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化学进展 2018, Vol. 30 Issue (12): 2012-2024 DOI: 10.7536/PC180446 前一篇   

• 综述 •

钛、镍、铁配合物在硅氢加成反应中的应用

杨晓玲, 白赢*, 厉嘉云, 代自男, 彭家建*   

  1. 杭州师范大学有机硅化学及材料技术教育部重点实验室 杭州 311121
  • 收稿日期:2018-04-28 修回日期:2018-08-21 出版日期:2018-12-15 发布日期:2018-11-21
  • 通讯作者: 白赢, 彭家建 E-mail:baiying0912@163.com;jjpeng@hznu.edu.cn
  • 基金资助:
    浙江省自然科学基金项目（No.LY18B020012）和浙江省公益项目（No.2017C31105）资助
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Application of the Tianium, Nickel and Iron Complexes in the Hydrosilylation

Xiaoling Yang, Ying Bai*, Jiayun Li, Zinan Dai, Jiajian Peng*   

  1. Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, China
  • Received:2018-04-28 Revised:2018-08-21 Online:2018-12-15 Published:2018-11-21
  • Supported by:
    The work was supported by the Natural Science Foundation of Zhejiang Province(No.LY18B020012) and the Zhejiang Provincial Technologies R&D Program of China(No.2017C31105).
Ti、Ni、Fe配合物作为催化剂广泛应用于有机催化反应中，表现出良好的催化性能，是有机金属催化化学的研究热点之一。本文介绍了近年来非贵金属钛、镍、铁配合物作为催化剂在烯炔烃、含羰基化合物及其他不饱和双键、三键化合物硅氢加成反应中的应用研究成果和进展，分析了这三类催化剂在使用过程中存在的不足，并对其作为催化剂的应用前景进行了展望。
关键词： 非贵金属, 催化, 硅氢加成
Tianium, nickel and iron complexes as catalysts have been widely applied in numerous catalytic organic reactions, in which these complexes show excellent catalytic performance and have been recognized as very important research field. We summarize the recent progress in the synthesis of titanium, nickel and iron complexes and their application in the catalytic hydrosilylation of alkenes, alkynes, carbonyl compounds and other unsaturated double bond, triple bond compounds. Furthermore, the deficiencies of the catalysts have been discussed. At last, the future development and prospects of these complexes as catalysts are also proposed.
Contents
1 Introduction
2 Application of the tianium complexes in the hydrosilylation
3 Application of the nickel complexes in the hydrosilylation
4 Application of the iron complexes in the hydrosilylation
5 Conclusion
Key words: non-noble metal, catalysis, hydrosilylation

中图分类号: 

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