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化学进展 2016, Vol. 28 Issue (5): 647-656 DOI: 10.7536/PC151110 前一篇   后一篇

• 综述与评论 •

石墨烯/纤维素复合材料的制备及应用

高玉荣1,2, 黄培1, 孙佩佩1, 吴敏1*, 黄勇1   

  1. 1. 中国科学院理化技术研究所 北京 100190;
    2. 中国科学院大学 北京 100049
  • 收稿日期:2015-11-01 修回日期:2016-01-01 出版日期:2016-05-15 发布日期:2016-03-25
  • 通讯作者: 吴敏 E-mail:wumin@mail.ipc.ac.cn.
  • 基金资助:
    国家自然科学基金项目(No.51472253,51172247,51373191)资助
下载PDF ( 3369 ) 引用
导出 被引次数 ( 4 | 3 )

Preparation and Application of Graphene/Cellulose Composites

Gao Yurong1,2, Huang Pei1, Sun Peipei1, Wu Min1*, Huang Yong1   

  1. 1. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China;
    2. University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2015-11-01 Revised:2016-01-01 Online:2016-05-15 Published:2016-03-25
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(No.51472253, 51172247, 51373191).
近年来,石墨烯/纤维素复合材料引起了研究者的广泛关注。该材料在透明导电柔性薄膜、电容器、载药、紫外线防护、传感器、吸附等领域有重要的应用价值。本文在收集、归类研究国内外研究者在石墨烯/纤维素复合材料制备方法、性能以及应用工作的基础上,对石墨烯和纤维素复合材料的混合技术、制备方法及应用进行了综述。
关键词： 纤维素, 石墨烯, 氧化石墨烯, 复合材料
Graphene is a one-atom-thick planar sheet of sp2-bonded carbon atoms densely packed together in a honeycomb hexagonal lattice. The exceptional structure endows graphene with excellent electrical, mechanical, thermal, and optical properties. Up to now, considerable efforts have been made to explore its application in varied areas, such as catalyst, battery, sensor and etc. Cellulose, one of the most abundant natural polymer on earth, is featured by non-toxicity, renewability, biodegradability and biocompatibility. The hydrophilicity and hydrophobicity, originated from the enriched O-H and C-H, respectively, have made cellulose an ideal candidate for the fabrication of graphene-based materials. So far, graphene/cellulose composites have shown great potential in the applications of transparent conductive flexible films, supercapacitors, drug delivery, UV-protection, sensors, absorbents and so on. In this review, we study the interaction between cellulose materials and graphene materials. Subsequently, the mixing technics, fabrication methods, and application of the graphene/cellulose composites are summarized. Finally, problems, such as dispersion of graphene in cellulose and production efficiency, hampering its up-scale application, have been pointed out.

Contents
1 Introduction
2 Interactions between graphene and cellulose
3 Mixing methods of graphene/cellulose composite
3.1 Solution mixing
3.2 Melting mixing
3.3 Others
4 Processing of graphene/cellulose composite
4.1 Regeneration of cellulose gel
4.2 Vacuum filtration
4.3 Solution coating
4.4 Dip and dry
4.5 Film transfer
4.6 Aerogel through freeze drying
5 Applications of graphene/cellulose composite
5.1 Thin film materials
5.2 Supercapacitors
5.3 Drug delivery
5.4 UV-protection
5.5 Sensors
5.6 Absorbents
5.7 Others
6 Conclusion

Key words: cellulose, graphene, graphene oxide, composite

中图分类号: 

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