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化学进展 2019, Vol. 31 Issue (11): 1550-1559 DOI: 10.7536/PC190731 前一篇   后一篇

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光响应离子液体的结构与性能调控

李志勇, 冯莹, 王慧勇, 袁晓晴, 赵玉灵, 王键吉**()   

  1. 河南师范大学化学化工学院 绿色化学介质与反应教育部重点实验室 新乡 453007
  • 收稿日期:2019-07-25 出版日期:2019-11-15 发布日期:2019-10-23
  • 通讯作者: 王键吉
  • 基金资助:
    国家自然科学基金项目(21803017); 国家自然科学基金项目(21673068); 国家自然科学基金项目(U1704251); 国家重点研发计划(2017YFA0403101); 河南省高校重点科研项目(19A150027)
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Structure and Performance Modulation of Photo-Responsive Ionic Liquids

Zhiyong Li, Ying Feng, Huiyong Wang, Xiaoqing Yuan, Yuling Zhao, Jianji Wang**()   

  1. Key Laboratory of Green Chemical Media and Reactions of Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, China
  • Received:2019-07-25 Online:2019-11-15 Published:2019-10-23
  • Contact: Jianji Wang
  • About author:
    ** E-mail:
  • Supported by:
    National Natural Science Foundation of China(21803017); National Natural Science Foundation of China(21673068); National Natural Science Foundation of China(U1704251); National Key Research and Development Program of China(2017YFA0403101); S&T Research Foundation of Education Department of Henan Province(19A150027)

光响应离子液体是一类兼具光刺激响应和离子液体双重特性的功能材料。在紫外/可见光照下,这类“智能型”离子液体的结构会发生变化,从而引起物理化学性质和相关体系性能的显著变化,以满足某些特定过程的需要。光刺激具有信号稳定、刺激部位精准、可快速切换、刺激过程不引入其他物质等优点,在刺激响应离子液体的结构与性质调控中具有独特的优势。本文以光响应离子液体的结构-性质-性能关系为主线,对光响应离子液体的光致异构化、物理化学性质调制、簇集行为调控、光致相转移及离子液体参与构筑的光响应乳液相行为调控等方面的研究进展进行了评述,分析了该领域研究中存在的主要问题,并对其发展前景进行了展望。

关键词： 离子液体, 光响应, 光致异构, 性能调控

Light-responsive ionic liquids(ILs) are a class of functional materials that combine the characteristics of light stimuli responsive materials and ILs. Upon UV/vis light irradiation, the structure, property and performance of these “smart” ILs can be significantly changed, which are expected to have important applications in many practical processes. Light trigger is of great importance because of its superiority, such as stable optical signal, accurate stimulation spot, and ability to be rapidly switched in a clean and non-invasive manner. In this work, the photo-isomerization of ILs and light modulation of IL properties, aggregation behavior of ILs, phase transfer of ILs, and phase behavior of emulsions involving IL are critically reviewed based on the structure-property-performance relationship of photo-responsive ILs. Meanwhile, the main problems in this field have been analyzed, and the future development is discussed.

Key words: ionic liquids, photo-responsive, photo-isomerization, performance modulation
()
图1 常见光响应官能团的结构及其异构化
Fig. 1 Chemical structure and isomerization of the commonly used photo-responsive groups
图2 25.0 ℃下光照射时间对[C4AzoC2DMEA]Br紫外可见吸收光谱的影响[31]:a, 初始状态; b, 2 min; c, 4 min; d, 6 min; e, 8 min; f, 10 min; g, 15 min; h, 20 min; i, 40 min; j, 60 min
Fig. 2 Effect of irradiation time on UV-vis spectrum of aqueous [C4AzoC2DMEA]Br at 25.0 ℃[31]: a, initial state; b, 2 min; c, 4 min; d, 6 min; e, 8 min; f, 10 min; g, 15 min; h, 20 min; i, 40 min; j, 60 min. Copyright 2018, PCCP Owner Societies, The Royal Society of Chemistry.
图3 偶氮苯离子液体的化学结构[31, 36]
Fig. 3 Chemical structure of the azobenzene-based ionic liquids[31, 36]. Copyright 2018, PCCP Owner Societies, The Royal Society of Chemistry.
图4 肉桂酸酯类离子液体的结构[41]
Fig. 4 Chemical structure of cinnamate-based ionic liquids[41]
图5 疏水性偶氮苯类离子液体的化学结构[39]
Fig. 5 Chemical structure of hydrophobic azobenzene-based ionic liquids[39]
表1 紫外光照前后光响应离子液体的临界簇集浓度[34,35,36]
Table 1 CAC values of light responsive ionic liquids before and after UV irradiation[34,35,36]
Ionic liquid CAC / mol·kg-1
before UV after UV
[C14mimAzo]Br 3.2×10-5 1.0×10-4
[C4AzoC6TMA][TfO] 3.7×10-4 5.2×10-4
[ChoC10Azo]Br 1.1×10-4 1.3×10-4
表2 25.0 ℃紫外光照前后离子液体在水溶液中的ΔGm0和CAC值[31]
Table 2 ΔGm0 and CAC values of the ionic liquids in aqueous solutions at 25.0 ℃ before and after UV irradiation[31]
IL CAC / mol·kg-1 ΔGm0/kJ·mol-1
before UV after UV before UV after UV
[C4AzoC2MIM]Br 1.9×10-3 — -44.6 —
[C4AzoC2TMA]Br 2.6×10-3 — -44.4 —
[C4AzoC2DMEA]Br 2.3×10-3 — -44.3 —
[C4AzoC4DMEA]Br 1.2×10-3 7.6×10-3 -47.9 -43.3
[C4AzoC6DMEA]Br 8.0×10-4 3.7×10-3 -48.9 -44.5
图6 光致[C16DMA-Azo]Br与α-环糊精修饰的纳米金形成的复合物在水相和甲苯相之间的可逆转移[57]
Fig. 6 Reversible phase transfer of α-CD-capped AuNPs by azo-ligands between water and toluene phases[57]. Copyright 2014, American Chemical Society.
图7 光致Azo-SEP在甲苯相和水相间的可逆转移[56]
Fig. 7 The reversible transfer of Azo-SEP between toluene and water phase induced by light irradiation[56]. Copyright 2013, American Chemical Society.
图8 偶氮苯离子液体在正辛醇和水相间的可逆转移[38]
Fig. 8 The reversible phase transfer of azobenzene-based ionic liquids between n-octanol and water[38]
图9 乳状液的光致破乳[59]
Fig. 9 Demulsification under light irradiation[59]. Copyright 2016, American Chemical Society.
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