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化学进展 2017, Vol. 29 Issue (9): 1053-1061 DOI: 10.7536/PC170513 前一篇   后一篇

• 综述 •

表界面调控晶体变化微观机制探索与铬渣治理研究的结合

刘炜珍1, 郑嘉毅1, 吴智诚2, 刘章斌1, 林璋1*   

  1. 1. 华南理工大学环境与能源学院 工业聚集区污染控制与生态修复教育部重点实验室 广东省环境纳米材料工程技术研究中心 广州 510006;
    2. 中国科学院福建物质结构研究所 福州 350002
  • 收稿日期:2017-05-08 修回日期:2017-07-29 出版日期:2017-09-15 发布日期:2017-09-05
  • 通讯作者: 林璋,e-mail:zlin@scut.edu.cn E-mail:zlin@scut.edu.cn
  • 基金资助:
    国家自然科学基金项目（No.21125730，21607045），国家重点研发计划（No.2013CB934302）和中科院纳米先导专项A（No.XDA09030203）资助
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The Application of Micro-Mechanism of Crystal Changes under the Surface/Interface Control in Treating Chromium-Containing Residues

Weizhen Liu1, Jiayi Zheng1, Zhicheng Wu2, Zhangbin Liu1, Zhang Lin1*   

  1. 1. School of Environment and Energy, South China University of Technology, the Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters(Ministry of Education), Guangdong Engineering and Technology Research Center for Environmental Nanomaterials, Guangzhou 510006, China;
    2. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
  • Received:2017-05-08 Revised:2017-07-29 Online:2017-09-15 Published:2017-09-05
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21125730, 21607045), the National Key Basic Research Program (No. 2013CB934302) and the Strategic Priority Research Program A of the Chinese Academy of Sciences (No. XDA09030203).
铬作为首要战略金属之一，在国民经济中有着重要地位。我国铬资源匮乏，但同时铬渣污染问题严重，亟需解决。本文阐述了目前对铬渣进行解毒处理和对其中的铬提取处理这两大类技术的优缺点和所面临的瓶颈，指出对铬渣的物相及铬的赋存状态进行深入的微结构分析是实现铬渣中铬有效提取的核心关键。本文综述了目前国际上铬渣微结构分析的研究现状，总结了本研究团队将表界面调控晶相/晶面变化的微观机制的研究认识用以指导铬渣中铬的提取的研究进展，展望了这种新的研究思路和技术手段实现铬渣变废为宝的潜力和发展趋势。
关键词： 铬渣, 资源回收, 微观结构, 表界面调控, 晶体生长
As one of the primary strategic metal, chromium plays an important role in the national economy in China. However, the chromium resource is seriously insufficient meanwhile the chromium pollution is severe in China. This article elaborates the advantages and disadvantages of the current detoxification methods and chromium extraction methods for the chromium-containing residues as well as the bottlenecks they are faced with. It points out that, for developing an effective extraction method for chromium from chromium-containing residues, the micro-structural analysis for the mineral phases of the chromium-containing residues and the thorough investigation on the chemical states, combined forms and distribution of chromium in each mineral phase are crucial. Moreover, this article summarizes the current international research of the micro-structural analysis of chromium-containing residues. This article also introduces the work of our research group that applies the understanding of micro-mechanism of crystal growth and transformation under the surface/interface control on chromium extraction from chromium-containing residue. This new idea and technology are instructional for achieving the combination of detoxification and reclamation for chromium-containing residues. Finally, the potentiality and developing tendency of this idea as well as the technologies of chromium extraction from chromium-containing residue via crystal growth and mineral phase transformation are prospected.
Contents
1 Introduction
2 The current researches on disposal of chromium-containing residue
2.1 Detoxification methods
2.2 Chromium extraction methods
3 Micro-structural analysis of chromium-containing residue
4 Chromium extractions under the guidance of micro-structural analysis
5 Conclusion
Key words: chromium-containing residues, resource recycle, micro-structure, surface/interface control, crystal growth

中图分类号: 

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