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化学进展 2019, Vol. 31 Issue (5): 690-698 DOI: 10.7536/PC180928 前一篇   后一篇

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基于超分子聚合物的自修复材料

侯瑞, 李桂群, 张岩*(), 李明俊, 周桂明, 柴晓明   

  1. 山东非金属材料研究所 济南 250031
  • 收稿日期:2018-09-25 出版日期:2019-05-15 发布日期:2019-03-21
  • 通讯作者: 张岩
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Self-Healing Polymers Materials Based on Dynamic Supramolecular Motifs

Rui Hou, Guiqun Li, Yan Zhang*(), Mingjun Li, Guiming Zhou, Xiaoming Chai   

  1. Shandong Institude of Non-metallic Materials, Jinan 250031, China
  • Received:2018-09-25 Online:2019-05-15 Published:2019-03-21
  • Contact: Yan Zhang
  • About author:
    * E-mail:

材料的自修复功能对于材料应用具有重要的意义,如键组装/解组装常数、键的方向和链的弛豫时间等因素会影响自修复效率。根据提供修复功能的物质构成形式,可以分为外援型自修复材料和本征型自修复材料,其中本征型自修复材料是当前的热点方向,在本征型自修复材料中,超分子自修复材料以其独特的可逆性组装,以及在快速、可逆、多重响应方面的优势而成为研究重点。本文重点阐述了基于不同结合效应的超分子自修复聚合物的研究进展,并对今后的研究方向作了展望,认为材料的耐环境性能能否达标是未来能否获得应用的关键因素之一。

关键词： 超分子, 自修复材料, 聚合物

The self-healing function of materials has high application value in many fields. It is reported some factors impact the self-healing efficiency, such as the constants of bond disassemble/assemble, the direction of bonding, chain relaxation time. According to the materials’ properties, self-healing materials can be divided into extrinsic self-healing polymer materials and intrinsic self-healing polymer materials. The possibility to disassemble structurally dynamic polymers is the basic of intrinsic self-healing materials, and a Diels-Alder reaction is used to realize this idea. Within the intrinsic self-healing materials, supramolecular chemistry is highly attractive to achieve self-healing for the fast equilibrium state, bonding directionality, and sensitivity. The research of self-healing polymers materials based on dynamic supramolecular motifs is built on the work on hydrogen-bonded monomer units. In this paper, the research progress of supramolecular self-healing polymer is the center of attention. The design and synthesis of supramolecular are summarized, at the same time, the application of supramolecular materials is introduced. At the end of the paper, the future research direction and development trend are prospected. It is considered that whether the environmental resistance of self-healing polymers materials can reach the standard is the key to its future application.

Key words: supramolecular, self-healing materials, polymers
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图1 丙烯酸聚合物PBA-UPy结构原理示意图
Fig. 1 Structure and schematic diagram of PBA-UPy polymer
图2 自修复-力致变色聚合物示意图[38]
Fig. 2 Schematic diagram of self-healing polymer with force chromogenic performance[38]
图3 超分子聚氨酯弹性体分子结构及自修复效果图[46]
Fig. 3 Molecular structure and self-healing effect of supramolecular polyurethane elastomer[46]
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摘要

基于超分子聚合物的自修复材料