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化学进展 2017, Vol. 29 Issue (9): 1021-1029 DOI: 10.7536/PC170522 前一篇   后一篇

• 综述 •

人工碳纳米材料的环境转化及其效应

李旭光, 杜婷婷, 刘金, 刘新蕾, 马朋坤, 戚豫, 陈威*   

  1. 南开大学环境科学与工程学院 环境污染过程与基准教育部重点实验室 天津市城市生态环境修复与污染防治重点实验室 天津 300350
  • 收稿日期:2017-05-10 修回日期:2017-07-15 出版日期:2017-09-15 发布日期:2017-09-05
  • 通讯作者: 陈威,e-mail:chenwei@nankai.edu.cn E-mail:chenwei@nankai.edu.cn
  • 基金资助:
    国家重点基础研究发展计划（973计划）（No.2014CB932001），国家自然科学基金重点项目（No.21237002）和国家杰出青年科学基金（No.21425729）资助
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Environmental Transformation of Engineered Carbon Nanomaterials and Its Implications

Xuguang Li, Tingting Du, Jin Liu, Xinlei Liu, Pengkun Ma, Yu Qi, Wei Chen*   

  1. Ministry of Education Key Laboratory of Pollution Processes and Environmental Criteria, Tianjin Key Laboratory of Environmental Remediation and Pollution Control, College of Environmental Science and Engineering, Nankai University, Tianjin 300350, China
  • Received:2017-05-10 Revised:2017-07-15 Online:2017-09-15 Published:2017-09-05
  • Supported by:
    The work was supported by the Ministry of Science and Technology of China (No. 2014CB932001), the National Natural Science Foundation of China (No.21237002) and the National Science Fund for Distinguished Young Scholars (No. 21425729).
近年来，人工碳纳米材料在诸多领域都显示出了广泛的应用前景，而碳纳米材料产量和使用量的大幅增加也使其环境行为与效应受到关注。碳纳米材料进入环境后，可发生复杂的物理、化学和生物转化，导致其表面电荷、疏水性及表面官能团等理化性质发生显著改变。碳纳米材料的环境转化一方面可导致其胶体稳定性、迁移能力和生物效应发生改变，另一方面可显著影响其富集、输送和转化环境污染物的能力，因此，环境转化决定了碳纳米材料的环境行为及其效应。本文总结了近年来有关人工碳纳米材料环境转化及其效应的主要研究成果，探讨了环境转化影响碳纳米材料环境行为与效应的关键机制和构效关系。
关键词： 人工碳纳米材料, 环境转化, 污染物, 迁移归宿, 生态效应
Engineered carbon nanomaterials have shown great promise in many applications. With the rapid increase in the production and use of these materials, their environmental behaviors and implications have received much attention. Carbon nanomaterials can undergo significant physical, chemical and biological transformation in the environment, resulting in remarkable changes in their surface charge, hydrophobicity and surface functionality. Environmental transformation of carbon nanomaterials can significantly affect their colloidal stability, transport and toxicity, as well as their capabilities to accumulate/mobilize environmental contaminants and to catalyze environmentally relevant reactions. Thus, environmental transformation largely dictates the environmental behaviors and implications of carbon nanomaterials. This paper summarizes the recent key research findings in the area, with an emphasis on the underlying mechanisms and structure-effect correlations.
Contents
1 Introduction
2 Transformation of engineered carbon nanomaterials
2.1 Physical transformation of carbon nanomaterials
2.2 Chemical transformation of carbon nanomaterials
2.3 Biological transformation of carbon nanomaterials
3 Effects of environmental transformation on environmental processes and implications of carbon nanomaterials
3.1 Environmental transformation affects transport of carbon nanomaterials
3.2 Environmental transformation affects capability of carbon nanoparticles to accumulate and mobilize contaminants
3.3 Environmental transformation affects catalytic efficiency of carbon nanomaterials
4 Conclusion
Key words: engineered carbon nanomaterials, environmental transformation, contaminants, transport and fate, ecological impacts

中图分类号: 

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