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化学进展 2016, Vol. 28 Issue (10): 1550-1559 DOI: 10.7536/PC160516 前一篇   后一篇

• 综述与评论 •

非TiO2光催化剂去除气态VOCs

张晓东1*, 杨阳1, 李红欣1, 邹学军2*, 王玉新3*   

  1. 1. 上海理工大学环境与建筑学院环境与低碳科学研究中心 上海 200093;
    2. 大连民族大学环境与资源学院 大连 116600;
    3. 台州职业技术学院应用生物技术研究所 台州 318000
  • 收稿日期:2016-05-01 修回日期:2016-08-01 出版日期:2016-10-15 发布日期:2016-11-05
  • 通讯作者: 张晓东, 邹学军, 王玉新 E-mail:fatzhxd@126.com;zouxuejun@dlnu.edu.cn;wyx790914@aliyun.com
  • 基金资助:
    国家自然科学基金项目（No.21507086）和上海市青年科技英才扬帆计划（No.14YF1409900，16YF1408100）资助
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Non-TiO2 Photocatalysts Used for Degradation of Gaseous VOCs

Zhang Xiaodong1*, Yang Yang1, Li Hongxin1, Zou Xuejun2*, Wang Yuxin3*   

  1. 1. Environment and Low-Carbon Research Center, School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China;
    2. College of Environment and Resources, Dalian Nationalities University, Dalian 116600, China;
    3. Institute of Applied Biotechnology, Taizhou Vocation & Technical College, Taizhou 318000, China
  • Received:2016-05-01 Revised:2016-08-01 Online:2016-10-15 Published:2016-11-05
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21507086) and Shanghai Sailing Program (No. 14YF1409900, 16YF1408100).
本文综述了近年来非TiO2光催化剂降解气态挥发性有机物（VOCs）的研究现状。对一些有代表性的新型光催化剂，如金属氧化物、宽带隙p区金属氧化物/氢氧化物、钙钛矿类、尖晶石类、铋系化合物、钒系化合物等的结构与光催化性能之间的关系进行分析。另外，本文从VOCs初始浓度、流速、光源、光强、温度、湿度等光催化反应的工艺条件出发，概述了工艺参数对VOCs废气净化效果影响的研究进展；并对目前非TiO2光催化剂研究中存在的主要问题进行总结并展望。
关键词： 非TiO2光催化剂, 挥发性有机物, 环境净化, 机理
In this paper, research progress about the utilization of non-TiO2 photocatalysts in degradation of gaseous VOCs are reviewed. We give a concise overview of several novel non-TiO2 photocatalysts with a focus in their structure, which affect the catalytic activities, including metal oxide, wide bandgap p-block metal oxides/hydroxides, perovskite-type, spinel-type, bismuth based compounds, vanadium based compounds, et al. In addition, the research progress of influence factors of non-TiO2 photocatalytic purification of gaseous VOCs exhaust is summarized from photocatalytic reaction conditions (such as VOCs initial concentration, flow rate, light source, light intensity, reaction temperature and humidity). Finally, the fundamental challenges and perspectives of non-TiO2 photocatalysts are briefly brought up.

Contents
1 Introduction
2 Non-TiO2 photocatalytic oxidation of VOCs
2.1 Metal oxide photocatalysts
2.2 Wide bandgap p-block metal oxides/hydroxides photocatalysts
2.3 Perovskite-type oxides photocatalysts
2.4 Spinel-type photocatalysts
2.5 Bismuth based photocatalysts
2.6 Vanadium based photocatalysts
2.7 Other photocatalysts
3 The effect of process parameters on VOCs purification
3.1 The initial concentration of VOCs and flow rate
3.2 The light source and light intensity
3.3 Temperature and humidity
3.4 Other parameters
4 Conclusion and outlook

Key words: non-TiO2 photocatalysts, volatile organic compounds, environmental purification, mechanism

中图分类号: 

