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化学进展 2017, Vol. 29 Issue (11): 1285-1296 DOI: 10.7536/PC170567 前一篇   后一篇

• 综述 •

二维原子晶体材料的制备与应变传感特性研究

朱文杰1, 台国安1,2*, 王旭峰1,2, 古其林1,2, 伍增辉1,2, 朱孔军1,2*   

  1. 1. 南京航空航天大学航空宇航学院 机械结构力学及控制国家重点实验室 南京 210016;
    2. 南京航空航天大学材料科学与技术学院 南京 210016
  • 收稿日期:2017-05-31 修回日期:2017-08-11 出版日期:2017-11-15 发布日期:2017-10-27
  • 通讯作者: 台国安,e-mail:taiguoan@nuaa.edu.cn;朱孔军,e-mail:kjzhu@nuaa.edu.cn E-mail:taiguoan@nuaa.edu.cn;kjzhu@nuaa.edu.cn
  • 基金资助:
    国家自然科学基金项目（No.61474063，61774085，51672130），江苏省自然科学基金项目（No.BK20151475），中央高校基本科研业务费专项资金（No.NE2017101），江苏省高校优势学科建设工程和江苏省“六大人才高峰”项目（XCL-046）资助
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Fabrication and Strain Sensing Properties of Two-Dimensional Atomic Crystal Materials

Wenjie Zhu1, Guoan Tai1,2*, Xufeng Wang1,2, Qilin Gu1,2, Zenghui Wu1,2, Kongjun Zhu1,2*   

  1. 1. State Key Laboratory of Mechanics and Control of Mechanical Structures, College of Aerospace Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China;
    2. College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China
  • Received:2017-05-31 Revised:2017-08-11 Online:2017-11-15 Published:2017-10-27
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 61474063, 61774085, 51672130), the Natural Science Foundation of Jiangsu Province (No. BK20151475), the Fundamental Research Funds for the Central Universities (No. NE2017101), the Priority Academic Program Development of Jiangsu Higher Education Institutions,and the Six Talent Peaks Project in Jiangsu Province (XCL-046).
二维原子晶体材料由于具有优异的光、电、力、磁和热学等性能而引起了广泛的研究兴趣。尤其，二维原子晶体材料在微小形变下可以产生较大的电阻变化，且能够承受比相应体材料更大的弹性应变而不至于使其结构破坏，在应变传感器方面具有重要的潜在应用价值，并且有望构建在各种条件下适用的柔性集成化的电子器件。目前，二维原子晶体材料备受关注的是石墨烯、二硫化钼和黑磷。本文从上述三种典型二维材料的基本物性出发，基于其物理性质和微观结构从理论上解释二维材料的应变传感特性，并详细介绍二维材料的各种制备方法如机械剥离法、溶液法和化学气相沉积法（CVD）等。在材料制备的基础上，阐述了石墨烯、二硫化钼、黑磷在应变传感领域如健康监测、可穿戴器件、电子皮肤等方面的具体应用，并展望了二维材料未来的研究方向与应用前景。
关键词： 二维材料, 弹性应变, 化学气相沉积法, 应变传感, 健康监测
Two-dimensional atomic crystal materials have attracted a wide range of research interests due to their excellent optical, electrical, mechanical, magnetic and thermal properties. In particular, two-dimensional atomic crystal materials can produce a large resistance change steadily under the micro-deformation. They can bear a greater elastic strain than the corresponding bulk material without causing breaking of the structures. The characteristic makes them have an important potential application for the high-performance strain sensors. Besides, they are expected to fabricate flexible integrated electronic devices which are appropriate for all kinds of working condition. At present, the studies related to two-dimensional atomic crystal materials have mainly concentrated on graphene, molybdenum disulfide and black phosphorus. In this review, we firstly introduce the basic properties of the three typical two-dimensional materials and explain theoretically their strain sensing characteristics based on their physical property and microstructure. Secondly, some important methods for preparing the 2D materials, such as micromechanical exfoliation, solution exfoliation and chemical vapor deposition (CVD), are summarized. Thirdly, the applications of the 2D materials in the strain sensing fields, such as health monitoring, wearable devices and electronic skin, are introduced in detailed. Finally, we present the future research direction and application prospect of two-dimensional materials.
Contents
1 Introduction
2 Basic physical properties of 2D materials
2.1 Graphene
2.2 MoS2
2.3 Phosphorene
2.4 Theory explanation for strain sensing
3 Synthesis of 2D materials
3.1 Mechanical exfoliation methods
3.2 Solution methods
3.3 Chemical vapor deposition
4 Application in strain sensing
4.1 Graphene
4.2 MoS2
4.3 Phosphorene
5 Conclusion
Key words: two-dimensional materials, elastic strain, chemical vapor deposition, strain sensing, health monitoring

中图分类号: 

