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化学进展 2019, Vol. 31 Issue (12): 1729-1736 DOI: 10.7536/PC190321 前一篇   后一篇

• •

新型2D MXenes 纳米材料在光催化领域的应用

赵文军1, 秦疆洲1, 尹志凡2, 胡霞1,**(), 刘宝军1,3,**()   

  1. 1. 贵州大学资源与环境工程学院　贵阳 550025
    2. 大连理工大学环境学院　大连 116024
    3. 香港理工大学电机工程系 香港 999077
  • 收稿日期:2019-03-19 出版日期:2019-12-15 发布日期:2019-08-01
  • 通讯作者: 胡霞, 刘宝军
  • 作者简介:
    † These authors contributed equally to this work.
  • 基金资助:
    国家自然科学基金项目(21703044)
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2D MXenes for Photocatalysis*

Wenjun Zhao1, Jiangzhou Qin1, Zhifan Yin2, Xia Hu1,**(), Baojun Liu1,3,**()   

  1. 1. College of Resource and Environmental Engineering, Guizhou University, Guiyang 550025, China
    2. School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, China
    3. Department of Electrical Engineering, The Hong Kong Polytechnic University, Hong Kong 999077, China
  • Received:2019-03-19 Online:2019-12-15 Published:2019-08-01
  • Contact: Xia Hu, Baojun Liu
  • About author:
    ** E-mail: (Xia Hu);
    (Baojun Liu)
  • Supported by:
    National Natural Science Foundation of China(21703044)

MXenes是一类新型的二维(2D)过渡金属碳化物、氮化物或碳氮化物的总称,在物理、化学、材料科学和纳米技术领域产生了巨大的影响。MXenes材料在制备过程中,表面会生成羟基、氟等基团,表面具有亲水性和良好的可见光响应,加上其自身具有比表面积大、活性位点丰富等优点,使其成为一种新兴的光催化材料。本文主要对MXenes及其复合材料在光催化领域的最新研究进展进行总结,简要介绍了MXenes材料的合成方法及理化性质,着重介绍了MXenes及其复合材料作为光催化剂的复合方式,光催化机理等方面的内容,并逐一列举其在光催化氧化与还原反应中的重要作用,最后对MXenes及其复合物的进一步研究提出建议和展望。

关键词： MXenes, 二维材料, 复合材料, 光催化机理

MXene, the latest 2D transition metal carbides/carbonitrides/nitrides, has exerted a great influence in the fields of physics, chemistry, material science and nanotechnology. It is an important and increasingly popular category for photocatalysis because of the advantages including hydrophilia, visible-light response, high specific surface area and abundant active sites with —OH or —F terminal during preparation. This review provides an overview of the latest progress of MXenes and its composites in the field of photocatalysis research. Firstly, we give a brief introduction of the synthesis, structure and fundamental properties, methodologies of MXenes and emphasize its composites and the corresponding photocatalysis mechanisms. Then we list the important roles in photocatalytic oxidation and reduction it plays, and forecast the development and potential applications of MXenes.

Key words: MXenes, 2D materials, Composites, Photocatalytic mechanism
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表1 部分MAX相制备MXenes的实验条件
Table 1 Process conditions for MXenes synthesis from MAX phases
Type MXene Precursor Etchant Concentration Time(h) T(℃) ref
M2X Ti2CTx Ti2AlC HF 10 wt% 10 RT 13
Ti2CTx Ti2AlC HF 50 wt% 19 RT 45
V2CTx V2AlC HF 50 wt% 90 RT 14
Mo2CTx Mo2Ga2C HF 25 wt% 160 55 15
HCl-LiF 9 M HCl-15 mol LiF 72 35 18
M3X2 Ti3C2Tx Ti3AlC2 HF 10, 25, 50 wt% 24 RT 16
Mo2TiC2Tx Mo2TiAlC2 HCl-LiF 6 M HCl-5 mol LiF 45 40 17
HF 9 M HCl-5 mol LiF 24 35 19
HF-HCl 6 M HCl-7.5 mol LiF 24 35 20
50 wt% 48 55 44
10 wt% 40 40 20
图1 MXenes的结构及侵蚀制备过程
Fig. 1 Illustration of the MXenes configurations and schematic depicting the synthesis process of MXene
图2 Ti3C2Tx对Cr(Ⅵ)去除机理[40]
Fig. 2 Illustration of the Removal Mechanism of Cr(Ⅵ) by the Ti3C2Tx nanosheets[34]
图3 (a) 由交换电流与吉布斯自由能构成析氢反应的火山图[36];(b)CdS/Ti3C2 体系中可见光照射下电荷分离与迁移机理[8]
Fig. 3 (a) Volcano curve of exchange current(i0) as a function of the average Gibbs free energy of hydrogen adsorption(ΔGH*a)[36];(b) The charge separation and transfer in the CdS/Ti3C2 system under visible-light irradiation[8]
图4 (a, b)不同浓度HF侵蚀下具有缺陷的单层Ti3C2Tx扫描透射电子显微镜[39];(c, d) TiO2/Ti3C2复合结构的SEM和TEM[40]
Fig. 4 (a, b) HAADF-STEM images from single-layer Ti3C2Tx MXene flakes prepared using etchants with different HF concentration[39];(c, d) SEM and TEM of TiO2/Ti3C2 composites[41]
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