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[1] Ou J M, Zheng J Y, Li R R, Huang X B, Zhong Z M, Zhong L J, Lin H. Sci. Total Environ., 2015, 530/531:393.
[2] 张晓东(Zhang X D), 王吟(Wang Y), 杨一琼(Yang Y Q), 陈丹(Chen D).物理化学学报(Acta Physico-Chimica Sinica), 2015, 31(9):1633.
[3] Fujishima A, Honda K. Nature, 1972, 238:37.
[4] 邹学军(Zou X J), 李新勇(Li X Y), 曲振平(Qu Z P), 王疆疆(Wang J J). 环境科学(Environmental Science), 2011, 32(12):3694.
[5] 邹学军(Zou X J), 李新勇(Li X Y), 肇启东(Zhao Q D), 陈国华(Chen G H). 高等学校化学学报(Chemical Journal of Chinese Universities), 2012, 33(5):1046.
[6] Zou X J, Li X Y, Qu Z P, Zhao Q D, Shi Y, Chen Y Y, Tade M, Liu S M. Mater. Res. Bull., 2012, 47:279.
[7] Zou X J, Li X Y, Zhao Q D, Liu S M. J. Colloid Interface Sci., 2012, 383:13.
[8] Li X Y, Zou X J, Qu Z P, Zhao Q D, Wang L Z. Chemosphere, 2011, 83:674.
[9] Zou X J, Dong Y Y, Zhang X D, Cui Y B. Appl. Surf. Sci., 2016, 366:173.
[10] Fagan R, McCormack D E, Dionysiou D D, Pillai S C. Mater. Sci. Semicond. Process., 2016, 42:2.
[11] Huang Y, Ho S S H, Lu Y F, Niu R Y, Xu L F, Cao J J, Lee S C. Molecules, 2016, 21:56.
[12] 崔星(Cui X), 石建稳(Shi J W),陈少华(Chen S H). 化工进展(Chemical Industry and Engineering Progress), 2013, 32(10):2377.
[13] 王会香(Wang H X), 姜东(Jiang D), 吴东(Wu D), 李德宝(Li D B), 孙予罕(Sun Y H). 化学进展(Progress in Chemistry), 2012, 24(11):2116.
[14] Wang Y X, Li X Y, Lu G, Quan X, Chen G H. J. Phys. Chem. C, 2008, 112:7332.
[15] Wang Y X, Li X Y, Lu G, Chen G H, Chen Y Y. Mater. Lett., 2008, 62:2359.
[16] Wang Y X, Li X Y, Wang N, Quan X, Chen Y Y. Sep. Purif. Technol., 2008, 62:727.
[17] Liao Y C, Xie C S, Liu Y, Huang Q W. J. Alloys Compd., 2013, 550:190.
[18] Rezaee A, Rangkooy H, Khavanin A, Jafari A J. Environ. Chem. Lett., 2014, 12:353.
[19] Xie W, Li Y Z, Shi W Q, Zhao L, Zhao X J, Fang P F, Zheng F, Wang S J. Chem. Eng. J., 2013, 213:218.
[20] Wang Y X, Yang Y Q, Xi L M, Zhang X D, Jia M H, Xu H M, Wu H G. Mater. Lett., 2016, 180:55.
[21] Yang Y Q, Li H X, Hou F L, Hu J Y, Zhang X D, Wang Y X. Mater. Lett., 2016, 180:97.
[22] Zhang X D, Wang Y X, Hou F L, Li H X, Yang Y, Yang Y Q, Wang Y. Appl. Surf. Sci., doi:10.1016/j.apsusc.2016.06.109.
[23] Chu D R, Mo J H, Peng Q, Zhang Y P, Wei Y G, Zhuang Z B, Li Y D. ChemCatChem., 2011, 3:371.
[24] Zhang F, Li X Y, Zhao Q D, Zhang Q Z, Tadé M, Liu S M. J. Colloid Interface Sci., 2015, 457:18.
[25] 曲振平(Qu Z P), 张晓东(Zhang X D), 陈丹(Chen D), 李新勇(Li X Y), 闻梦(Weng M), 王奕(Wang Y), 马丁(Ma D), 吴晶晶(Wu J J). 高等学校化学学报(Chemical Journal of Chinese Universities), 2011, 32(7):1605.
[26] Qu Z P, Yu F L, Zhang X D, Wang Y, Gao J S. Chem. Eng. J., 2013, 229:522.
[27] Mao M Y, Lv H Q, Li Y Z, Yang Y, Zeng M, Li N, Zhao X J. ACS Catal., 2016, 6:418.
[28] Li Y Z, Sun Q, Kong M, Shi W Q, Huang J C, Tang J W, Zhao X J. J. Phys. Chem. C, 2011, 115:14050.
[29] Qu Z P, Bu Y B, Qin Y, Gao K, Wang Y, Fu Q. Appl. Catal. B, 2013, 132/133:353.
