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化学进展 2018, Vol. 30 Issue (2/3): 198-205 DOI: 10.7536/PC170712 前一篇   后一篇

• 综述 •

埃洛石纳米管在分离富集中的应用

张华东, 李攻科*, 胡玉斐*   

  1. 中山大学化学学院 广州 510275
  • 收稿日期:2017-07-14 修回日期:2017-10-18 出版日期:2018-02-15 发布日期:2017-12-11
  • 通讯作者: 李攻科,cesgkl@mail.sysu.edu.cn;胡玉斐,huyufei@mail.sysu.edu.cn E-mail:cesgkl@mail.sysu.edu.cn;huyufei@mail.sysu.edu.cn
  • 基金资助:
    国家自然科学基金项目（No.21675178，21475153，21575167）、广东省自然科学重点基金项目（No.2015A030311020）、广东省自然科学基金自由申请项目（No.2016A030313358）、广东省公益研究与能力建设专项基金项目（No.2015A030401036）和广州市民生科技重大专项资助项目（201604020165）资助
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Applications of Halloysite Nanotubes in Separation and Enrichment

Huadong Zhang, Gongke Li*, Yufei Hu*   

  1. School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China
  • Received:2017-07-14 Revised:2017-10-18 Online:2018-02-15 Published:2017-12-11
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(No. 21675178, 21475153, 21575167), the Guangdong Provincial Natural Science Foundation(No. 2015A030311020, 2016A030313358), the Special Funds for Public Welfare Research and Capacity Building in Guangdong Province of China(No. 2015A030401036), and the Guangzhou Minsheng Science and Technology Major Project of China(No.201604020165).
埃洛石纳米管（Halloysite Nanotubes，HNTs）是一种天然的纳米管状材料，具有对环境友好、生物相容性好、细胞毒性小等特点，近年来该材料得到了广泛的应用。HNTs是生物相容性较好的“绿色”材料，成本低、来源广等优点使其成为制备生物复合材料中的添加剂，而且HNTs具有的空腔结构、表面电荷性质及表面吸附性为重金属离子、染料分子、有机分子等的分离富集提供有利条件。另外，HNTs及其衍生的生物复合材料在循环肿瘤细胞的富集上得到应用。为了更好地了解和利用埃洛石纳米管，本文介绍了埃洛石纳米管的物理化学性能，以及HNTs在分离富集、活性分子的载运与控制释放等方面的应用进展，并对埃洛石纳米管的发展及应用前景进行展望。
关键词： 埃洛石纳米管, 分离, 富集, 药物分子, 肿瘤细胞
Halloysite nanotubes(HNTs), as a natural nano-tubular material, with a variety of advantages, such as environmental friendliness, biocompatibility, low cytotoxicity and so on, have been widely used in recent years. As a kind of biocompatible "green" material, because of their low cost and abundant natural resources, HNTs can be used as excellent additives for biomaterials. Besides, nano-tubular structure, surface charge and adsorption properties provide favorable conditions for separation and enrichment of metal ions, dyes, organic compounds and so on. Even better, HNTs and HNTs-derived biomaterials have been used as absorbents to capture circulating tumor cells in recent studies. For better understanding and utilize the nanotube, we introduce the structure and properties of HNTs in detail, and review their application in separation, loading and controlled release of active molecules, etc. in this paper. Finally, we give a conclusion that HNTs own a splendid perspectives on future opportunities and promising applications.
Contents
1 Introduction
2 Structure and properties of halloysite nanotubes
2.1 General Structure
2.2 Main Properties
3 Application of halloysite nanotubes in detection
3.1 Application in detection of heavy metal ions
3.2 Application in detection of compounds
4 Application of halloysite nanotubes in enrichment
4.1 Enrichment of dyes
4.2 Enrichment of functional compounds
4.3 Enrichment of tumor cells
5 Conclusion
Key words: halloysite nanotubes, separation, enrichment, drug molecule, tumor cell

中图分类号: 

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