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化学进展 2017, Vol. 29 Issue (9): 1042-1052 DOI: 10.7536/PC170444 前一篇   后一篇

• 综述 •

溶解态黑碳的环境过程研究

魏晨辉1, 付翯云1*, 瞿晓磊1*, 朱东强1,2   

  1. 1. 南京大学环境学院 污染控制与资源化研究国家重点实验室 南京 210046;
    2. 北京大学城市与环境学院 北京 100871
  • 收稿日期:2017-04-27 修回日期:2017-07-20 出版日期:2017-09-15 发布日期:2017-09-05
  • 通讯作者: 付翯云,e-mail:heyunfu@nju.edu.cn;瞿晓磊,e-mail:xiaoleiqu@nju.edu.cn E-mail:heyunfu@nju.edu.cn;xiaoleiqu@nju.edu.cn
  • 基金资助:
    国家重点基础研究发展计划（No.2014CB441103）和国家自然科学基金项目（No.21407073，21622703）资助
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Environmental Processes of Dissolved Black Carbon

Chenhui Wei1, Heyun Fu1*, Xiaolei Qu1*, Dongqiang Zhu1,2   

  1. 1. State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210046, China;
    2. School of Urban and Environmental Sciences, Peking University, Beijing 100871, China
  • Received:2017-04-27 Revised:2017-07-20 Online:2017-09-15 Published:2017-09-05
  • Supported by:
    The work was supported by the National Key Basic Research Program of China (No. 2014CB441103) and the National Natural Science Foundation of China (No. 21407073, 21622703).
溶解态黑碳是黑碳连续体中可溶解于水的组分，是连接陆地土壤和海洋底泥两个主要黑碳库的关键纽带。溶解态黑碳也是天然可溶性有机质的重要组分，富含芳香微域结构和羧基、羟基、羰基等功能性官能团，具有较高的反应活性，可介导污染物在环境中的分配和转化过程。因此，研究溶解态黑碳的环境地球化学行为对研究全球碳循环以及污染物的环境归趋和效应都具有重要意义，已成为了相关领域的前沿和热点。本文综述了十余年以来溶解态黑碳在环境过程方面的研究进展，重点阐述了溶解态黑碳的定性、定量分析方法，在环境中的含量和空间分布、结构特征、环境转化过程，以及其对污染物吸附、氧化还原转化、光转化等环境行为的影响，并在此基础上对溶解态黑碳的未来研究方向进行了展望。
关键词： 溶解态黑碳, 时空分布, 结构特征, 污染物环境效应, 作用机制
Dissolved black carbon (DBC) is the water-soluble fraction of the black carbon continuum, being the key flux that connects two major black carbon pools:the soils and the ocean sediments. DBC is also an important component of the dissolved organic matter pool. It has rich aromatic clusters and oxygen-containing functional groups including carboxyl, hydroxyl, and carbonyl groups. DBC plays an important role in the sorption and environmental transformation of pollutants. Thus, research on the biogeochemical behavior of DBC is key to the understanding of the global carbon cycle as well as the environmental fate and impact of pollutants. The present paper reviews the previous studies on the environmental processes of DBC. The discussion covers the qualitative and quantitative analytical methods of DBC, its spatiotemporal distribution, its structural characteristics and environmental transformation, as well as its impacts on the sorption, redox transformation and photo transformation of pollutants in the environments. Then the new research directions addressing current knowledge gaps are proposed.
Contents
1 Introduction
2 Analytical methods and the spatiotemporal distribution of DBC
2.1 Qualitative and quantitative analytical methods for DBC
2.2 Spatiotemporal distribution of DBC
3 Structural characteristics and environmental transformation of DBC
3.1 Structural characteristics of DBC
3.2 Environmental transformation of DBC
4 Impacts of DBC on the environmental behavior of pollutants
4.1 Impacts of DBC on the sorption behavior of pollutants
4.2 Impacts of DBC on the redox reactions of pollutants
4.3 Impacts of DBC on the photoconversion reactions of pollutants
5 Conclusion
Key words: dissolved black carbon, spatiotemporal distribution, structural characteristics, environmental implications of pollutants, reaction mechanism

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摘要

溶解态黑碳的环境过程研究