English
往期目录
新闻公告
More
化学进展 2016, Vol. 28 Issue (8): 1238-1250 DOI: 10.7536/PC160105 前一篇   后一篇

• 综述与评论 •

改性聚苯胺及其衍生物涂层的防腐性能

胡传波1,2, 厉英1,2*, 孔亚州1,2, 丁玉石1,2   

  1. 1. 东北大学冶金学院 沈阳 110819;
    2. 东北大学辽宁省冶金传感器及技术重点实验室 沈阳 110819
  • 收稿日期:2016-01-01 修回日期:2016-04-01 出版日期:2016-08-15 发布日期:2016-07-12
  • 通讯作者: 厉英 E-mail:liying@mail.neu.edu.cn
  • 基金资助:
    国家自然科学基金项目（No.51274057，51474057）项目资助
下载PDF ( 476 ) 引用
导出 被引次数 ( 1 | 2 )

Anticorrosion Properties of Modified Polyanilines and Its Derivatives Coatings

Hu Chuanbo1,2, Li Ying1,2*, Kong Yazhou1,2, Ding Yushi1,2   

  1. 1. School of Metallurgy, Northeastern University, Shenyang 110819, China;
    2. Liaoning Key Laboratory for Metallurgicall Sensor and Technology, Northeastern University, Shenyang 110819, China
  • Received:2016-01-01 Revised:2016-04-01 Online:2016-08-15 Published:2016-07-12
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 51274057, 51474057
导电聚合物作为一种新型高分子材料，由于具有可逆的氧化还原特性，在金属腐蚀防护领域具有潜在的应用前景。在众多的导电聚合物中，聚苯胺因其具有独特的抗点蚀、抗划伤和防止海洋生物附着等特殊性能，被广泛应用于金属材料、化学工业和航海航天等领域， 逐渐成为防腐涂料领域的研究热点。本文通过对单一聚苯胺涂层防腐性能不足的分析，系统总结了近年来改性聚苯胺涂层在金属腐蚀防护领域的研究进展，包括单一环取代聚苯胺涂层和N取代聚苯胺涂层、改性聚苯胺复合涂层和改性聚苯胺复合材料/树脂共混复合涂层；通过各种腐蚀测试手段比较了改性聚苯胺涂层与未改性聚苯胺涂层之间防腐性能的优劣，进一步证明了供电子取代基（如烷基、烷氧基和氨基等）能够提高聚苯胺涂层的防腐性能，复合改性或与树脂共混也能够提高聚苯胺及其衍生物涂层的防腐性能；同时展望了聚苯胺及其衍生物涂料未来发展的新趋势。
关键词： 导电聚合物, 聚苯胺, 防腐性能, 供电子取代基, 复合改性
Conducting polymers represent a promising application prospect in the field of metal corrosion protection as a new polymer material since its reversible redox properties. Among the conducting polymers, polyaniline has become the focus in the anticorrosion coating field and has been widely applied in many fields like metal materials, chemistry industry, navigation and spaceflight because of its unique resistance to pitting corrosion and scratch and its inhibition to adhesion of marine organisms. In this paper, through the analysis of the deficient anticorrosion properties of the single polyaniline coatings, the research progress of modified polyaniline coatings in the field of metal corrosion protection in recent years are summarized, including a single ring substituted polyaniline coatings and N-substituted polyaniline coatings, modified polyaniline composite coatings and modified polyaniline composite materials/resin blending hybrid coatings. The anticorrosion properties of the modified polyaniline coatings and the unmodified polyaniline coatings are compared by various corrosion test methods, further proving that the electron-donating substituents (e.g., alkyl, alkoxy, amino, etc.) can improve the anticorrosion properties of polyaniline coatings, composite modification or blended with resin can also improve the anticorrosion properties of polyaniline and its derivatives. Meanwhile, the future study and development trend of polyaniline and its derivatives are prospected.

Contents
1 Introduction
2 Anticorrosion properties of substituted polyaniline derivatives
2.1 Ring substituted polyaniline derivatives
2.2 N-substituted polyaniline derivatives
3 Anticorrosion properties of polyaniline and its derivatives' composites
3.1 Polyaniline/inorganic composites
3.2 Polyaniline/polymer composites
3.3 Substituted polyaniline composites
3.4 Polyaniline and its derivatives composites/resin hybrid composites
4 Conclusion and outlook

Key words: conducting polymers, polyaniline, anticorrosion properties, the electron-donating substituents, composite modification

中图分类号: 

