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化学进展 2019, Vol. 31 Issue (4): 561-570 DOI: 10.7536/PC180919 前一篇   后一篇

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硅藻土基吸附与光催化材料在水处理中的应用

何洪波1,2, 罗一旻2, 罗荘竹2,**(), 余长林3,4,**()   

  1. 1. 中山大学材料科学与工程学院 广州 510000
    2. 中山大学化学工程与技术学院 珠海 519000
    3. 广东石油化工学院环境科学与工程学院 广东省石油化工污染过程与控制重点实验室 茂名 525000
    4. 江西理工大学冶金与化学工程学院 赣州 341000
  • 收稿日期:2018-09-19 出版日期:2019-01-15 发布日期:2019-01-14
  • 通讯作者: 罗荘竹, 余长林
  • 作者简介:
  • 基金资助:
    国家自然科学基金项目(51575504); 国家自然科学基金项目(21567008); 江西省5511科技创新人才计划(20165BCB18014); 江西省主要学科学术带头人计划(20172BCB22018); 广东省扬帆计划资助
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Diatomite-Based Material as an Adsorbent or Photocatalyst for Water Treatment

Hongbo He1,2, Yimin Luo2, Zhuangzhu Luo2,**(), Changlin Yu3,4,**()   

  1. 1. School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou 510000, China
    2. School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai 519000, China
    3. Faculty of Environmental Science and Engineering, Key Laboratory of Petrochemical Pollution Process and Control, Guangdong Province, Guangdong University of Petrochemical Technology, Maoming 525000, China
    4. School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
  • Received:2018-09-19 Online:2019-01-15 Published:2019-01-14
  • Contact: Zhuangzhu Luo, Changlin Yu
  • About author:
    ** E-mail: (Zhuangzhu Luo)
    ** E-mail: (Changlin Yu)
  • Supported by:
    Fund:The work was supported by the National Natural Science Foundation of China(51575504); Fund:The work was supported by the National Natural Science Foundation of China(21567008); 5511 Talents in Scientific and Technological Innovation of Jiangxi Province(20165BCB18014); Academic and Technical Leaders of the Main Disciplines in Jiangxi Province(20172BCB22018); Guangdong Province of Yangfan Project.

硅藻土是一种由硅藻遗骸所形成的多孔材料,具有比表面积大、抗腐蚀性好和绿色无毒等优点。作为一种原料易得且价格低廉的吸附与催化载体材料,硅藻土在水处理方面表现出广泛的应用前景。天然硅藻土中含有不同比例的金属氧化物杂质,会降低硅藻土的孔隙率和影响其吸附及催化活性。因此,表面修饰和复合改性增强硅藻土吸附及催化性能是目前硅藻土材料应用于水处理方向的研究重点。本文从吸附和光催化原理出发,分析了不同表面修饰及复合改性方法对硅藻土结构与性能的影响,总结了硅藻土基材料在有机废水,富营养污水和重金属离子废水等污水处理方面的应用进展,并对硅藻土基吸附与光催化材料的发展和研究方向进行分析和展望。

关键词： 硅藻土基材料, 吸附, 光催化, 水处理

Diatomite is a porous material formed by the remains of diatom, which has the advantages of large specific surface area, good corrosion resistance, green and innocuity. Diatomite-based materials as adsorbent or photocatalyst show wide application prospects in sewage treatment because of easily available raw material and low in price. However, most of the natural diatomite contains some metal oxide impurities, which may reduce the porosity and affect the adsorption and photocatalysis performance of diatomite. Therefore, the majority of research of diatomite materials for water treatment have been focused on surface decoration and composite modification to strengthen the adsorption and photocatalytic performance. In this review, the recent research progress of diatomite-based materials in treatment of wastewater(such as organic wastewater, eutrophic wastewater, heavy metal ion wastewater, etc.) are summarized and commented based on the principle of adsorption and photocatalysis, and the relationships between structure and performance of diatomite are analyzed from different modification methods. Finally, suggestions and outlooks on the future research directions in diatomite-based materials as adsorbent or photocatalyst are given.

