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化学进展 2017, Vol. 29 Issue (10): 1260-1272 DOI: 10.7536/PC170532 前一篇   后一篇

• 综述 •

钒氧基电极材料特点及其改性方法

李秀娟1, 曹云鹤1,2, 华康1, 王畅1, 徐卫林1, 方东1,2*   

  1. 1. 武汉纺织大学材料科学与工程学院 湖北省纺织新材料与先进加工技术省部共建国家重点实验室培育基地 湖北省纺织新材料及其应用重点实验室 武汉 430200;
    2. 昆明理工大学材料科学与工程学院 昆明 650093
  • 收稿日期:2017-05-12 修回日期:2017-07-23 出版日期:2017-10-15 发布日期:2017-08-29
  • 通讯作者: 方东,e-mail:csufangdong@gmail.com E-mail:csufangdong@gmail.com
  • 基金资助:
    国家自然科学基金项目（No.51201117，51741102），云南省教育厅重大专项（No.2016CYH08）和云南省科技厅创新团队（No.2017HC033）资助
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Characterization and Modification Method of Oxovanadium-Based Electrode Materials

Xiujuan Li1, Yunhe Cao1,2, Kang Hua1, Chang Wang1, Weilin Xu1, Dong Fang1,2*   

  1. 1. State Key Laboratory of New Textile Materials & Advanced Processing Technologies and Hubei Key Laboratory of Advanced Textile Materials & Application, Hubei Key Laboratory of Advanced Textile Materials & Application, College of Materials Science and Engineering, Wuhan Textile University, Wuhan 430200, China;
    2. College of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China
  • Received:2017-05-12 Revised:2017-07-23 Online:2017-10-15 Published:2017-08-29
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 51201117, 51741102), the Major Projects of Yunnan Provincial Education Department (No. 2016CYH08), and the Innovation Team of Yunnan Provincial Science and Technology Department(No. 2017HC033).
钒氧基化合物作为钒基化合物中重要的一员，其具有比容量高、价格低廉等特点，是一种极具有前景的电极材料，然而其电导率低、可溶解于电解液，造成充放电过程中倍率、循环稳定性差。本文介绍了钒氧基化合物作为锂离子/钠离子电池电极材料的研究进展，重点介绍了钒氧基化合物电化学性能降低的原因。综述了针对钒氧基化合物问题所采用的离子掺杂、表面包覆、导电物质复合解决办法，并讨论了一些具有代表性的改性后电极材料的制备方法、电化学性能及相应机制，且展望了钒氧基化合物未来的研究方向。
关键词： 钒氧基化合物, 锂离子电池, 电导率, 循环稳定性, 改性
Among various vanadium-based materials, oxovanadium-based materials are promising candidates for lithium-ion battery electrodes because of their high capacity and low price. However, due to their fairly low conductivity and dissolution in electrolyte, the practical usage of oxovanadium-based materials shows poor rate capability and cycling stability. In this review, the recent progress in oxovanadium-based materials for lithium/sodium ion batteries is introduced and focused on their storage and capacity fading mechanisms. To overcome the low conductivity and irreversible phase transition, metal-doped, surface coating and conductive material composite are reviewed. Synthesis method, electrochemical performance and possible mechanism of typical modified electrode materials are discussed and the prospects of oxovanadium-based materials are also discussed.
Contents
1 Introduction
2 Structure characterization of vanadium oxide electrode materials
3 Electrochemical performance of vanadium oxide electrode materials
3.1 Lithium/sodium ion storage performance of vanadium oxide electrode materials
3.2 Vanadium oxide electrode materials for supercapacitors
3.3 Capacity fading mechanism of vanadium oxide electrode materials
4 Modification research of vanadium oxide electrode materials
4.1 Ion-doping
4.2 Surface coating
4.3 Conductive material composite
4.4 The lithium intercalation mechanism of modified vanadium oxide
5 Conclusion
Key words: oxovanadium-based materials, lithium ion battery, conductivity, cycling stability, modification

中图分类号: 

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