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化学进展 2017, Vol. 29 Issue (9): 919-929 DOI: 10.7536/PC170504 前一篇   后一篇

• 综述 •

短链氯化石蜡的分析方法、污染现状与毒性效应

王亚韡1*, 王莹1,2, 江桂斌1   

  1. 1. 中国科学院生态环境研究中心 环境化学与生态毒理学国家重点实验室 北京 100085;
    2. 赣南师范大学化学化工学院 赣州 341000
  • 收稿日期:2017-05-03 修回日期:2017-06-05 出版日期:2017-09-15 发布日期:2017-09-05
  • 通讯作者: 王亚韡,e-mail:ywwang@rcees.ac.cn E-mail:ywwang@rcees.ac.cn
  • 基金资助:
    国家自然科学基金项目(No.21625702,21337002,21621064)和973项目(No.2015CB453100)资助

Analytical Methods, Environmental Pollutions and Toxicity of Short Chain Chlorinated Paraffins

Yawei Wang1*, Ying Wang1,2, Guibin Jiang1   

  1. 1. State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China;
    2. College of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou 341000, China
  • Received:2017-05-03 Revised:2017-06-05 Online:2017-09-15 Published:2017-09-05
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21625702, 21337002, 21621064), and the National Basic Research Program of China(973 Program) (No. 2015CB453100).
作为一种新型有机污染物,短链氯化石蜡(SCCPs)在2006年被列入斯德哥尔摩公约持久性有机污染物(POPs)候选名单。2017年5月第8次《关于持久性有机污染物的斯德哥尔摩公约》缔约方大会上,SCCPs最终被列入了《公约》附件A受控POPs清单。我国是氯化石蜡(CPs)生产使用大国,其在环境介质中的含量处于较高水平。本文对SCCPs的分析方法、污染现状、环境中来源与释放及其毒性效应进行了综述,并针对目前存在的问题及研究需求进行了总结。
Short chain chlorinated paraffins (SCCPs),as a class of emerging organic pollutants, have been listed in the candidates of potential persistent organic pollutants (POPs) under the Stockholm Convention(SC)in 2006, and the POPs review committees considered SCCPs to fulfill the criteria of Annex A of the SC in 2017. Due to their broad industrial production and application in China, SCCPs have been found in high levels in different environmental matrixes. In this paper, the sources, releases, analytical methods, the current pollution situation in various environmental matrixes and the toxicity of SCCPs are reviewed. Meanwhile, the problems in present studies and the future research demands are also summarized in this paper.
Contents
1 Introduction
2 The sources and releases of chlorinated paraffins
3 The analytical methods of short chain chlorinated paraffins
3.1 The pretreatment method
3.2 The instrument analysis
4 The current pollutions situation of short chain chlorinated paraffins in multi-environmental medium
4.1 Air and dust
4.2 Water
4.3 Sludge, sediment and soil
4.4 Organisms
4.5 Food
5 The toxicity of short chain chlorinated paraffins
6 Conclusion

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[1] Muir D C, Stern G, Tomy G, Paasivirta J. The Handbook of Environmental Chemistry.Vol. 3. Berlin Heidelberg:Springer-Verlag, 2000. 203.
[2] 张海军(Zhang H J), 高媛(Gao Y), 马新东(Ma X D), 耿柠波(Geng N B), 张亦弛(Zhang Y C), 陈吉平(Chen J P). 中国科学:化学(Science China Chemistry), 2013, 43(3):255.
[3] Chen M Y, Luo X J, Zhang X L, He M J, Chen S J, Mai B X. Environmental Science & Technology, 2011, 45(23):9936.
[4] 周浩郎(Zhou H L),邢永泽(Xing Y Z), 阎冰(Yan B). 广西科学院学报(Journal of Guangxi Academy of Sciences), 2016, 32(1):68.
[5] Bettina H, Hermann F, Wolfgang V L, Mehmet C. Environmental Science & Technology, 2011, 45(7):2842.
