G, Wunderich B, J. Polym. Sci. Polym. Phys. ,1991, 29, 139.
[48 ] Bu H, Chen E, Xu S, Guo K, Wunderich B, J. Polym. Sci. Polym. Phys. , 1994, 32, 1351.
[49 ] Xue G, Wang Y, Li Y, Macromol. Rapid Commun. , 1994, 15, 719.
[50 ] Bu H, Chen E, Yao J , Xu S, Kuang Y, Polym. Eng. Sci. , 1992, 32, 1209.
[51 ] Natta G, Corradini P, Angew. Chem. , 1956, 68, 615.
[52 ] Keller A , Martuscelli E, Makromol. Chem. , 1972, 151, 189.
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