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化学进展 2022, Vol. 34 Issue (11): 2361-2372 DOI: 10.7536/PC220311 前一篇   后一篇

• 综述 •

有机碳材料在光电催化系统中的作用

陈向娟, 王欢*(), 安伟佳, 刘利, 崔文权*()   

  1. 华北理工大学化学工程学院 河北省环境光电催化材料重点实验室 唐山 063210
  • 收稿日期:2022-03-11 修回日期:2022-05-22 出版日期:2022-11-24 发布日期:2022-06-25
  • 通讯作者: 王欢, 崔文权
  • 作者简介:

    王欢 研究方向能源与环境催化,主持河北省自然科学基金项目1项,河北省教育厅青年拔尖人才项目1项。发表学术论文20余篇,其中SCI、EI收录的论文17篇,ESI高被引论文2篇。

    崔文权 研究方向能源与环境催化,主持国家自然科学基金两项,河北省杰出青年基金项目一项。共发表SCI收录的论文100余篇,其中,TOP期刊论文25篇,8篇入选ESI前1%高被引论文,个人H因子35。

  • 基金资助:
    河北省自然科学基金青年基金项目(B2020209065); 河北省高等学校科学技术研究项目(BJK2022013); 河北省自然科学基金重点项目(B2020209017)
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Study on Photoelectrocatalysis of Organic Carbon Materials

Xiangjuan Chen, Huan Wang(), Weijia An, Li Liu, Wenquan Cui()   

  1. Hebei Provincial Key Laboratory of Environmental Photocatalytic Materials,College of Chemical Engineering, North China University of Science and Technology,Tangshan 063210, China
  • Received:2022-03-11 Revised:2022-05-22 Online:2022-11-24 Published:2022-06-25
  • Contact: Huan Wang, Wenquan Cui
  • Supported by:
    Youth Program of Natural Science of Hebei Province(B2020209065); Science and Technology Project of Hebei Education Department(BJK2022013); Key Program of Natural Science of Hebei Province(B2020209017)

有机碳材料因电荷传导效率高、结构可调、无污染等特点被广泛应用于光电催化领域。将含有机碳材料的催化剂作为电极材料已成为光电催化领域的研究热点之一。本文介绍了几种常见的有机碳材料的结构、特点、制备方法及其研究方向,并将含有机碳材料的电极进行分类。主要总结并论述了有机碳材料在光电催化系统中的五种作用:(1)作为催化剂;(2)作为光敏剂(3)作为电子介质;(4)作为催化剂载体;(5)作为光电极的稳定剂,最后阐述了有机碳材料在光电催化系统中的研究现状及难点问题。

关键词： 有机碳材料, 光电催化, 光电极

Organic carbon materials are widely used in the field of photoelectrocatalysis because of their high charge conduction efficiency, adjustable structure and no pollution. The catalyst containing organic carbon as electrode material has become one of the research hotspots in the field of photoelectrocatalysis. The structure and characteristics of several common organic carbon materials are introduced in this paper. These preparation methods and research direction of photoelectrocatalysis are also elaborated. And the electrodes containing organic carbon were divided into three categories. Five functions of organic carbon materials in photoelectric catalytic system are summarized and discussed: (1) act as catalyst; (2) act as photosensitizer; (3) act as electronic medium; (4) act as carrier; (5) act as photoelectrode stabilizer. In the end the research status and difficulties of organic carbon materials in photoelectrocatalytic system are also described in this paper.

