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化学进展 2019, Vol. 31 Issue (2/3): 275-282 DOI: 10.7536/PC180730 前一篇   后一篇

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层状双金属氢氧化物在电催化中的应用

周伶俐1, 谢瑞刚2, 王林江1,3,**()   

  1. 1. 桂林理工大学材料科学与工程学院 桂林 541004
    2. 百色学院化学与环境工程学院 百色 533000
    3. 广西有色金属隐伏矿床勘察及材料开发协同创新中心 桂林 541004
  • 收稿日期:2018-07-23 出版日期:2019-02-15 发布日期:2018-12-20
  • 通讯作者: 王林江
  • 基金资助:
    国家自然科学基金项目(41572034); 国家自然科学基金项目(41272064)
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Application of Layered Double Hydroxides in Electrocatalysis

Lingli Zhou1, Ruigang Xie2, Linjiang Wang1,3,**()   

  1. 1. College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, China
    2. College of Chemistry and Environment Engineering, Baise University, Baise 533000, China
    3. Collaborative Innovation Center for Exploration of Hidden Nonferrous Metal Deposits and Development of New Materials in Guangxi, Guilin 541004, China
  • Received:2018-07-23 Online:2019-02-15 Published:2018-12-20
  • Contact: Linjiang Wang
  • About author:
    ** E-mail:
  • Supported by:
    National Natural Science Foundation of China(41572034); National Natural Science Foundation of China(41272064)

在能源紧张和环境问题突出的今天,开发可再生的清洁能源和储能装置已引起研究者们的广泛关注。电催化及其催化材料在新能源开发和使用中起着举足轻重的作用。而二维层状材料因其具有较高的比表面积和独特的电子特性可作为很好的电极材料,在电催化和储能中应用广泛。其中,层状双金属氢氧化物(layered double hydroxides, LDHs)以其典型的层状结构特征,且价格低廉、合成方法简单并易于功能化、组成易于调控、结构可裁剪等优点在电催化及催化材料的制备中具有很好的发展前景。本文主要从LDHs作为阳极析氧反应(oxygen evolution reaction, OER)催化剂、电催化剂载体以及作为制备电催化剂的前驱体三个方面综述了层状双金属氢氧化物应用于电催化材料的研究进展,对调控LDHs材料的电子结构、形貌、界面相互作用以及与贵金属催化剂之间的协同催化等提高其催化性能作了相关阐述,并对以LDHs为前驱体制备电催化剂作了简要阐述。最后,对LDHs应用于电催化所存在的问题及前景进行了展望。

关键词： 层状双金属氢氧化物, 电催化, 催化剂, 催化剂载体, 前驱体

The development of renewable clean energy and energy storage devices has attracted extensive attention because of bad condition of energy shortages and harsh environmental problems. Electrocatalytic reaction and catalyst materials play vital roles in the process of catalysis. Two dimensional layered materials have been widely used as electrode materials in electrocatalysis and energy storage devices thanks to their high specific surface area and unique electronic properties. Among them, layered double hydroxides(LDHs) have a good development prospect in the electrocatalysis process and preparation of catalyst materials due to their typical layered structure and unique advantages such as low price, easy to be prepared and functionalized, good tunability in the composition and structure, etc. This review summarizes the research progress of LDHs applied in catalyst for oxygen evolution reaction(OER), catalyst supporter and used as precursor to prepare electrocatalyst. Especially, we discusse the recent advances in tuning LDHs including electronic structure, morphology, interface interaction and synergetic catalytic effect with noble metal catalyst to improve the catalytic performance. In addition, we briefly describe the preparation of electrocatalysts using LDHs as precursors. Finally, the current difficulties and future research directions of LDHs are also discussed to give an outlook of their prospect in electrocatalysis.

Key words: layered double hydroxides, electrocatalysis, catalyst, catalyst supporter, precursor
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图1 (a) 生长在泡沫镍上NiFe-LDH示意图;(b) 泡沫镍的SEM图;(c) LDHs的结构示意图[40]
Fig. 1 (a) Schematic illustration of NiFe-LDH nanoplates grown on nickel foam;(b) the SEM image of nickel foam; (c) the crystal structure of LDHs[40]. Copyright 2014, the Royal Society of Chemistry
图2 (a)自模板法制备层级中空Ni-Fe LDH纳米棱柱体流程;水解反应后的层级中空Ni-Fe LDH棱柱体的(b) FESEM(c) TEM图[31]
Fig. 2 (a) Formation of hierarchical Ni-Fe LDH hollow nanoprisms by a self-templated strategy;(b) FESEM and(c) TEM images of the hierarchical Ni-Fe LDH hollow prisms obtained after hydrolysis reaction[31]. Copyright 2018, John Wiley&Sons, Inc.
表1 不同调控方式所得的LDHs材料OER性能总结
Table 1 Summary of OER performance of LDHs obtained using different tuning methods
Main method OER catalyst Current density
(mA·cm-2)		 η
(mV)		 Tafel slope
(mV·dec-1)		 ref
Electronic structure Hydrothermal Fe-Ni8-Co2 LDH 10 200 42 32
Hydrothermal Fe-Ni9-Co LDH 10 210 52 32
Hydrothermal NiFeV LDH 20 195 42 33
Co-precipitation NiFeMn LDH 20 289 47 34
Hydrothermal NiFeCr LDH@CP 25 225 69 35
Dry exfoliation CoFe LDHs-Ar/NF 10 237 - 36
Acid etching Acid-etched CoFe-LDH 10 300 41 37
N2 plasma exfoliation N-doped ultrathin CoFe LDHs 10 233 40.03 38
Morphology Liquid-phase exfoliation Single layered Ni-Co LDH 10 334 41 30
In situ growth on NF 3D NiFe LDH film 10 230 50 40
Self-templated strategy Ni-Fe LDH hollow prisms 10 280 49.4 31
Interface interaction Self-assembly 3DGN/CoAl-NS 10 252 64 46
Electro-deposition Cu@NiFe LDH 10 199 27.6 48
Electro-deposition CoFe/LDH 10 286 48 50
图3 (a)以CoAl-LDH/CP 制备P-CoP/CP的流程图;(b) 1.0 M KOH(c) 0.5 M H2SO4(d) 1.0 M PBS电解质中基于电化学活性面积的CoP/CP和p-CoP/CP的HER性能[73]
Fig. 3 (a) Schematic illustration showing the fabrication of p-CoP/CP from CoAl-LDH/CP; The HER performance for CoP/CP and p-CoP/CP after normalization of the electrochemical active area in(b) 1.0 M KOH(c) 0.5 M H2SO4 and(d) 1.0 M PBS[73]. Copyright 2018, the Royal Society of Chemistry.
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