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化学进展 2022, Vol. 34 Issue (9): 1879-1881 DOI: 10.7536/PC220715   后一篇

• 中国化学印记 •

具有全色发光的非芳香聚马来酰亚胺

朱天文, 袁望章*()   

  1. 上海交通大学化学化工学院 上海 200240
  • 出版日期:2022-09-20 发布日期:2022-09-19
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Nonaromatic Polymaleimides with Full-Color Photoluminescence

Tianwen Zhu, Wang Zhang Yuan()   

  1. School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
  • Online:2022-09-20 Published:2022-09-19
  • Contact: *e-mail: wzhyuan@sjtu.edu.cn

Jun Zhang’s group developed a new kind of nonaromatic polymaleimides (A-PM) via anionic polymerization. By adjusting the reaction conditions, the emission colors of A-PM are readily tunable from blue, green to orange and red, which is rarely achieved in nonconventional luminophores. These unique properties endow A-PM promising for applications in encryption, ion detection, fingerprint identification, etc. This work not only sheds new lights on the rational regulation of photophysical properties of nonconventional luminophores, but also paves the way for their versatile applications.

()
Fig.1 (a) Synthetic routes to Fr-PM and A-PM; (b) Fluorescent images of A-PM powders and DMF solutions synthesized with different Lewis bases. (c) Concentration and (d) water contents dependent emission spectra of A-PM-TEA/DMF solutions. (e) Fluorescent images and (f) emission intensities of A-PM-TEA compressed by different pressures [6]
Fig.2 Schematic illustration of (a) charge transfer and (b) photophysical process of Fr-PM and A-PM. The application of A-PM in (c) security encryption, (d) ion detection, and (e) fingerprint identification[6]
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