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化学进展 2020, Vol. 32 Issue (12): 1990-2003 DOI: 10.7536/PC200403 前一篇   后一篇

• 综述 •

催化还原降解Cr(Ⅵ)

王洪红1, 雷文1, 李孝建1, 黄仲1, 贾全利2, 张海军1,**()   

  1. 1 武汉科技大学省部共建耐火材料与冶金国家重点实验室 武汉 430081
    2 郑州大学河南省高温功能材料重点实验室 郑州 450052
  • 收稿日期:2020-04-03 修回日期:2020-07-09 出版日期:2021-10-20 发布日期:2020-10-20
  • 通讯作者: 张海军
  • 作者简介:
    ** Corresponding author e-mail:
  • 基金资助:
    国家自然科学基金面上项目(No. 51872210); 国家自然科学基金面上项目(51672194); 湖北省自然科学基金创新群体项目(No. 2017CFA004); 湖北省教育厅高等学校优秀中青年科技创新团队计划(No. T201602)
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Catalytic Reductive Degradation of Cr(Ⅵ)

Honghong Wang1, Wen Lei1, Xiaojian Li1, Zhong Huang1, Quanli Jia2, Haijun Zhang1,**()   

  1. 1 The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China
    2 Henan Key Laboratory of High Temperature Functional Ceramics, Zhengzhou University, Zhengzhou 450052, China
  • Received:2020-04-03 Revised:2020-07-09 Online:2021-10-20 Published:2020-10-20
  • Contact: Haijun Zhang
  • Supported by:
    the National Natural Science Foundation of China(No. 51872210); the National Natural Science Foundation of China(51672194); the Key Program of Natural Science Foundation of Hubei Province, China(No. 2017CFA004); and the Program for Innovative Teams of Outstanding Young and Middle-Aged Researchers in the Higher Education Institutions of Hubei Province(No. T201602)

工业化的快速发展导致含有六价铬(Cr(Ⅵ))的废水排放量日益增加,Cr(Ⅵ)的毒性和高流动性造成极大的环境污染问题。将Cr(Ⅵ)还原成低毒性和低流动性三价铬(Cr(Ⅲ))是当前的有效处理方式之一。与传统方法相比,利用太阳光、电和微波等驱动氧化还原反应进行Cr(Ⅵ)降解,无催化剂消耗,还原剂用量少,且不会造成二次污染和有限资源损耗,成为处理Cr(Ⅵ)污染的有效解决方案。基于此,本文综述了光催化剂、电催化剂及微波催化剂等在还原Cr(Ⅵ)领域的应用现状,在总结分析前人研究成果的基础上,对今后Cr(Ⅵ) 催化还原技术的研究方向和重点进行了展望。

关键词： Cr(Ⅵ), 催化还原, 光催化剂, 电催化剂, 光电催化剂, 微波催化剂

With the rapid development of industrialization, the discharge of wastewater containing hexavalent chromium(Cr(Ⅵ)) is increasing day by day. The toxicity and high mobility of Cr(Ⅵ) cause great environmental pollution. Reducing Cr(Ⅵ) to trivalent chromium(Cr(Ⅲ)) with low toxicity and low fluidity is one of the current effective treatment methods. Compared with the traditional methods, the catalytic reduction of Cr(Ⅵ) driven by sunlight, electricity and microwave, has the advantages of no catalyst consumption, less reductant consumption, no secondary pollution and limited resource loss, and has become an effective solution to deal with Cr(Ⅵ) pollution. Based on this, the present paper reviews the application of photocatalyst, electrocatalyst and microwave catalyst for Cr(Ⅵ) reduction. Based on the summary and analysis of previous research results, the research direction and key points of Cr(Ⅵ) catalytic reduction technology in the future are prospected.

