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化学进展 2017, Vol. 29 Issue (10): 1206-1214 DOI: 10.7536/PC170619 前一篇   后一篇

所属专题： 电化学有机合成； 金属有机框架材料

• 综述 •

MOF构筑的电化学传感器及应用

姜信欣, 赵成军, 钟春菊, 李建平*   

  1. 桂林理工大学化学与生物工程学院 广西电磁化学功能物质重点实验室 桂林 541004
  • 收稿日期:2017-06-19 修回日期:2017-08-10 出版日期:2017-10-15 发布日期:2017-08-29
  • 通讯作者: 李建平,e-mail:likianping@263.net E-mail:likianping@263.net
  • 基金资助:
    国家自然科学基金项目（No.21375031，21765006），广西自然科学基金创新研究团队项目（No.2015GXNSFFA139005）和广西高等学校高水平创新团队及卓越学者计划项目（桂教人[2014]49号）资助
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The Electrochemical Sensors Based on MOF and Their Applications

Xinxin Jiang, Chengjun Zhao, Chunju Zhong, Jianping Li*   

  1. Guangxi Key Laboratory of Electrochemical and Magnetochemical Function Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, China
  • Received:2017-06-19 Revised:2017-08-10 Online:2017-10-15 Published:2017-08-29
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21375031, 21765006), the Natural Science Foundation of Guangxi Province, China (No. 2015GXNSFFA139005), and the High Level Innovation Teams of Guangxi Colleges & Universities and Outstanding Scholars Program, China (No. Guijiaoren[2014]49).
金属-有机框架化合物（以下简称金属-有机框架）是一类有机配体与金属中心通过自组装形成的具有三维框架结构的多孔材料，其特异复杂的结构使其具有良好的化学性能。金属-有机框架化合物在分析化学方面的应用受到广泛关注，在电化学传感器应用方面也取得了显著进展。本文简要介绍近年来金属-有机框架用于构建电化学传感器的方法及在电化学传感器中的作用；对基于金属-有机框架的电化学传感器的应用进行了综述；分析了目前金属-有机框架-电化学传感器研究中存在的问题和局限性并对其应用进行了展望。
关键词： 金属-有机框架化合物, 敏感膜, 电化学传感器, 多孔材料
Metal organic framework is a kind of three-dimensional framework porous materials self-assembly by a structure of organic ligands and metal centers. Because of the structure of metal organic complex framework, it has good chemical properties. Metal-organic frameworks have become more and more mature when applied to material analysis. Significant progress has also been achieved in the application of electrochemical sensors. In this paper, the newly found preparing approaches to the mental-organic frameworks, constructing electrochemical sensor methods as well as the summary of its application in electrochemical sensor based on MOF are presented. The problems and the limitations in metal-organic frameworks application to the electrochemical sensors are also involved. At the end, we briefly discuss the direction and expectations of electrochemical sensor based on metal-organic frameworks.
Contents
1 Introduction
2 Methods for preparing MOF modified electrode
2.1 Layer-by-Layer self-assembly
2.2 Electro polymerization
2.3 Solvothermal Method
3 The role of MOF in electrochemical sensor
3.1 Catalysis
3.2 Improvement of surface areas
3.3 Electroactive immobilization
3.4 Molecular recognition
4 Application in electrochemical sensor about MOF
4.1 Application in the determination of organics
4.2 Application in the determination of inorganic ions
4.3 Application in the determination of biomacromolecules
5 Conclusion
Key words: metal-organic framework, sensitive membrane, electrochemical sensors, porous materials

中图分类号: 

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摘要

MOF构筑的电化学传感器及应用