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化学进展 2016, Vol. 28 Issue (1): 121-130 DOI: 10.7536/PC150745 前一篇   后一篇

• 综述与评论 •

水热炭的制备、性质及应用

吴艳姣, 李伟, 吴琼, 刘守新*   

  1. 东北林业大学材料科学与工程学院 哈尔滨 150040
  • 收稿日期:2015-07-01 修回日期:2015-09-01 出版日期:2016-01-15 发布日期:2015-12-21
  • 通讯作者: 刘守新 E-mail:liushouxin@126.com
  • 基金资助:
    林业公益性行业科研专项经费项目(No.201504605)、国家自然科学基金项目(No.31570567,31500467)、中央高校基本科研业务费专项资金项目(No.2572014EB01)和浙江省林业工程重中之重一级学科开放基金项目(No.2014lygcz017)资助
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Preparation, Properties and Applications of Hydrochar

Wu Yanjiao, Li Wei, Wu Qiong, Liu Shouxin*   

  1. Material Science and Engineering College, Northeast Forestry University, Harbin 150040, China
  • Received:2015-07-01 Revised:2015-09-01 Online:2016-01-15 Published:2015-12-21
  • Supported by:
    The work was supported by the Special Fund for Forest Scientific Research in the Public Welfare (No. 201504605), the National Natural Science Foundation of China (No. 31570567, 31500467),the Fundamental Research Funds for the Central Universities(No. 2572014EB01), and the Zhejiang Key Level 1 Discipline of Forestry Engineering (No. 2014lygcz017).
水热炭是一种以生物质或其组分为原料,以水为溶剂和反应介质,在150~375 ℃和自生压力下,经水热反应得到的以碳为主体,含氧官能团丰富,热值(HHV)高的黑色固体产物。水热炭的性质主要受原料种类、反应温度和时间的影响。水热炭在吸附、多孔炭制备、催化剂载体和清洁能源等领域展现出了良好的应用前景。本文综述了水热炭的制备、性质和形成机理,并对水热炭的应用进行了总结,对水热炭未来的发展方向进行了展望。
关键词： 水热炭, 制备, 表面化学性质, 机理, 应用
Hydrochar is a black carbonaceous solid which is derived from biomass via hydrothermal carbonization condition: using water as solvent and reaction medium, at the temperature of 150~375 ℃ and autogenously pressure. Rich oxygen-containing functional groups, together with high heat value (HHV) are the distinguished properties of hydrochar. Their properties are influenced by raw materials type, hydrothermal carbonization temperature and time. It has revealed a promising perspective in absorbent, preparation of porous carbon, catalyst carrier and clean energy. In this study, the production, properties and formation mechanism of hydrochar are summarized. Meanwhile, the applications of hydrochar are reviewed and the future development is prospected.

Contents
1 Introduction
2 Production of hydrochar
2.1 Influence of feedstock
2.2 Influence of hydrothermal temperature
3 Properties of hydrochar
3.1 Surface chemical properties
3.2 High heat value
3.3 Microcrystalline structure
3.4 Morphological characterization
4 Formation mechanism of hydrochar
5 Applications of hydrochar
5.1 Adsorption of heavy metal ion
5.2 Preparation of porous carbon
5.3 Solid acid catalyst
5.4 Clean energy
6 Conclusion

Key words: hydrochar, preparation, surface chemical properties, mechanism, applications

中图分类号: 

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摘要

水热炭的制备、性质及应用