[6] Persistent Organic Pollutants Review Committee on the Work of its Twelfth Meeting:Draft Risk Management Evaluation:Short-Chained Chlorinated Paraffins, (2016-10-07).[2017-04-30]. http://chm.pops.int/TheConvention/POPsReviewCommittee/Meetings/POPRC12/Overview/tabid/5171/Default.aspx
[7] 吴苹(Wu P), 赫巍(He W), 张海军(Zhang H J),陈吉平(Chen J P), 余正坤(Yu Z K).现代化工(Modern Chemical Industry), 2013, (1):17.
[8] Feo M, Eljarrat E, Barcelo D. TrAC Trends in Analytical Chemistry, 2009, 28(6):778.
[9] Bayen S, Obbard J P, Thomas G O. Environment International, 2006, 32(7):915.
[10] Reth M, Zencak Z, Oehme M. Chemosphere, 2005, 58(7):847.
[11] Tomy G T, Fisk A T, Westmore J B, Muir D C. Reviews of Environmental Contamination and Toxicology. Berlin:Springer, 1998. 53.
[12] Report of the Persistent Organic Pollutants Review Committee on the Work of its Eleventh Meeting:Risk Profile on Short-Chained Chlorinated Paraffins, (2015-11-23).[2017-04-30]. http://chm.pops.int/TheConvention/POPsReviewCommittee/Meetings/POPRC11/Overview/tabid/4558/mctl/ViewDetails/EventModID/871/EventID/553/xmid/13837/Default.aspx
[13] Environment Agency (in Japanese). EA Chemicals in the Environment in 1980, Office of Health Studies, Environmental Health Department.1980.
[14] Zhang B Y, Zhao B, Xu C, Zhang J B. Science of the Total Environment, 2017, 581/582:582.
[15] Ali T E S, Legler J. The Handbook of Environmental Chemistry:Chlorinated Paraffins.Vol.10. Berlin Heidelberg:Springer-Verlag, 2010. 135.
[16] Dick T A, Gallagher C P, Tomy G T. World Review of Science, Technology and Sustainable Development, 2010, 7(4):387.
[17] Ma X D, Zhang H J, Wang Z, Yao Z W, Chen J W, Chen J P. Environmental Science & Technology, 2014, 48(10):5964.
[18] Castells P, Santos F, Galceran M. Journal of Chromatography A, 2004, 1025(2):157.
[19] Castells P, Santos F, Galceran M. Journal of Chromatography A, 2003, 984(1):1.
[20] Nicholls C, Allchin C, Law R. Environmental Pollution, 2001, 114(3):415.
[21] 陈茹(Chen R), 王亚韡(Wang Y W), 王璞(Wang P), 江桂斌(Jiang G B). 环境化学(Environmental Chemistry), 2014, 33(6):873.
[22] Luo X J, Sun Y X, Wu J P, Chen S J, Mai B X. Environmental Pollution, 2015, 198:41.
[23] Zeng L X, Wang T, Wang P, Liu Q, Han S L, Yuan B, Zhu N L, Wang Y W, Jiang G B. Environmental Science & Technology, 2011, 45(13):5529.
[24] Petersen A K. Short and Medium Chained Chlorinated Paraffins in Buildings and Constructionsin the EU, 2012.[2017-04-30]. http://www.dibk.no/globalassets/avfall-og-miljosanering/publikasjoner/master-thesis-fixed-karoline-petersen.pdf.
[25] Nøst T H, Halse A K, Randall S, Borgen A R, Schlabach M, Paul A, Rahman A, Breivik K. Environmental Science & Technology, 2015, 49(19):11372.
[26] Muir D, Braekevelt E, Tomy G, Whittle M. Organohalogen Compounds, 2003, 64:166.
[27] Gandolfi F, Malleret L, Sergent M, Doumenq P. Journal of Chromatography A, 2015, 1406:59.
[28] Zeng L X, Li H J, Wang T, Gao Y, Xiao K, Du Y G, Wang Y W, Jiang G B. Environmental Science & Technology, 2013, 47(2):732.
[29] Boreen A R, Schlabach M, Mariussen E. Organohalogen Compounds, 2003, 60:331.
[30] Castells P, Santos F, Galceran M. Organohalogen Compounds, 2002, 59:295.
