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化学进展 2017, Vol. 29 Issue (10): 1252-1259 DOI: 10.7536/PC170541 前一篇   后一篇

• 综述 •

纳米金属-有机框架材料的制备及应用

赵田*, 董茗, 赵熠, 刘跃军*   

  1. 湖南工业大学包装与材料工程学院 株洲 412007
  • 收稿日期:2017-05-18 修回日期:2017-07-21 出版日期:2017-10-15 发布日期:2017-08-29
  • 通讯作者: 赵田,e-mail:tian_zhao@hut.edu.cn;刘跃军,e-mail:yjliu_2005@126.com E-mail:tian_zhao@hut.edu.cn;yjliu_2005@126.com
  • 基金资助:
    国家自然科学基金项目（No.11372108）资助
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Preparation and Application of Nano-Sized Metal-Organic Frameworks

Tian Zhao*, Ming Dong, Yi Zhao, Yuejun Liu*   

  1. School of Packaging and Materials Engineering, Hunan University of Technology, Zhuzhou 412007, China
  • Received:2017-05-18 Revised:2017-07-21 Online:2017-10-15 Published:2017-08-29
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 11372108).
金属-有机框架材料（MOFs）自发现以来备受关注，其独特的高孔隙率结构特性、孔径可调以及可官能化等特点，在许多领域都有潜在的应用，如储气、分离、催化和热能转化等。纳米金属-有机框架材料（NMOFs）因具有纳米尺寸，既拥有传统块状MOFs的性质，也具备特殊的物理/化学特性，表现出更为优异的性能。本文介绍了MOFs的发展，及几种经典的MOFs结构及其应用；重点论述了近年来一些重要的纳米MOFs的制备方法和应用，并对纳米MOFs在新型材料领域中的应用及其发展方向进行了展望。
关键词： 金属-有机框架, 纳米, 制备, 应用
Metal-organic frameworks (MOFs) receive great attention, due to their high porosity which promises applications in gas storage, separations, catalysis and heat transformation etc. Nano metal-organic framework materials (NMOFs) combined the bulk phase properties of the MOFs together with the additional physical/chemical properties derived from nano-sized particles, which can display improved properties. This review generally introduces the development of MOFs, several classical prototypical MOFs structures and their applications. Meanwhile, the preparation methods of some special important NMOFs and their applications are discussed. Finally, we present the trend and future prospects of novel materials based on NMOFs.
Contents
1 Introduction
2 Metal-organic frameworks
3 Preparation and application of nano metal-organic framework materials
3.1 Preparation of nano-sized classical MOFs
3.2 Applications of classical nano-MOFs
3.3 Preparation and application of other nano-MOFs
4 Conclusion
Key words: metal-organic frameworks, nano, syntheses, application

中图分类号: 

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