()
[1] Deshpande P P,Jadhav N G,Gelling V J,Sazou D.J.Coat.Technol.Res.,2014,11(4):473.
[2] Xing C J,Zhang Z M,Yu L M,Waterhouse G I N,Zhang L J.Prog.Org.Coat.,2014,77(2):354.
[3] Xiong S X,Wei J,Jia P T,Yang L P,Ma J,Lu X H.ACS Appl.Mater.Inter.,2011,3(3):782.
[4] Olad A,Barati M,Behboudi S.Prog.Org.Coat.,2012,74(1):221.
[5] Gülce H,Eskizeybek V,Haspulat B,Sar? F,Gülce A,Avc? A.Ind.Eng.Chem.Res.,2013,52(32):10924.
[6] Kurtan U,Junejo Y,Vnal B,Baykal A.J.Inorg.Organomet.Polym.,2013,23(5):1089.
[7] Schauer T,Joos A,Dulog L,Eisenbach C D.Prog.Org.Coat.,1998,33(1):20.
[8] Jaymand M.Prog.Polym.Sci.,2013,38(9):1287.
[9] Yeole K V,Mahajan L H,Mhaske S T.Polym.Compos.,2015,36(8):1477.
[10] Rehim S S A E,Sayyah S M,Deeb M M E,Kamal S M,Azooz R E.Mater.Chem.Phys.,2010,123(1):20.
[11] Chaudhari S,Patil P P.Electrochim.Acta,2010,55(12):6715.
[12] Arjomandi J,Tadayyonfar S.Polym.Compos.,2014,35(2):351.
[13] Eskizeybek V,Sar? F,Gülce H,Gülce A,Avc? A.Appl.Catal.B:Environ.,2012,119/120(30):197.
[14] Yan J,Yang Y W,Ma L,Gan M Y,Li X.Polym.Compos.,2015,36(8):1541.
[15] Li Z T,Ma L,Gan M Y,Yan J,Hu H F,Zeng J,Chen F F.Polym.Compos.,2013,34(5):740.
[16] Bilal S,Farooq S,Shah A H A,Holze R.Synth.Met.,2014,197:144.
[17] Shinde V,Patil P P.Mater.Sci.Eng.B,2010,168(1/3):142.
[18] Ma L,Huang C Q,Gan M Y.J.Appl.Polym.Sci.,2012,127(5):3699.
[19] Shinde V,Gaikwad A B,Patil P P.Appl.Surf.Sci.,2006,253(3):1037.
[20] Shinde V,Sainkar S R,Gangal S A,Patil P P.J.Mater.Sci.,2006,41(10):2851.
[21] Ghoreishi S M,Nooshabadi M S,Behpour M,Jafari Y.Prog.Org.Coat.,2012,74(3):502.
[22] Chaudhari S,Patil P P.Electrochim.Acta,2007,53(2):927.
[23] Yano J,Muta A,Harima Y,Kitani A.J.Solid State Electrochem.,2011,15(3):601.
[24] Yano J,Ota Y,Kitani A.Mater.Lett.,2004,58(12/13):1934.
[25] Lindfors T,Ivaska A.J.Electroanal.Chem.,2002,535(1/2):65.
[26] Duran B,Bereket G,Turhan M C,Virtanen S.Thin Solid Films,2011,519(18):5868.
[27] Duran B,Turhanb M C,Bereketa G,Saraç A S.Electrochim.Acta,2009,55(1):104.
[28] Ya?an A,Pekmez N Ö,Y?ld?z A.Synth.Met.,2006,156(9/10):664.
[29] Olad A,Nosrati R.Prog.Org.Coat.,2013,76(1):113.
[30] Piromruen P,Kongparakul S,Prasassarakich P.Prog.Org.Coat.,2014,77(3):691.
[31] Olad A,Rasouli H.J.Appl.Polym.Sci.,2010,115(4):2221.
[32] Chaudhari S,Patil P P.Electrochim.Acta,2011,56(8):3049.
[33] Ozyilmaz A T,Akdag A,Karahan I H,Ozyilmaz G.Prog.Org.Coat.,2014,77(4):872.
[34] Karpakam V,Kamaraj K,Sathiyanarayanan S.J.Electrochem.Soc.,2011,158(12):C416.
[35] Zubillaga O,Cano F J,Azkarate I,Molchan I S,Thompson G E,Cabral A M,Morais P J.Surf.Coat.Technol.,2008,202(54):5936.
[36] Yu Q J,Xu J M,Liu J,Li B X,Liu Y J,Han Y Y.Appl.Surf.Sci.,2012,263:532.