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[1] Novoselov K S, Geim A K, Morozov S V, Jiang D, Zhang Y, Dubonos S V, Grigorieva I V, Firsov A A. Science, 2004, 306:666.
[2] Novoselov K S, Jiang D, Schedin F, Booth T J, Khotkevich V V, Morozov S V, Geim A K. Proc. Natl. Acad. Sci. U.S.A., 2005, 102:10451.
[3] Wu M, Zeng X. Nano Lett., 2016, 16:3236.
[4] Zhao S J, Kang W, Xue J M. Appl. Phys. Lett., 2014, 104:13.
[5] Tai G, Hu T, Zhou Y, Wang X, Kong J, Zeng T, You Y, Wang Q. Angew. Chem. Int. Ed., 2015, 54:15473.
[6] Feng B J, Zhang J, Zhong Q, Li W B, Li S, Li H, Cheng P, Chen S M L, Wu K H. Nat.Chem., 2016, 8:564.
[7] Mannix A J, Zhou X F, Kiraly B, Wood J D, Alducin D, Myers B D, Liu X L, Brandon L F, Santiago U, Jeffrey R, Yacaman M J, Ponce A, Oganov A R, Mark C, Guisinger N P. Science, 2015, 350:1513.
[8] Schwierz F. Nat. Nano, 2010, 5:487.
[9] Sundaram R S, Navarro C G, Balasubramaniam K, Burghard M, Kern K. Adv. Mater., 2008, 20:3050.
[10] Li X H, Choy W C H, Huo L J, Xie F X, Sha W E I, Ding B F, Guo X, Li Y F, Hou J H, You J B, Yang Y. Adv. Mater., 2012, 24:3046.
[11] Michael E, Mathias S, Phaedon A. Nano Lett., 2014, 14:6414.
[12] Koenig S P, Doganov R A, Schmidt H, Neto A H C, Ozyilmaz B. Appl. Phys. Lett., 2014, 104:103106.
[13] Mayorga-Martinez C C, Sofer Z, Pumera M. Angew. Chem. Int. Ed., 2015, 54:14317.
[14] Dai J, Zeng X C. J. Phys. Chem. Lett., 2014, 5:1289.
[15] Lopez-Sanchez O, Lembke D, Kayci M, Radenovic A, Kis A. Nat. Nanotechnol., 2013, 8:497.
[16] Radisavljevic B, Radenovic A, Brivio J, Giacometti V, Kis A. Nat. Nanotechnol., 2011, 6:147.
[17] Pu J, Yomogida Y, Liu K K, Li L J, Iwasa Y, Takenobu T. Nano Lett., 2012, 12:4013.
[18] Gao M R, Xu Y F, Jiang J, Yu S H. Chem. Soc. Rev., 2013, 42:2986.
[19] Park M, Park Y, Chen X, Park Y K, Kim M S, Ahn J H. Adv. Mater., 2016, 28:2556.
[20] Shi G, Zhao Z H, Pai J H, Lee I, Zhang L Q, Stevenson C, Ishara K, Zhang R J, Zhu H W, Ma J. Adv. Funct. Mater., 2016, 2:619.
[21] Wang Y, Wang L, Yang T, Li X, Zang X, Zhu M, Wang K, Wu D, Zhu H. Adv. Funct. Mater., 2014, 24:4666.
[22] Casiraghi C, Hartschuh A, Lidorikis E, Qian H, Harutyunyan H, Gokus T, Novoselov K S, Ferrari A C. Nano Lett., 2007, 7:2711.
[23] Katsnelson M. Mater. Today, 2007, 10:20.
[24] Balandin A, Ghosh S, Bao W, Calizo I, Teweldebrhan D, Miao F, Lau C N. Nano Lett., 2008, 8:902.
[25] Chae H, Siberio-Pérez D, Kim J, Go Y B, Eddaoudi M, Matzger A, O'Keeffe M, Yaghi1 O M. Nature, 2004, 427:523.
[26] Liu Y, Xiao N, Gong N, Wang H, Shi X, Gu W, Ye L. Carbon, 2014, 68:258.
[27] Lee C, Wei X, Kysar J, Hone J. Science, 2008, 321:385.
[28] Xu M S, Liang T, Shi M M, Chen H Z. Chem. Rev., 2013, 113:3766.
[29] Mak K F, Lee C, Hone J, Shan J, Heinz T F. Phys. Rev. Lett., 2010, 105:136805.
[30] Splendiani A, Sun L, Zhang Y B, Li T S, Kim J, Chim C Y, Galli, G, Wang F. Nano Lett., 2010, 10:1271.
[31] Hui Y Y, Liu X, Jie W, Chan N Y, Hao J, Hsu Y T, Li L J, Guo W, Lau S P. ACS Nano, 2013, 7:7126.