Contents

1 Introduction

2 Photocatalyst

2.1 Morphology control

2.2 Surface modification

2.3 Ion doping

2.4 Introduction of defect

2.5 Composite material

3 Electrocatalyst

3.1 Electrochemical catalyst

3.2 Piezoelectric catalyst

4 Photo-electrocatalyst

5 Microwave catalyst

5.1 Microwave enhanced catalyst

5.2 Microwave induced catalyst

6 Conclusion and outlook

Key words: Cr(Ⅵ), catalytic reduction, photocatalyst, electrocatalyst, photo-electrocatalyst, microwave catalyst
()
图1 光催化过程的机理示意图[51]
Fig.1 Schematic illustration of mechanism of a photocatalytic process[51]
图2 TiO 2纳米结构: (a) P25纳米颗粒[57];(b) 纳米片[58];(c) 纳米线[53];(d) 纳米花[60]
Fig.2 TiO 2 nanostructures: (a) P25 nanoparticles[57];(b) nanosheets[58];(c) nanowires[53];(d) nanoflowers[60]
图3 TiO 2-Au/Pt光催化还原Cr(Ⅵ)示意图[32]
Fig.3 Photocatalytic reduction of Cr(Ⅵ) by TiO 2-Au/Pt[32]
图4 (a) Me xS y/MIL-125(Ti)[54]及(b) MIL-53(Fe)/CQDs[65]对Cr(Ⅵ)的光催化还原机理
Fig.4 The photocatalytic reduction mechanism of Cr(VI) by (a) Me xS y/MIL-125(Ti)[54] and(b) MIL-53(Fe)/CQDs[65]
图5 (a)$TiO_{2}-HNO_{3}$[73]和(b) Fe-THWO 3薄膜光催化还原Cr(Ⅵ)示意图[74]
Fig.5 The mechanism of photocatalytic reduction of Cr(Ⅵ) by (a) $TiO_{2}-HNO_{3}$[73] and (b) Fe-THWO3[74]
图6 RP 0.01TiO 2的制备及光催化还原Cr(Ⅵ)的机理示意图[77]
Fig.6 Preparation of RP 0.01TiO 2 and its mechanism of photocatalytic reduction of Cr(Ⅵ)[77]
图7 g-C 3N 4/GO/BiFeO 3异质结光催化体系的能带图[52]
Fig.7 The energy band diagram of the photocatalytic-system of g-C 3N 4/GO/BiFeO 3 heterostructures[52]
图8 C-SO 3H/CN-TiO 2的制备及光催化还原Cr(Ⅵ)的机理示意图[80]
Fig.8 Preparation of C-SO 3H/CN-TiO 2 and its mechanism of photocatalytic reduction of Cr(Ⅵ)[80]
图9 PGAs电催化还原Cr(Ⅵ)及氧化BPA的机理[21]
Fig.9 Mechanism of electrocatalytic reduction of Cr(Ⅵ) and oxidation of BPA by PGAs[21]
图10 MFC中FeS@rGO修饰的阴极还原Cr(Ⅵ)的机理[18]
Fig.10 Mechanism of Cr(Ⅵ) reduction at FeS@rGO decorated cathode in MFC[18]
图11 Au/BiVO 4压电催化去除Cr(Ⅵ)和4-CP的机理[83]
Fig.11 Mechanism of piezo-catalytic removal of Cr(Ⅵ) and 4-CP by Au/BiVO4[83]
图12 Ni foam@ZnO@ZnFe-LDH光电催化去除Cr(Ⅵ)和酸性红1[89].
Fig.12 The photoelectrocatalytic removal of Cr(Ⅵ) and acid red 1 by Ni foam@ZnO@ZnFe-LDH[89]
图13 MW/MoS 2-MnFe 2O 4体系中Cr(Ⅵ)的还原机理[22]
Fig.13 Mechanism of Cr(Ⅵ) reduction in MW/MoS 2-MnFe 2O 4 system[22]
图14 MW/Fe 3O 4@PANI体系中Cr(Ⅵ)的还原机理[19]
Fig.14 Mechanism of Cr(Ⅵ) reduction in MW/Fe 3O 4@PANI system[19]
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摘要

催化还原降解Cr(Ⅵ)