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化学进展 2017, Vol. 29 Issue (9): 1008-1020 DOI: 10.7536/PC170566 前一篇   后一篇

• 综述 •

环境持久性自由基的产生机理及环境化学行为

韩林, 陈宝梁*   

  1. 浙江大学环境科学系 浙江省有机污染过程与控制重点实验室 杭州 310058
  • 收稿日期:2017-05-31 修回日期:2017-07-18 出版日期:2017-09-15 发布日期:2017-09-05
  • 通讯作者: 陈宝梁,e-mail:blchen@zju.edu.cn E-mail:blchen@zju.edu.cn
  • 基金资助:
    国家自然科学基金项目（No.21425730，21537005）资助
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Generation Mechanism and Fate Behaviors of Environmental Persistent Free Radicals

Lin Han, Baoliang Chen*   

  1. Zhejiang Provincial Key Laboratory of Organic Pollution Process and Control, Department of Environmental Science, Zhejiang University, Hangzhou 310058, China
  • Received:2017-05-31 Revised:2017-07-18 Online:2017-09-15 Published:2017-09-05
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(No. 21425730, 21537005).
环境持久性自由基因其能在环境中持续存在且具有潜在环境毒性效应而逐渐受到关注。与瞬时自由基相比，环境持久性自由基的研究相对较少，其产生机理及环境化学行为等方面值得深入研究。本文评述了环境持久性自由基的检测方法、生成机理、种类，环境稳定性、持久性与反应性，以及环境效应及消除方法等方面的研究进展；展望了未来研究方向，并提出环境持久性自由基的迁移转化行为及环境效应是环境化学领域新的研究方向。
关键词： 环境持久性自由基, 生成机理, 稳定性, 持久性, 反应性, 迁移转化行为
Environmental persistent free radicals (EPFRs) can persist in environment for hours to days, and have potential environmental and public health impacts, which has attracted more and more attention in recent years. Environmental persistent free radicals are found to exist in a variety of environmental media, such as combustion particles and organic contaminated soil, and they are considered to be an emerging pollutant recently. Compared with transient free radicals, environmental persistent free radicals have received relatively less attention, and the generating mechanisms and environmental impacts remain unclear. Meanwhile, environmental persistent free radicals are widely distributed in the environment, which makes them more complex in their research. This review highlights EPFRs from the following aspects:detection methods, generating mechanisms, speciation types, environmental characteristics (persistence, stability, and reactivity), the harm to the environment and the elimination method. By studying the fate behaviors of environmental persistent free radicals, this article proposes a possible migration pathway in environment. The purpose of this review is to have a more comprehensive understanding of the EPFRs, especially to help reduce the harm to the human and environment, and provide scientific basis for researchers to have a deeper study on it.
Contents
1 Introduction
2 Environmental persistent free radicals (EPFRs)
3 Generation mechanism of EPFRs
3.1 The media of the EPFRs formation
3.2 The precursors of the EPFRs
3.3 The influential conditions of EPFRs formation
3.4 The formation mechanism of the EPFRs
4 Species of EPFRs
5 Persistence and stability of EPFRs
6 Reactivity of EPFRs and its application on the environmental pollution control
7 Potential hazards of EPFRs and its elimination methods
7.1 Potential hazards of EPFRs
7.2 Elimination methods of EPFRs
8 Environmental chemistry behaviors of EPFRs
9 Conclusion
Key words: environmental persistent free radicals(EPFRs), generating mechanisms, stability, persistence, reactivity, transport and transformation behaviors

中图分类号: 

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