[30] Qu Z P, Bu Y B, Qin Y, Wang Y, Fu Q. Chem. Eng. J., 2012, 209:163.
[31] Liu F, Zeng M, Li Y Z, Yang Y, Mao M Y, Zhao X J. Adv. Funct. Mater., 2016, 26:4518.
[32] Yu F L, Qu Z P, Zhang X D, Fu Q, Wang Y. J. Energy Chem., 2013, 22(6):845.
[33] Jiang D, Wang W Z, Zhang L, Qiu R H, Sun S M, Zheng Y L. Appl. Catal. B, 2015, 165:399.
[34] Wang G, Huang B B, Lou Z Z, Wang Z Y, Qin X Y, Zhang X Y, Dai Y. Appl. Catal. B, 2016, 180:6.
[35] Zheng Y L, Wang W Z, Jiang D, Zhang L. Chem. Eng. J., 2016, 284:21.
[36] Ma Y, Li Y Z, Mao M Y, Hou J T, Zeng M, Zhao X J. J. Mater. Chem. A, 2015, 3:5509.
[37] Hou J T, Li Y Z, Mao M Y, Yue Y Z, Greaves G N, Zhao X J. Nanoscale, 2015, 7:2633.
[38] Mao M Y, Li Y Z, Hou J T, Zeng M, Zhao X J. Appl. Catal. B, 2015, 174:496.
[39] Liu H H, Li Y Z, Yang Y, Mao M Y, Zeng M, Lan L, Yun L, Zhao X J. J. Mater. Chem. A, 2016, 4:9890.
[40] Zheng Y L, Wang W Z, Jiang D, Zhang L, Li X M, Wang Z. J. Mater. Chem. A, 2016, 4:105.
[41] 李朝晖(Li Z H), 刘平(Liu P), 付贤智(Fu X Z). 物理化学学报(Acta Physico-Chimica Sinica), 2010, 26(4):877.
[42] Hou Y D, Wu L, Wang X C, Ding Z X, Li Z H, Fu X Z. J. Catal., 2007, 250:12.
[43] Sun M, Li D Z, Zhang W J, Fu X Z, Shao Y, Li W J, Xiao G C, He Y H. Nanotechnology, 2010, 21(35):355601.
[44] Li Z H, Xie Z P, Zhang Y F, Wu L, Wang X X, Fu X Z. J. Phys. Chem. C, 2007, 111:18348.
[45] Yan T J, Long J L, Chen Y S, Wang X X, Li D Z, Fu X Z. C. R. Chimie., 2008, 11:101.
[46] Xue H, Li Z H, Wu L, Ding Z X, Wang X X, Fu X Z. J. Phys. Chem. C, 2008, 112:5850.
[47] Sun M, Li D Z, Zhang W J, Chen Z X, Huang H J, Li W J, He Y H, Fu X Z. J. Phys. Chem. C, 2009, 113:14916.
[48] Huang R K, Xu X M, Zhu J, Liu W J, Yuan R S, Fu X Z, Zhang Y F, Li Z H. Appl. Catal. B, 2012, 127:205.
[49] Fu X L, Wang X X, Ding Z X, Y.C. Leung D, Zhang Z Z, Long J L, Zhang W X, Li Z H, Fu X Z. Appl. Catal. B, 2009, 91:67.
[50] Fu X L, Huang D W, Qin Y, Li L F, Jiang X L, Chen S F. Appl. Catal. B, 2014, 148/149:532.
[51] Huang D W, Fu X L, Long J L, Jiang X L, Chang L, Meng S G, Chen S F. Chem. Eng. J., 2015, 269:168.
[52] Li H Q, Hong W S, Cui Y M, Jia Q F, Fan S H. J. Mol. Catal. A, 2013, 378:164.
[53] Meng S G, Li D Z, Sun M, Li W J, Wang J X, Chen J, Fu X Z, Xiao G C. Catal. Commun., 2011, 12:972.
[54] Sun M, Li D Z, Zheng Y, Zhang W J, Shao Y, Chen Y B, Li W J, Fu X Z. Environ. Sci. Technol., 2009, 43:7877.
[55] Luo Y P, Chen J, Liu J W, Shao Y, Li X F, Li D Z. Appl. Catal. B, 2016, 182:533.
[56] Marchelek M, Bajorowicz B, Mazierski P, Cybula A, Klimczuk T, Winiarski M, Fija?kowsk N, Zaleska A. Catal. Today, 2015, 252:47.
[57] Nath R K, Zain M F M, Kadhum A A H, Kaish A B M A. Constr. Build Mater., 2014, 54:348.
[58] Chen Y B, Li D Z, Chen J, Wang J X, Meng S G, Xian J G, Fu X Z, Shao Y. Appl. Catal. B, 2013, 129:403.
[59] Zhang X N, Huang J H, Ding K N, Hou Y D, Wang X C, Fu X Z. Environ. Sci. Technol., 2009, 43:5947.
