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化学进展 2018, Vol. 30 Issue (9): 1415-1423 DOI: 10.7536/PC180126 前一篇   后一篇

• 综述 •

化学法催化纤维素高效水解成糖

乔颖1,2, 腾娜1, 翟承凯1,3, 那海宁1*, 朱锦1*   

  1. 1. 中国科学院宁波材料技术与工程研究所 浙江省生物基高分子材料技术与应用重点实验室 宁波 315201;
    2. 上海大学材料科学与工程学院高分子系 上海 200444;
    3. 中国科学技术大学纳米科学技术研究所 合肥 230026
  • 收稿日期:2018-01-26 修回日期:2018-03-02 出版日期:2018-09-15 发布日期:2018-05-16
  • 通讯作者: 那海宁, 朱锦 E-mail:nahaining@nimte.ac.cn;jzhu@nimte.ac.cn
  • 基金资助:
    国家自然科学基金项目（No.51773217）、中国科学院青年创新促进会项目（No.2017339）和宁波市创新团队项目（No.2015B11003）资助
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High Efficient Hydrolysis of Cellulose into Sugar by Chemical Catalytic Method

Ying Qiao1,2, Na Teng1, Chengkai Zhai1,3, Haining Na1*, Jin Zhu1*   

  1. 1. Key Laboratory of Bio-Based Polymeric Materials of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China;
    2. Department of Polymer, College of Material Science and Engineering, Shanghai University, Shanghai 200444, China;
    3. Nano Science and Technology Institute, University of Science and Technology of China, Hefei 230026, China
  • Received:2018-01-26 Revised:2018-03-02 Online:2018-09-15 Published:2018-05-16
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(No.51773217), the Youth Innovation Promotion Association of CAS(No.2017339), and the Ningbo Innovation Project(No.2015B11003).
利用化学法实施纤维素高效水解成糖是将可再生非粮生物质转化为能源与材料的关键支撑技术，对维系未来资源与环境的可持续发展具有重要意义。近年来，随着纤维素水解研究的不断深入，研究重点已从探索水解可行性发展到构建高效（即高转化率、高选择性、高转化速度）水解成糖技术。本文通过系统综述纤维素高效水解成糖的原理与方法，围绕纤维素结晶结构转变与水解成糖效率间的关系，详细探讨了各类技术方法在实施高效水解成糖方面的优势与不足。最后，结合最新的研究进展，为未来成功实现纤维素的高效水解成糖提供思路与建议。
关键词： 纤维素, 化学催化, 水解
Using chemical method to efficiently hydrolyze cellulose into sugar is a key support technology for converting renewable non-food biomass into energy and materials, which has great significance to maintain the sustainable development of resources and the environment in the future. In recent years, with the development of the research on the hydrolysis of cellulose, the research content has been shifted from exploring the feasibility of hydrolysis into building a technology of highly efficient (i.e., high conversion rate, high selectivity and high conversion speed) hydrolysis of cellulose into sugar. The principle and method of highly efficient hydrolysis of cellulose into sugar are systematically reviewed. On basis of the relationship between the crystalline structure of cellulose and the high efficiency of hydrolysis, the advantages and disadvantages of various technical methods are discussed in detail. Combining with the latest progress of hydrolysis research, some ideas and suggestions are also provided with the aim to successfully achieve highly efficient hydrolysis of cellulose into sugar in the future.
Contents
1 Introduction
2 Mechanism of highly efficient hydrolysis of cellulose into sugar by chemical catalytic method
2.1 Dissociation of glycosidic bond
2.2 Inhibition of highly crystalline structure
2.3 Recrystallization in hydrolysis
3 Technology and methods to hydrolyze cellulose into sugar
3.1 Catalyst
3.2 System of hydrolysis
3.3 Hydrolytic and driving methods
4 Conclusion and outlook
Key words: cellulose, chemical catalysis, hydrolysis

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摘要

化学法催化纤维素高效水解成糖