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化学进展 2016, Vol. 28 Issue (4): 450-458 DOI: 10.7536/PC151026 前一篇   后一篇

• 综述与评论 •

催化剂的孔道限域效应

薛丽君, 张迪, 魏杰, 刘欣梅*   

  1. 中国石油大学(华东) 重质油国家重点实验室 中国石油催化重点实验室 青岛 266580
  • 收稿日期:2015-10-01 修回日期:2015-12-01 出版日期:2016-04-15 发布日期:2016-01-17
  • 通讯作者: 刘欣梅 E-mail:lxmei@upc.edu.cn
  • 基金资助:
    国家自然科学基金项目(No. 21376267)、山东省自然科学基金项目(No. 2013ZRE28069)和中央高校基本科研业务费专项资金(No. 14CX06106A)资助
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Pore Confinement Effects of Catalysts

Xue Lijun, Zhang Di, Wei Jie, Liu Xinmei*   

  1. State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, China National Petroleum Corporation, China University of Petroleum, Qingdao 266580, China
  • Received:2015-10-01 Revised:2015-12-01 Online:2016-04-15 Published:2016-01-17
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(No. 21376267), the Shandong Province Natural Science Foundation of China(No. 2013ZRE28069)and the Fundamental Research Funds for the Central Universities(No. 14CX06106A).
限域孔道可以调控催化剂的表面电子分布和几何结构,进而影响催化剂的活性、选择性和稳定性.本文结合理论计算和实验方法,从热力学、动力学、几何效应以及电子转移等角度出发,阐明了不同限域体系中催化剂活性组分和反应分子特性的差异,揭示了限域孔道对反应物种扩散、吸附和反应等过程的影响规律,以期为催化剂的微观结构设计和反应性能调控提供借鉴.
关键词： 催化剂, 孔道限域效应, 扩散, 吸附, 催化反应
The surface electronic distribution and geometric construction of catalysts can be regulated by confined pore canals, which will affect the activity, selectivity and stability of catalysts. Combined with theoretical calculations and experimental methods, from the perspectives of thermodynamics, kinetics, geometric effect and electron transfer, this review illustrates the differences of the active components of catalysts and the characteristics of reaction molecules in different confined systems, and reveals the influence of confined pore canals on the diffusion, adsorption and reaction of reaction species. It aims to provide a reference for the microstructure design and performance control of catalysts.

Contents
1 Introduction
2 Pore confinement effects on diffusion
3 Pore confinement effects on adsorption
4 Pore confinement effects on catalytic reaction
5 Conclusion

Key words: catalysts, pore confinement effects, diffusion, adsorption, catalytic reaction

中图分类号: 

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摘要

催化剂的孔道限域效应