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化学进展 2017, Vol. 29 Issue (11): 1316-1330 DOI: 10.7536/PC170424 前一篇   后一篇

• 综述 •

高性能的n-型和双极性有机小分子场效应晶体管材料

林高波, 罗婷, 袁铝兵, 梁文杰*, 徐海*   

  1. 中南大学化学化工学院 长沙 410083
  • 收稿日期:2017-04-14 修回日期:2017-09-22 出版日期:2017-11-15 发布日期:2017-10-27
  • 通讯作者: 徐海,e-mail:xhisaac@csu.edu.cn;梁文杰,e-mail:360043896@qq.com E-mail:xhisaac@csu.edu.cn;360043896@qq.com
  • 基金资助:
    国家自然科学基金项目（No.21290191）和长沙市科技计划（No.kq1606007）资助
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High Performance n-Type and Ambipolar Small Organic Semiconductors for Organic Field-Effect Transistors

Gaobo Lin, Ting Luo, Lvbing Yuan, Wenjie Liang*, Hai Xu*   

  1. College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
  • Received:2017-04-14 Revised:2017-09-22 Online:2017-11-15 Published:2017-10-27
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21290191), the Changsha Science and Technology Plan (No. kq1606007).
作为有机场效应晶体管的关键组成部分，有机半导体材料直接决定了器件的性能和稳定性。相比于p-型有机半导体材料，n-型和双极性有机半导体材料在迁移率和稳定性等方面则显著滞后。因此，n-型和双极性小分子有机半导体材料的设计与合成已成为高性能OFETs的学术研究的焦点。这篇综述重点突出了近十年报道的具有较好性能的n-型和双极性小分子有机半导体材料，并且对其结构和性能的关系进行了归纳，旨在对设计合成高性能、空气稳定的n-型和双极性有机小分子半导体材料提供一些指导帮助。
关键词： 小分子, 有机场效应晶体管, 双极性有机半导体材料, n-型有机半导体材料
Organic semiconductors, as the key component of organic feld-effect transistors (OFETs), determine the performance and stability of OFET devices directly. However, the overall development of n-type and ambipolar organic semiconductors still lags behind their p-type counterparts in terms of mobility, ambient stability, and so on. Thus, the design and synthesis of n-type and ambipolar organic semiconductors have become the focus of academic research for high-performance OFETs. In this review, high performance n-type and ambipolar small organic semiconductors are highlighted and their structure-property relationship is analyzed, which is aimed to provide some meaningful guidelines for designing high-performance n-type and ambipolar organic semiconductors.
Contents
1 Introduction
2 n-type small organic semiconductors
2.1 NDI and PDI-based small organic semiconductors
2.2 DPP-based small organic semiconductors
2.3 Small organic semiconductors containing thiophene or thiazole
2.4 Acene-based small organic semiconductors
3 Ambipolar small organic semiconductors
4 The principles for the design of high performance n-type and ambipolar small molecules
4.1 Molecular structure
4.2 HOMO and LUMO energy levels
4.3 Molecular arrangement
4.4 The introduction of substituent group
4.5 Other factors
5 Conclusion
Key words: small molecules, organic field-effect transistor(OFET), ambipolar organic semiconductors, n-type organic semiconductors

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