Key words: diatomite-based materials, adsorption, photocatalysis, water treatment
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图1 水中污染物净化示意图,(a)吸附过程;(b)光催化过程
Fig. 1 The diagrams of water purification process by(a) adsorption and (b) photocatalysis
表1 硅藻土基吸附材料在水处理中的应用
Table 1 Application of diatomite-based adsorbent materials in water treatment
Absorbent Method Contaminant/c(mg·L-1) q(mg·g-1) ref
DE(Diatomite) Spray drying-calcination Methylene blue/100 15.38 33
MnO2/DE Hydrothermal Methyl orange/30 420.0 36
DE@C Hydrothermal Crystal violet /200 87.05 38
ZrO2/DE Surface crosslinking Phosphorus/2 10.56 36
NiO/DE Precipitation-calcining Toluene/150 145.36 40
MgO/DE Precipitation-calcining Phosphorus/40 137.93 38
AC/DE Calcining Phenol/25 4.53 32
β-FeOOH/DE Immersion Phosphorus/2 1.67 37
γ-AlOOH/DE Hydrothermal Pb2+ /1000 357.1 51
γ-Al2O3/DE 416.7
Brewing Spent DE(BSDT-800) Beer industrial by-product Cu2+ /50 34.1 49
图2 硅藻土微球样品的制备流程(a); 硅藻土微球SEM照片(b); 硅藻土微球吸附亚甲基蓝(c); 吸附机理(d)[33]
Fig. 2 Preparation process of diatomite microsphere(a); SEM image(b); adsorption of MB(c); adsorption mechanism(d)[33]. Copyright 2018, Elsevier.
图3 MgO-D回收富营养化废水中磷酸盐的机理示意图[47]
Fig. 3 Recovery mechanism of phosphate from eutrophic wastewater by MgO-D[47]. Copyright 2017, ACS Publications.
图4 NZV-DE的HRTEM图像及Si、O、Fe元素对应的EDS图(a);NZVI-DE对Cu2+的选择性吸附(b)[68]
Fig. 4 HRTEM images and corresponding EDS maps for Si, O and Fe for the NZVI-DE(a); Selectively adsorption of Cu2+ by NZVI-DE(b)[68]. Copyright 2018, Elsevier.
表2 硅藻土基光催化材料在水处理中的应用
Table 2 Application of diatomite-based photocatalyst materials in water treatment
Photocatalyst Method Contaminant/c(mg·L-1) Light source(W) k(min-1) ref
Ag/AgBr-DE Deposition-photoreduction Rhodamine B/4 Xenon/300(λ >300 nm) 0.0297 83
DE/g-C3N4 Impregnation-calcination Rhodamine B/10 Metal halide/400(λ >300 nm) 0.1464 85
Bi2O3/DE Freeze drying-calcination Methylene blue/200 Xenon/500 0.0246 84
TiO2/DE Sol-gel Brilliant blue RAW/50 Mercury/175 0.1250 87
ZnO/DE Immersion-calcination Methylene blue/7.5 FL10BLB-UV/10 0.0193 86
Ce-TiO2/DE Sol-gel Rhodamine B/10 Xenon/1000 0.0039 88
Nb2O5/DE Hydrothermal Cr(Ⅵ)/150 Mercury/500 0.0340 92
图5 SEM照片,硅藻土(a);Nb2O5/硅藻土,160 ℃水热处理6 h(b)、9 h(c)和(d)、12 h(e)和(f)、14 h(g)和(h)[92]
Fig. 5 SEM images of raw diatomite sample(a), and Nb2O5/diatomite samples having been hydrothermally treated at 160 ℃ successively for(b) 6 h,(c) and(d) 9 h,(e) and(f) 12 h, and(g) and(h) 14 h[92]. Copyright 2018, Elsevier.
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