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化学进展 2016, Vol. 28 Issue (5): 673-685 DOI: 10.7536/PC151208 前一篇   后一篇

• 综述与评论 •

低分子量含氟聚合物的制备、官能化及特性

李东翰1, 齐士成2, 张孝阿2, 廖明义1*   

  1. 1. 大连海事大学交通运输装备与海洋工程学院 大连 116026;
    2. 北京化工大学材料科学与工程学院 北京 100029
  • 收稿日期:2015-12-01 修回日期:2015-12-01 出版日期:2016-05-15 发布日期:2016-03-25
  • 通讯作者: 廖明义 E-mail:liaomy2000@sohu.com
  • 基金资助:
    国家国际科技合作专项项目(No.2015DFR40500)资助
下载PDF ( 1814 ) 引用
导出 被引次数 ( 3 | 4 )

Preparation, Functionalization and Properties of Low Molecular Fluoropolymers

Li Donghan1, Qi Shicheng2, Zhang Xiaoa2, Liao Mingyi1*   

  1. 1. College of Transportation Equipments and Ocean Engineering, Dalian Maritime University, Dalian 116026, China;
    2. College of Material Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • Received:2015-12-01 Revised:2015-12-01 Online:2016-05-15 Published:2016-03-25
  • Supported by:
    The work was supported by the International Science & Technology Cooperation Program of China (ISTCP) (No.2015DFR40500).
低分子量含氟聚合物是重要的新型功能材料,在国防工业中占有特殊地位。同时,作为高科技战略物资,近年来逐渐成为研究热点。本文对低分子量含氟聚合物的制备方法、官能化及特性进行了综述,重点介绍了低分子量含氟聚合物的制备和官能化方法的研究进展,并总结和详细介绍了低分子量含氟聚合物的特性,最后对该领域的前景和发展方向进行了展望。
关键词： 低分子量含氟聚合物, 制备, 官能化, 特性
Low molecular fluoropolymers have a special status in the defense industry as the important new functional materials. Meanwhile, as high-tech strategic materials, they have attracted more attention. Low molecular fluoropolymers, not only have excellent performance of traditional fluoropolymers, but also have irreplaceable characteristics. In the present study, the preparation, functionalization, and properties of low molecular fluoropolymers are reviewed. The study highlights the research progress in the preparation and functionalization methods. The properties of low molecular fluoropolymers are also summarized. Finally, the future development of low molecular fluoropolymers is prospected.

Contents
1 Introduction
2 Preparation methods of low molecular fluoropolymers
2.1 Copolymerization method
2.2 Oligomerization method
2.3 ITP method
2.4 Functional initiator method
2.5 Oxidative degradation method
3 Functionalization methods of low molecular fluoropolymers
3.1 Functional monomer method
3.2 Functional group transformation method
3.3 Functional monomer and group transformation method
4 Properties of low molecular fluoropolymers
4.1 Processing property
4.2 Physical property
5 Conclusion and outlook

Key words: low molecular fluoropolymers, preparation, functionalization, properties

中图分类号: 

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