[31] Korytar P, Parera J, Leonards P E G, Santos F J, De Boer J, Brinkman U T. Journal of Chromatography A, 2005, 1086(1):71.
[32] Korytar P, Leonards P E G, De Boer J, Brinkman U T. Journal of Chromatography A, 2005, 1086(1):29.
[33] Coelhan M. Analytical Chemistry, 1999, 71(20):4498.
[34] Iino F, Takasuga T, Senthilkumar K, Nakamura N, Nakanishi J. Environmental Science & Technology, 2005, 39(3):859.
[35] Tomy G, Stern G, Lockhart W, Muir D. Environmental Science & Technology, 1999, 33(17):2858.
[36] Štejnarová P, Coelhan M, Kostrhounová R, Parlar H, Holoubek I. Chemosphere, 2005, 58(3):253.
[37] Wang T, Yu J C, Han S L, Wang Y W, Jiang G B. Environmental Pollution, 2015, 196:309.
[38] Zeng L X, Zhao Z S, Li H J, Wang T, Liu Q, Xiao K, Du Y G, Wang Y W, Jiang G B. Environmental Science & Technology, 2012, 46(18):9898.
[39] Zhao Z S, Li H J, Wang Y W, Li G L, Cao Y L, Zeng L X, Lan J, Wang T, Jiang G B. Environmental Science & Technology, 2013, 47(10):5013.
[40] Zeng L X, Chen R, Zhao Z S, Wang T, Gao Y, Li A, Wang Y W, Jiang G B, Sun L G. Environmental Science & Technology, 2013, 47(20):11449.
[41] Zeng L X, Wang T, Han W Y, Yuan B, Liu Q, Wang Y W, Jiang G B. Environmental Science & Technology, 2011, 45(6):2100.
[42] Wang T, Han S L, Yuan B, Zeng L X, Li Y M, Wang Y W, Jiang G B. Environmental Pollution, 2012, 171:38.
[43] Gao W, Wu J, Wang Y W, Jiang G B. Chemosphere, 2016, 144:1327.
[44] Yuan B, Wang T, Zhu N L, Zhang K G, Zeng L X, Fu J J, Wang Y W, Jiang G B. Environmental Science & Technology, 2012, 46(12):6489.
[45] Zeng L, Lam J C, Wang Y W, Jiang G B, Lam P K. Environmental Science & Technology, 2015, 49(19):11348.
[46] Borgen A R, Schlabach M, Kallenborn R, Christensen G,Skotvold T. Organohalogen Compounds, 2002, 59:303.
[47] Sun R X, Luo X J, Tang B, Li Z R, Huang L Q, Wang T, Mai B X. Science of the Total Environment, 2016, 553:196.
[48] Fisk A T, Cymbalisty C D, Tomy G T, Muir D C. Aquatic Toxicology, 1998, 43(2):209.
[49] Thomas G O, Farrar D, Braekevelt E, Stern G, Kalantzi O I, Martin F L, Jones K C. Environment International, 2006, 32(1):34.
[50] Wang X T, Zhang Y, Miao Y, Ma L L, Li Y C, Chang Y Y, Wu M H. Environmental Science and Pollution Research, 2013, 20(7):4742.
[51] Ma X D, Chen C, Zhang H J, Gao Y, Wang Z, Yao Z W, Chen J P, Chen J W. Marine Pollution Bulletin, 2014, 79(1):299.
[52] Nilsson M L, Bengtsson S, Kylin H. Environmental Pollution, 2012, 163:142.
[53] Parera J, Abalos M, Santos F, Galceran M T, Abad E. Chemosphere, 2013, 93(3):499.
[54] Wang Y, Li J, Cheng Z N, Li Q L, Pan X H, Zhang R J, Liu D, Luo C L, Liu X, Katsoyiannis A. Environmental Science & Technology, 2013, 47(6):2679.
[55] Wang X T, Wang X K, Zhang Y, Chen L, Sun Y F, Li M, Wu M H. Science of the Total Environment, 2014, 490:144.
