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化学进展 2020, Vol. 32 Issue (2/3): 179-189 DOI: 10.7536/PC190802 前一篇   后一篇

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pH敏感性智能水凝胶的设计及其应用

于秋灵1, 李政1,3,**(), 窦春妍1, 赵义平2, 巩继贤1,**(), 张健飞1,4   

  1. 1. 天津工业大学纺织科学与工程学院 先进纺织复合材料教育部重点实验室 天津 300387
    2. 天津工业大学材料科学与工程学院 天津 300387
    3. 宁夏中宁枸杞产业创新研究院有限公司 中宁 755199
    4. 山东省生态纺织协同创新中心 青岛 266071
  • 收稿日期:2019-08-02 出版日期:2020-02-15 发布日期:2019-12-19
  • 通讯作者: 李政, 巩继贤
  • 基金资助:
    国家重点研发计划(2017YFB0309800); 国家重点研发计划(2016YFC0400503-02); 新疆自治区重大专项(2016A03006-3); 天津自然科学基金项目(18JCYBJC89600); 中国纺织工业联合会科技指导性项目(2017011); 宁夏中宁枸杞产业创新研究院一般项目(ZNGQCX-B-2019006)

Design and Application of pH Sensitive and Intelligent Hydrogels

Qiuling Yu1, Zheng Li1,3,**(), Chunyan Dou1, Yiping Zhao2, Jixian Gong1,**(), Jianfei Zhang1,4   

  1. 1. Key Laboratory of Advanced Textile Composites of Ministry of Education, School of Textiles Science and Engineering, Tiangong University, Tianjin 300387, China
    2. School of Material Science and Engineering, Tiangong University, Tianjin 300387, China
    3. Innovation Research Institute of Wolfberry Industry Co. LTD, Zhongning 755199, China
    4. Collaborative Innovation Center for Eco-Textiles of Shandong Province, Qingdao 266071, China
  • Received:2019-08-02 Online:2020-02-15 Published:2019-12-19
  • Contact: Zheng Li, Jixian Gong
  • About author:
    ** e-mail: (Zheng Li);
    (Jixian Gong)
  • Supported by:
    National Key Research and Development Project Foundation of China(2017YFB0309800); National Key Research and Development Project Foundation of China(2016YFC0400503-02); Xinjiang Autonomous Region Major Significant Project Foundation(2016A03006-3); Tianjin Natural Science Foundation(18JCYBJC89600); Science and Technology Guidance Project of China National Textile and Apparel Council(2017011); Innovation Research Institute of Wolfberry Industry Co. LTD(ZNGQCX-B-2019006)

水凝胶是一种交联的三维网状亲水性聚合物材料,具有与生物组织相似的特点并且能够吸收大量的水分。作为智能水凝胶的一种,pH敏感性水凝胶因其结构中含有大量碱性或酸性基团从而具有一定的pH敏感性。凭借这些特性,近年来pH敏感性水凝胶在生物、医学、物理、环境、纺织等众多研究领域备受关注。本文围绕pH敏感性水凝胶的响应机制、分类以及应用三个方面进行综述。在响应机制上,本文从响应过程、影响因素和溶胀扩散模型三方面进行综述;在分类上,根据水凝胶敏感性的不同分为溶胀-收缩类和溶胶-凝胶类两类,并进一步根据pH作用范围的不同将溶胀-收缩类细分为阴离子类、阳离子类以及两性离子类,溶胀-收缩类细分为硼酸酯类、酰腙类以及亚胺类;在应用研究上,本文总结了其在医学、环境、生物、智能检测、功能材料等热门领域的研究情况。最后,对pH敏感性水凝胶的未来的发展方向进行了展望。

As a cross-linked three-dimensional network of hydrophilic polymer materials, hydrogels have similar characteristics to biological tissues and can absorb a large amount of water. As a kind of smart hydrogel, pH-sensitive hydrogel has a certain amount of pH sensitivity due to its structure containing a large number of basic or acidic groups. With these properties, such hydrogels have attracted much attention of researchers in many research fields such as biology, medicine, physics, environment and textiles in recent years. This review mainly focuses on three aspects: the response mechanism, classification and application of pH-sensitive hydrogels. Firstly, the response mechanism of pH sensitivity is reviewed from three aspects: response process, influencing factors and swelling-diffusion model. According to the pH sensitivity of such hydrogel, it can be divided into two types: swelling-shrinking type and sol-gel type. Further, the swelling-shrinking type can be divided into three types: anionic, cationic and amphoteric ionic according to the pH working range of such hydrogel, and the sol-gel type can be divided into borates, hydrazine and imines. In the field of applied research, this article summarizes the research status of such hydrogels in some popular fields such as medicine, environment, biology, intelligent monitoring and functional materials. Finally, the future of such hydrogel is prospected.

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图1 pH敏感性水凝胶随溶液pH值体积变化规律[17]
Fig.1 pH sensitive hydrogels volume change with the pH of solution[17]
图2 酶解木质素接枝聚丙烯酸水凝胶合成[40]
Fig.2 Hydrogel synthesis of ligin-grafted polyacrylate by enzymatic hydrolysis[40]
图3 LC/PAA聚合物网络随pH值改变的结构变化示意图[45]
Fig.3 Schematic diagram of the structure change of LC/PAA polymer network with pH value change[45]
图4 pH诱导的Dns-PAAM水凝胶形状记忆照片[53]。 (a)pH=2.0的原始形状,(b)pH=5.0时的临时形状,(c~l)在pH=2.0下在10 min内从临时形状转变为原始形状
Fig.4 Photographs that demonstrate the macroscopic pH-induced shape memory behaviour of Dns-PAAM hydrogel[53]. (a) Original shape at pH=2.0. (b) Temporary shape at pH=5.0. (c~l) Transition from temporary shape to original shape at pH=2.0 in 10 min.
图5 GO/CS 水凝胶网络结构示意图[56]
Fig.5 Schematic diagram of GO/CS hydrogel network structure[56]
图6 PAAc/PDMAEMA水凝胶制备过程[58] 2-(N-morpholino) ethyl methacrylate(MEMA):2-甲基-2-丙烯酸2-(4-吗啉基)乙基酯;ammonium persulfate(APS):过硫酸铵;PEC水凝胶:PAAc/PDMAEMA水凝胶
Fig.6 Preparation process of PAAc/PDMAEMA hydrogel[58]
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