[37] Deyab M A.J.Power Sources,2014,268(5):50.
[38] Kalendová A,Sapurina I,Stejskal J,Vesel Dy'D.Corros.Sci.,2008,50(12):3549.
[39] Chang C H,Huang T C,Peng C W,Yeh T C,HLu H I,Hung W I,Weng C J,Yang T I,Yeh J M.Carbon,2012,50(14):5044.
[40] Thinh P X,Kim J K,Huh D S.Polymer,2014,55(20):5168.
[41] Raotole P M,Koinkar P,Joshi B,Patil S R.J.Coat.Technol.Res.,2015,12(4):757.
[42] Xing C J,Zhang Z M,Yu L M,Zhang L J,Bowmaker G A.RSC Adv.,2014,4:32718.
[43] Narayanasamy B,Rajendran S.Prog.Org.Coat.,2010,67(3):246.
[44] Panah N B,Danaee I.Prog.Org.Coat.,2010,68(3):214.
[45] Syed J A,Tang S C,Lu H B,Meng X K.Ind.Eng.Chem.Res.,2015,54(11):2950.
[46] Chaudhari S,Gaikwad A B,Patil P P.J.Coat.Technol.Res.,2010,7(1):119.
[47] Jafari Y,Nooshabadi M S,Ghoreishi S M.Polym.Adv.Technol.,2014,25(3):279.
[48] Mert B D,Yaz?c? B.Mater.Chem.Phys.,2011,125(3):370.
[49] Yalç?nkaya S,Tüken T,Yaz?c? B,Erbil M.Curr.Appl.Phys.,2010,10(3):783.
[50] Zhang Y J,Shao Y W,Zhang T,Meng G Z,Wang F H.Prog.Org.Coat.,2013,76(5):804.
[51] Lim T S,Ryu H S,Hong S H.Corro.Sci.,2012,62:104.
[52] Mostafaei A,Nasirpouri F.Prog.Org.Coat.,2014,77(1):146.
[53] Jamari S K M,Kasi R,Ismail L,Nor N A M,Subramanian R R,Subramaniam T R,Balakrishnan V,Arof A K M.Pigm.Resin.Technol.,2016,45(1):18.
[54] Hu C B,Zheng Y S,Qing Y Q,Wang F L,Mo C Y,Mo Q.J.Inorg.Organomet.Polym.,2015,25(3):583.
[55] Ma L,Fu D D,Gan M Y,Zhang F,Li Z T,Li S.J.Appl.Polym.Sci.,2013,130(6):4528.
[56] Gupta G,Birbilis N,Khanna A S.Int.J.Electrochem.Sci.,2013,8:3132.
[57] Rawat N K,Sinha A K,Ahmad S.RSC Adv.,2015,5:94933.
[1] 吴磊, 刘利会, 陈淑芬. 基于碳基透明电极的柔性有机电致发光二极管[J]. 化学进展, 2021, 33(5): 802-817.
[2] 鲍长远, 韩家军*, 程瑾宁, 张瑞涛. 石墨烯-聚苯胺类超级电容器复合电极材料[J]. 化学进展, 2018, 30(9): 1349-1363.
[3] 舒昕, 李兆祥, 夏江滨. 聚噻吩的合成方法[J]. 化学进展, 2015, 27(4): 385-394.
[4] 杨雷, 程涛, 曾文进, 赖文勇, 黄维. 导电聚合物薄膜的喷墨打印制备及其光电器件[J]. 化学进展, 2015, 27(11): 1615-1627.
[5] 宿丹, 第凤, 邢季, 车剑飞, 肖迎红. 导电聚合物在药物可控释放领域的应用[J]. 化学进展, 2014, 26(12): 1962-1976.
[6] 康丁, 张洪斌, 西成胜好. 生物医用结冷胶及其改性水凝胶材料[J]. 化学进展, 2014, 26(07): 1172-1189.
[7] 李庆川, 曹立新, 胡海峰, 王凯, 闫培生. 黄曲霉毒素电化学生物传感器[J]. 化学进展, 2014, 26(04): 657-664.
[8] 苗力孝, 王维坤, 王梦佳, 段博超, 杨裕生, 王安邦. 含单质硫正极复合材料[J]. 化学进展, 2013, 25(11): 1867-1875.
[9] 肖横洋, 第凤, 车剑飞, 肖迎红. 神经元电极的表面修饰及其功能化设计[J]. 化学进展, 2013, 25(11): 1962-1972.
[10] 任芳芳, 蒋丰兴, 周卫强, 杜玉扣*, 徐景坤*. 导电聚合物/贵金属复合材料应用于C1小分子电催化氧化[J]. 化学进展, 2012, (9): 1818-1836.
[11] 朱英, 刘明杰, 万梅香, 江雷. 一维纳米纤维构筑的导电聚合物三维结构及其可控的浸润性[J]. 化学进展, 2011, 23(5): 819-828.
[12] 涂亮亮 贾春阳 翁小龙 邓龙江 唐武. 导电聚合物电致变色材料*[J]. 化学进展, 2010, 22(10): 2053-2059.
[13] 涂亮亮 贾春阳. 导电聚合物超级电容器电极材料*[J]. 化学进展, 2010, 22(08): 1610-1618.
[14] 董彬,徐景坤,郑利强. 离子液体应用于电合成导电聚合物* [J]. 化学进展, 2009, 21(09): 1792-1799.
[15] 安红芳,王先友,李娜,郑丽萍,陈权启. 超级电容器用炭/导电聚合物复合材料*[J]. 化学进展, 2009, 21(09): 1832-1838.