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化学进展 2020, Vol. 32 Issue (9): 1307-1315 DOI: 10.7536/PC200222 前一篇   后一篇

• 综述 •

玄武岩纤维增强树脂基复合材料界面改性策略

贾航1, 乔越1, 张玉1, 孟庆鑫1, 刘程1,**(), 蹇锡高1   

  1. 1. 大连理工大学 化工学院高分子材料系 大连 116024
  • 收稿日期:2020-02-24 修回日期:2020-05-19 出版日期:2020-09-24 发布日期:2020-06-30
  • 通讯作者: 刘程
  • 作者简介:
    ** Corresponding author e-mail:
  • 基金资助:
    *国家自然科学基金项目(91860204); 大连市科技创新基金项目(2018J12GX055)

Interface Modification Strategy of Basalt Fiber Reinforced Resin Matrix Composites

Hang Jia1, Yue Qiao1, Yu Zhang1, Qingxin Meng1, Cheng Liu1,**(), Xigao Jian1   

  1. 1. Department of Polymer Science and Materials, School of Chemical Engineering, Dalian University of Technology,Dalian 116024, China
  • Received:2020-02-24 Revised:2020-05-19 Online:2020-09-24 Published:2020-06-30
  • Contact: Cheng Liu
  • Supported by:
    the National Natural Science Foundation of China(91860204); the Dalian Science and Technology Innovation Fund Project(2018J12GX055)

近年来,工业界和学术界都将注意力聚焦在可持续天然纤维复合材料的开发上。玄武岩纤维具有高强度、高模量、耐高温、耐酸碱、隔热隔音、热振稳定性好、介电性能优异、绿色无污染及成本低等优点,玄武岩纤维增强树脂基复合材料凭借其优异的机械性能和可设计性被广泛地应用于飞行器、汽车、船舶、建筑、石油化工管道及风力发电机叶片等领域。然而,玄武岩纤维与聚合物基底间差的相容性导致玄武岩纤维增强树脂基复合材料存在诸多缺陷和不足。其中,界面强度不够高、界面相易被破坏的问题成为制约玄武岩纤维增强树脂基复合材料发展的瓶颈之一,因此许多玄武岩纤维增强树脂基复合材料研究工作集中在提高其界面结合能力上。本文介绍了玄武岩纤维增强树脂基复合材料的主要研究方向,以及几种常见的复合材料界面作用机理,并综述了近年来国内外关于玄武岩纤维增强树脂基复合材料界面增强改性方面的研究工作。

In recent years, both industry and academia have been focusing their attention toward the development of sustainable natural fiber composites. Basalt fiber(BF) is a kind of green, environmentally friendly natural high-performance inorganic fiber, which has the advantages of high strength, high modulus, high temperature resistance, acid and alkali resistance, heat and sound insulation, good thermal vibration stability, excellent dielectric properties, and low cost. And the basalt fiber reinforced polymer(BFRP) composites are widely used in aircraft, automobiles, ships, construction, petrochemical pipelines, and wind turbine blades, due to their excellent mechanical properties and designability. However, the poor compatibility between BF and polymer matrix leads to many defects and deficiencies in BFRP composites, and the insufficient interface strength and the fragile interface phase have been the bottlenecks restricting the development of basalt fiber reinforced resin-based composites. Therefore, various physical or chemical treatment methods have been developed to treat BF surface by investigators in order to enhance the interface interaction between BF and resins, thus improving the interface binding capacity of BFRP composites. The main research directions about BFRP composites and several common mechanisms of composite interface interaction are introduced. Furthermore, the research work on the interface reinforcement of BFRP composites in recent years is reviewed in detail. Finally, current problems and future perspectives are discussed.

Contents

1 Introduction

2 Interface mechanism of resin-based composites

2.1 Wettability theory

2.2 Chemical bond theory

2.3 Mechanical bonding theory

3 Research progress of BFRPC interface modification

3.1 Acid-base treatment

3.2 Silane coupling agent treatment

3.3 Nanoparticle modification

3.4 Plasma treatment

3.5 CVD modification

4 Conclusion and outlook

()
表1 玄武岩纤维、碳纤、E玻纤性能对比[5,7,13~15]
Table 1 Performance comparison of basalt fiber, carbon fiber and E-glass fiber[5,7,13~15]
图1 硅烷偶联剂作用机理图
Fig.1 Coupling mechanisms of common silane coupling agent
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