[60] Sun M, Li D Z, Zhang W J, Chen Z X, Huang H J, Li W J, He Y H, Fu X Z. J. Solid State Chem., 2012, 190:135.
[61] Li X Y, Zhu Z R, Zhao Q D, Wang L Z. J. Hazard. Mater., 2011, 186:2089.
[62] Zhu Z R, Zhao Q D, Li X Y, Li H, Moses T, Liu S M. Catal. Sci. Technol., 2013, 3:788.
[63] Zhu Z R, Liu F Y, Zhang W. Mater. Res. Bull., 2015, 64:68.
[64] Zhu Z R, Li X Y, Zhao Q D, Li H, Shen Y, Chen G H. Chem. Eng. J., 2010, 165:64.
[65] Ai Z H, Lee S C, Huang Y, Ho W K, Zhang L Z. J. Hazard. Mater., 2010,179:141.
[66] He R A, Cao S W, Zhou P, Yu J G. Chin. J. Catal., 2014, 35:989.
[67] Zou X J, Dong Y Y, Zhang X D, Cui Y B, Ou X X, Qi X H. Appl. Surf. Sci., doi:10.1016/j.apsusc.2016.06.003.
[68] Ai Z H, Huang Y, Lee S C, Zhang L Z. J. Alloys Compd., 2011, 509:2044.
[69] Rifath S, Ray M. B. J. Air Waste Manage. Assoc., 2012, 62(9):1032.
[70] Li H Q, Cui Y M, Hong W S. Appl. Surf. Sci., 2013, 264:581.
[71] Cheng J, Shi S X, Tang T T, Tian S Q, Yang W J, Zeng D W. J. Alloys Compd., 2015, 643:159.
[72] Chen Y L, Cao X X, Kuang J D, Chen Z, Chen J L, Lin B Z. Catal. Commun., 2010, 12:247.
[73] Guo S, Li X F, Wang H Q, Dong F, Wu Z B. J. Colloid Interface Sci., 2012, 369:373.
[74] 吴大旺(Wu D W), 李硕(Li S), 陈耀强(Chen Y Q), 龚茂初(Gong M C), 张秋林(Zhang Q L),刘康莲(Liu K L), 王玉林(Wang Y L).物理化学学报(Acta Physico-Chimica Sinica), 2010, 26(12):3299.
[75] 李思佳(Li S J), 邹学军(Zou X J), 董玉瑛(Dong Y Y), 李新勇(Li X Y), 杨宝灵(Yang B L). 化工环保(Environmental Protection of Chemical Industry), 2015, 35(2):182.
[76] Chang W S, Li Y C M, Chung T W, Lin Y S, Huang C M. Appl. Catal. A, 2011, 407:224.
[77] 陈亦琳(Chen Y L), 操小鑫(Cao X X), 林碧洲(Lin B Z).无机材料学报(Journal of Inorganic Materials), 2011, 26(5):508.
[78] He Y M, Zhao L H, Wang Y J, Lin H J, Li T T, Wu X T, Wu Y. Chem. Eng. J., 2011, 169:50.
[79] Chen F, Wu T H, Zhou X P. Catal. Commun., 2008, 9:1698.
[80] Luo L, Li Y Z, Hou J T, Yang Y. Appl. Surf. Sci., 2014, 319:332.
[81] Kontelles-carceller O, Muñoz-Batista M J, Fernández-García M, Kubacka A. ACS Appl. Mater., 2016, 8:2617.
[82] Zou X J, Dong Y Y, Li X Y, Zhao Q D, Cui Y B, Lu G. Catal. Commun., 2015, 69:109.
[83] Zou X J, Ran C Q, Dong Y Y, Chen Z B, Dong D P, Hu D X, Li X Y, Cui Y B. RSC Adv., 2016, 6:20664.
[84] Anpo M, Shioya Y, Yamashita H, Giamello E, Morterra C, Che M, Patterson H H, Webber S, Ouellette S. J. Phys. Chem., 1994, 98(22):5744.
[85] Yamashita H, Matsuoka M, Tsuji K, Shioya Y, Anpo M. J. Phys. Chem., 1996, 100(1):397.
[86] Kato Y, Yoshida H, Satsuma A, Hattori T. Micropor. Mesopor. Mater., 2002, 51:223.
[87] Yan G Y, Long J L, Wang X X, Li Z H, Fu X Z. C. R. Chimie., 2008, 11:114.
[88] Yan G Y, Wang X X, Fu X Z, Li D Z. Catal. Today, 2004, 93/95:851.
[89] Blatter F, Sun H, Vasenkov S, Frei H. Catal.Today, 1998, 41(4):297.
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摘要

非TiO2光催化剂去除气态VOCs