[56] Chaemfa C, Xu Y, Li J, Chakraborty P, Hussain S J, Naseem M R, Wang Y, Tian C G, Zhang G, Jones K C. Environmental Science & Technology, 2014, 48(9):4799.
[57] Geiß S, Einax J W, Scott S P. Clean-Soil, Air, Water, 2010, 38(1):57.
[58] Zencak Z, Reth M, Oehme M. Analytical Chemistry, 2003, 75(10):2487.
[59] Reth M, Oehme M. Analytical and Bioanalytical Chemistry, 2004, 378(7):1741.
[60] Gao W, Wu J, Wang Y W, Jiang G B. Journal of Chromatography A, 2016, 1452:98.
[61] Bogdal C, Alsberg T, Diefenbacher P S, MacLeod M, Berger U. Analytical Chemistry, 2015, 87(5):2852.
[62] Xia D, Gao L R, Zheng M H, Tian Q C, Huang H T. Environmental Science & Technology, 2016, 50(14):7601.
[63] Li T, Wan Y, Gao S X, Wang B L, Hu J Y. Environmental Science & Technology, 2017, 51(6):3346.
[64] Yuan B, Alsberg T, Bogdal C, MacLeod M, Berger U, Gao W, Wang Y W, de Wit C A. Analytical Chemistry, 2016, 88(18):8980.
[65] Li Q L, Li J, Wang Y, Xu Y, Pan X H, Zhang G, Luo C L, KobaraY, Nam J J, Jones K C. Environmental Science & Technology, 2012, 46(21):11948.
[66] Barber J L, Sweetman A J, Thomas G O, Braekevelt E, Stern G A, Jones K C. Environmental Science & Technology, 2005, 39(12):4407.
[67] Tomy G T. Dissertation Abstracts International Part B:Science and Engineering, 1998, 58(11):5932.
[68] Bidleman T, Alaee M, Stern G. Synopsis of Research Conducted under the 2000, 1999:93.
[69] Boreen A R, Schlabach M, Gundersen H. Organohalogen Compounds, 2000, 47:272.
[70] Ma X D, Zhang H J, Zhou H Q, Na G S, Wang Z, Chen C, Chen J W, Chen J P. Atomospheric Environment, 2014, 90:10.
[71] Fridén U E, Mclachlan M S, Berger U. Environment International, 2011, 37(7):1169.
[72] Hilger B, Fromme H, V lkel W, Coelhan M. Environmental Pollution, 2013, 175:16.
[73] Huang H T, Gao L R, Xia D, Qiao L, Wang R H, Su G J, Liu W B, Liu G R, Zheng M H. Enviromental Pollution, 2017, 225:674.
[74] 马新东(Ma X D), 陈晨(Chen C), 吕景才(Lv J C), 王震(Wang Z), 林忠胜(Lin Z S), 钟怡宁(Zhong Y N), 关奕(Guan Y), 姚子伟(Yao Z W). 海洋环境科学(Marine Environmental Science), 2014, 2:029.
[75] Houde M, Muir D C, Tomy G T, Whittle D M, Teixeira C, Moore S. Environmental Science & Technology, 2008, 42(10):3893.
[76] 于国龙(Yu G L).大连海事大学硕士论文(Master Dissertation of Dalian Maritime University), 2012.
[77] Zeng L X, Wang T, Ruan T, Liu Q, Wang Y W, Jiang G B. Environmental Pollution, 2012, 160:88.
[78] Wang Y W, Zhang Q H, Lv J X, Li A, Liu H X, Li G G, Jiang G B. Chemosphere, 2007, 68(9):1683.
[79] Yuan B, Wang Y W, Fu J J, Zhang Q H, Jiang G B. Chinese Science Bulletin, 2010, 55(22):2396.
[80] Fu J J, Wang Y W, Zhang Q H. Organohalogen Compounds, 2009, 71:1143.
[81] 夏青(Xia Q). 浙江工业大学硕士论文(Master Dissertation of Zhejiang University of Technology), 2012.
[82] Chen L G, Huang Y M, Han S, Feng Y B, Jiang G, Tang C M, Ye Z X, Zhan W, Liu M, Zhang S K. Journal of Chromatography A, 2013, 1274:36.
