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化学进展 2017, Vol. 29 Issue (7): 750-756 DOI: 10.7536/PC170334 前一篇   后一篇

• 综述 •

光响应性微凝胶的分子设计和智能材料构筑

王平, 杨巧凤, 赵传壮*   

  1. 宁波大学材料科学与化学工程学院 宁波市特种高分子材料制备与应用技术重点实验室 宁波 315211
  • 收稿日期:2017-03-21 修回日期:2017-05-24 出版日期:2017-07-15 发布日期:2017-06-22
  • 通讯作者: 赵传壮 E-mail:zhaochuanzhuang@nbu.edu.cn
  • 基金资助:
    国家自然科学基金项目（No.21604044），宁波市自然科学基金项目（No.2015A610020，2016A610047）和宁波大学王宽诚幸福基金资助
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Molecular Design and Intelligent Material Construction of Light-Responsive Microgel

Ping Wang, Qiaofeng Yang, Chuanzhuang Zhao*   

  1. Faculty of Materials Science and Chemical Engineering, Ningbo Key Laboratory of Specialty Polymers, Ningbo University, Ningbo 315211, China
  • Received:2017-03-21 Revised:2017-05-24 Online:2017-07-15 Published:2017-06-22
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No.21604044),the Ningbo Natural Science Foundation (No.2015A610020,2016A610047) and the K.C.Wong Magna Fund in Ningbo University.
微凝胶能够在外界刺激下改变自身尺寸,是一类重要的智能材料构筑基元。光刺激具有可远程控制、能快速切换等特点,在刺激响应性材料的设计中受到了广泛关注。将光刺激响应性基元引入到微凝胶体系,可以得到一系列具有重要应用前景的智能材料。本文综述了近年来光响应微凝胶的研究进展,总结了赋予微凝胶光响应性的四种分子设计,包括光致异构化型、光致生热型、光致(解)交联型、光致生酸型;介绍了光响应微凝胶在调光材料、药物控释、信息显示和自修复凝胶等领域的应用;展望了该领域的研究方向、发展和应用前景。
关键词： 微凝胶, 光响应性, 智能材料, 水凝胶
Microgel can change its size under external stimuli, manifesting itself an important building block of intelligent materials. Because light stimulus enables remote control and rapid shifting, photo-responsive materials have drawn great attention of scientists. Introducing photo-responsiveness into microgel has greatly broadened the potential of applications of microgel. This review summarizes recent research progress on light-responsive microgel. Four types of light-responsive microgel are elaborated, including photo-isomerization, photo-thermal, photo-(de)crosslinking, and photo-acidifying. Also, a wide range of applications of light-responsive microgel are reviewed, including light-tuning, drug controlled releasing, information displaying and self-healing hydrogel. At last, a brief outlook on the future development of this field is presented.
Contents
1 Introduction
2 Molecular design of photo-responsive microgel
2.1 Photo-isomerization microgel
Key words: microgel, light responsive, intelligent material, hydrogel

中图分类号: 

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