[32] Li L, Yu Y, Ye G J, Ge Q, Ou X, Wu H, Feng D, Chen X H, Zhang Y. Nat. Nanotechnol., 2014, 9:372.
[33] Asahina H, Shindo K, Morita A. J. Phys. Soc. Jpn., 1982, 51:1193.
[34] Qiao J, Kong X, Hu Z X, Yang F, Ji W. Nat. Commun., 2014, 5:4475.
[35] Li L, Kim J, Jin C, Ye G, Qiu D Y, da Jornada F H, Shi Z, Chen L, Zhang Z, Yang F, Watanabe K, Taniguchi T, Ren W, Louie S G, Chen X, Zhang Y, Wang F. Nat. Nanotechnol., 2016, 12:21.
[36] Liu H, Neal A T, Zhu Z, Luo Z, Xu X, Tománek D, Ye P D. ACS Nano, 2014, 8:4033.
[37] Guo X F, Qiu J P, Guo W L. Nanotechnology, 2016, 27:505702.
[38] Pan D X, Li Y, Wang T C, Guo W L. Acta Mech. Sin., 2017,33:71.
[39] Liu X F, Pan D X, Hong Y Z, Guo W L. Am. Phys. Soc., 2014, 112:205502.
[40] Geim A K, Novoselov K S. Nat. Mater., 2007, 6:183.
[41] Xie L M, Jiao L Y, Dai H J. J. Am. Chem. Soc., 2010, 132:14751.
[42] Yin Z Y, Li H. ACS Nano, 2011, 6:74.
[43] Li H, Yin Z Y, He Q Y, Li H, Huang X, Lu G, Fam D W H, Tok A I Y, Zhang Q, Zhang H. Small, 2012, 8:63.
[44] Jeong H K, Lee Y P, Lahaye R J W E, Park M H, An K H, Kim I J, Yang C W, Park C Y, Ruoff R S, Lee Y H. J. Am. Chem. Soc., 2008, 130:1362.
[45] Zhang L, Liang J J, Huang Y, Ma Y F, Wang Y, Chen Y S. Carbon, 2009, 47:3365.
[46] Becerril H A, Mao J, Liu Z, Stoltenberg R M, Randall M, Bao Z, Chen Y. ACS Nano, 2008, 2:463.
[47] Chang H X, Sun Z H, Yuan Q H, Ding F, Tao X M, Yan F, Zheng Z J. Adv. Mater., 2010, 22:4872.
[48] Li D, Muller M B, Gilje S, Kaner R B, Wallace G G. Nat. Nanotechnol., 2008, 3:101.
[49] Zeng Z Y, Yin Z Y, Huang X, Li H, He Q Y, Lu G, Boey F, Zhang H. Angew. Chem. Int. Edit., 2011, 50:11093.
[50] Gopalakrishnan D, Damien D, Shaijumon M M. ACS Nano, 2014, 8:5297.
[51] Sun Z B, Xie H H, Tang S Y, Yu X F, Guo Z N, Shao J D, Zhang H, Huang H, Wang H Y, Chu P K. Angew. Chem. Int. Ed., 2015, 54:11526.
[52] Obraztsov A N, Obraztsova E A, Tyurnina A V. Carbon, 2007, 45:2017.
[53] Yu Q, Lian J, Siriponglert S. Appl. Phys. Lett., 2008, 93:113103.
[54] Li X S, Cai W W, Colombo L G, Ruoff R S. Nano Lett., 2009, 9:4268.
[55] Bae S, Kim H, Lee Y, Xu X F, Park J, Zheng Y, Balakrishnan J, Lei T, Kim H R, Song Y, Kim Y, Kim K S, Özyilmaz B, Ahn J, Hong B H, Iijima S.Nat. Nanotechnol., 2010, 5:574.
[56] Ling X, Lee Y H, Lin Y X, Fang W J, Yu L L, Dresselhaus M S, Kong J. Nano lett., 2014, 14:464.
[57] Wang X S, Feng H B, Wu Y M, Jiao L Y. J. Am. Chem. Soc., 2013, 135:5304.
[58] Tai G, Zeng T, Yu J, Zhou J, You Y, Wang X, Wu H, Sun X, Hu T, Guo W. Nanoscale, 2016, 8:2234.
[59] Wang Y, Yang R, Shi Z W, Zhang L Z, Shi D X, Wang E G, Zhang G Y. ACS Nano, 2011, 5:3645.
[60] Li X, Sun P, Fan L, Zhu M, Wang K, Zhong M, Wei J, Wu D, Cheng Y, Zhu H. Sci. Rep., 2012, 2:395.
[61] Yang T, Wang W, Zhang H, Li X, Shi J, He Y, Zheng Q, Li Z, Zhu H. ACS Nano, 2015, 9:10867.
[62] Fei R, Yang L. Nano Lett., 2014, 14:2884.
[63] Wu H R, Liu X F, Yin J, Zhou J X, Guo W L. Small, 2016, 12:5276.
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