Contents

1 Introduction

2 Common carbon-based compounds

2.1 C-Dots

2.2 G-C3N4

2.3 Graphene

2.4 Metal-organic skeleton

2.5 Other organic carbon materials

3 Carbon-based compound electrode material

3.1 Thin film type photoelectrode

3.2 Array type photoelectrode

3.3 Gel type photoelectrode

4 The role of organic carbon materials in photocatalysis

4.1 Act as catalyst

4.2 Act as photosensitizer

4.3 Act as electronic medium

4.4 Act as carrier

4.5 Act as stabilizer

5 Conclusion and outlook

Key words: organic carbon material, photoelectrocatalysis, photoelectrode
()
图1 (a) CDs的分类以及聚合物点碳核的结构[8]; (b) TiO2/Ti和CDs-TiO2/Ti的光电流响应[9]; (c) g-C3N4分子结构图;(d) 石墨烯分子结构图; (e) UiO系列MOF分子结构图; (f) 常见的COF分子结构图
Fig. 1 (a) Classification of CDs and the structures of carbon core of CPDs[8], Copyright 2019, Wiley; (b) Photocurrent responses of TiO2/Ti and CDs-TiO2/Ti[9], Copyright 2019, Elsevier; (c) The molecular structure diagram of g-C3N4; (d) The molecular structure diagram of GO; (e) The molecular structure diagram of UiO Metal-Organic Frameworks; (f) The molecular structure diagram of common COF
图2 光电催化降解有机物原理示意图[48]
Fig. 2 Schematic diagram of photocatalytic degradation of organic compounds[48], Copyright 2021, Elsevier
图3 C-Co-Pi/ Fe2O3电荷分离与转移机理[72]
Fig. 3 Charge separation and transfer mechanism in the C-Co-Pi/Fe2O3 photoanode[72]. Copyright 2018, Elsevier
表1 近年来碳材料在碳基化合物中作为电子介质的研究
Table 1 Recent studies on the use of carbon materials as electron mediators in carbon-based compounds
Organic carbon
composite photoelectrode		 The electrode type Application Organic carbon material effect
CDs/TiO2/g-C3N4[78] Thin film Degradation g-C3N4 constructed z-type heterojunction with TiO2, and CDs extended carrier life and enhanced charge separation efficiency.
N-CDs/TiO2[77] Thin film Oxygen production Broaden the range of light absorption and improve the efficiency of charge separation.
CDs/SiNWs@Co3O4[79] Array Oxygen production As electron acceptor, extend carrier life and improve semiconductor stability.
MOF/BiVO4[58] Thin film Oxygen production Conduction hole, effectively avoid photogenerated electrons and hole compound efficiency
CDs/Au/TiO2[71] Array Oxygen production Increase the amount and rate of electron separation.
CDs/BiVO4/g-C3N4[22] Thin film Hydrogen production As an electron donor, the density of semiconductor electron cloud is increased and enhance the reduction ability is enhanced.
CDs/Cu-In-Zn-S/MoS2[11] Thin film Hydrogen production Act as electron acceptor, temporarily store electrons, extend carrier life.
CNT /TiO2[80] Thin film Degradation Carbon nanotubes significantly reduce the charge transfer resistance and increase the anodic photocurrent response of the film.
FeNi-MOF/TiO2[81] Array Oxygen production Improve the separation rate of photogenerated electrons and holes.
CNT/Ag3PO4[82] Thin film Degradation MWCNTs were used as electron traps to effectively separate photocarriers.
CDs/(Co-Pi)/Fe2O3[72] Thin film Oxygen production The charge separation and charge transfer in Co-Pi/Fe2O3 photoanode were promoted by using CQDs as charge bridge to conduct interfacial electrons.
GO /Bi2WO6[30] Thin film Degradation The conjugation of graphene structure and the hybridization between Bi2WO6 and rGO can promote the migration of interfacial charge carriers and effectively improve the photogenerated charge separation and photocatalytic quantum efficiency.
GO/CdS[83] Thin film Degradation The synergistic effect of enhanced light absorption and high electron conductivity of graphene sheets contributes to charge separation and extends the lifetime of photogenerated electron-hole pairs by reducing the recombination rate.
GO/TiO2/Cu2O[84] Thin film Degradation Charge transfer channel.
GO/CeO2/TiO2[85] Array Degradation It can improve the utilization efficiency of visible part of sunlight and effectively reduce the recombination rate of photogenerated electrons and holes.
CNT/TiO2[86] Thin film Degradation As the channel of electron transmission, the separation efficiency of electron and hole is enhanced.
CNT/CdS[87] Thin film Hydrogen production As a channel of electronic transmission between CdS and stainless steel substrate, fast transmission to the cathode to produce hydrogen.
GO/α-Fe2O3[88] Thin film Oxygen production Graphene can extract photoenergetic electrons from α -Fe2O3 and inhibit the charge recombination of electron-hole pairs, thus enhancing the photocurrent response.
γ-GO/TiO2[74] Array Degradation Heterojunction is constructed to improve charge separation efficiency.
P3HT/TiO2[89] Array Degradation Heterojunction was constructed to effectively improve the separation efficiency of photogenerated electrons and holes
CNT/MoS2-MoO3[90] Thin film Hydrogen production The introduction of multi-walled carbon nanotubes (MWCNTs) and the formation of heterostructures can improve the charge transfer rate and the ability of electron and hole separation.
g-C3N4/TiO2[73] Array Degradation Heterojunction is constructed to improve charge separation efficiency.
图4 (a) 负载于不锈钢网上的石墨烯水凝胶;(b) 石墨烯气凝胶的电子显微镜图
Fig. 4 (a) Graphene hydrogel supported on stainless steel mesh; (b) electron microscopic view of graphene aerogel
图5 碳气凝胶作为固碳基质还原CO2机理图[98]
Fig. 5 Mechanism diagram of carbon aerogel as carbon sequestration matrix for CO2 reduction[98]. Copyright 2016, The Royal Society of Chemistry
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