[83] Halse A K, Schlabach M, Schuster J K, Jones K C, Steinnes E, Breivik K. Environmental Pollution, 2015, 196:21.
[84] Gao Y, Zhang H J, Su F, Tian Y Z, Chen J P. Environmental Science & Technology, 2012, 46(7):3771.
[85] Castells P, Parera J, Santos F, Galceran M T. Chemosphere, 2008, 70(9):1552.
[86] Stern G, Evans M. Canadian Arctic Contaminants Assessment Report Ⅱ. Sources, Occurrence, Trends and Pathways in the Physical Environment. Northern Contaminants Program, Department of Indian Affairs and Northern Development, Ottawa, Ontario, 2003:100.
[87] Stern G A, Braekevelt E, Helm P A, Bidleman T F, Outridge P M, Lockhart W L, McNeeley R, Rosenberg B, Ikonomou M G, Hamilton P. Science of the Total Environment, 2005, 342(1):223.
[88] Lahaniatis M R, Coelhan M, Parlar H. Organohalogen Compounds, 2000, 47:276.
[89] Li H J, Fu J J, Zhang A Q, Zhang Q H, Wang Y W. Environment International, 2016, 94:408.
[90] Tomy G T, Muir D C, Stern G A, Westmore J B. Environmental Science & Technology, 2000, 34(9):1615.
[91] Reth M, Ciric A, Christensen G N, Heimstad E S, Oehme M. Science of the Total Environment, 2006, 367(1):252.
[92] Iozza S, Schmid P, Oehme M, Bassan R, Belis C, Jakobi G, Kirchner M, Schramm K W, Kräuchi N, Moche W. Environmental Pollution, 2009, 157(12):3225.
[93] Darnerud P O, Aune M, Glynn A, Borgen A. 2012 A Report ofthe Swedish Chemicals Agency:http://www.kemi.se/Documents/Publikationer/Trycksaker/PM/PM%2018_12.pdf
[94] Xia D, Gao L R, Zheng M H, Li J G, Zhang L, Wu Y N, Tian Q C, Huang H T, Qiao L. Environmental Science & Technology, 2017, 51:608.
[95] Thomas G, Jones K. A Report on a Research Project Funded by the Euro Chlor Chlorinated Paraffins Sector Group. Department of Environmental Sciences, Lancaster University, Lancaster, UK[cited in UK Environment Agency 2003a, b], 2002.
[96] Harada K H, Takasuga T, Hitomi T, Wang P Y, Matsukami H, Koizumi A. Environmental Science & Technology, 2011, 45(16):7019.
[97] Cao Y, Harada K H, Liu W Y, Yan J X, Zhao C, Niisoe T, Adachi A, Fujii Y, Nouda C, Takasuga T. Chemosphere, 2015, 138:104.
[98] Thompson R, Madeley J. Imperial Chemical Industries PLC, Devon, UK (Brixham Report BL/B/2358), 1983.
[99] Thompson R, Madeley J. Imperial Chemical Industries PLC, Devon, UK (Brixham Report BL/B/2373), 1983.
[100] Thompson R, Shillabeer N. ICI Confidential Report BL/B/2331, 1983.
[101] Cooley H, Fisk A, Wiens S, Tomy G T, Evans R E, Muir D C. Aquatic Toxicology, 2001, 54(1):81.
[102] Bur Dy šková B, Bláha L, Vršková D, Šimkova K, Maršalek B. Acta Veterinaria Brno, 2006, 75(1):115.
[103] Wyatt I, Coutss C, Elcombe C. Toxicology, 1993, 77(1):81.
[104] EC, European Union Risk Assessment Report. 1st Priority List Vol. 4:Alkanes, C10-13, Chloro-. European Commission. European Chemicals Bureau, Luxembourg. 166 pp. (EUR 19010; ISBN 92828-8451-1).
[105] Geng N B, Zhang H J, Zhang B Q, Wu P, Wang F D, Yu Z K, Chen J P. Environmental Science & Technology, 2015, 49(5):3076.
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