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化学进展 2016, Vol. 28 Issue (1): 40-50 DOI: 10.7536/PC150740 前一篇   后一篇

• 综述与评论 •

二氧化钛在钙钛矿太阳电池中的应用

阙亚萍1, 翁坚1, 胡林华1*, 戴松元1,2*   

  1. 1. 中国科学院合肥物质科学研究院应用技术研究所 中国科学院新型薄膜太阳电池重点实验室 合肥 230031;
    2. 华北电力大学可再生能源学院 新型薄膜太阳电池北京市重点实验室 北京 102206
  • 收稿日期:2015-07-01 修回日期:2015-09-01 出版日期:2016-01-15 发布日期:2015-12-21
  • 通讯作者: 胡林华, 戴松元 E-mail:solarhu@sina.com;sydai@ipp.cas.cn
  • 基金资助:
    国家自然科学基金项目(No.21173228,U1205112,21173227)和国家高技术研究发展计划(863)项目(No.2015AA050602)资助
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Applications of Titanium Dioxide in Perovskite Solar Cells

Que Yaping1, Weng Jian1, Hu Linhua1*, Dai Songyuan1,2*   

  1. 1. Key Laboratory of Novel Thin-Film Solar Cells, Institute of Applied Technology, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, China;
    2. Beijing Key Laboratory of Novel Thin-Film Solar Cells, School of Renewable Energy, North China Electric Power University, Beijing 102206, China
  • Received:2015-07-01 Revised:2015-09-01 Online:2016-01-15 Published:2015-12-21
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21173228,U1205112,21173227) and the National High Technology Research and Development Program of China (No. 2015AA050602).
纳米TiO2由于具有合适的禁带宽度、良好的光电化学稳定性、制作工艺简单等特点,目前广泛应用于染料敏化、量子点和钙钛矿等太阳电池中。作为电池的重要组成部分之一,纳米TiO2晶体尺寸、颗粒大小和制备方法等明显影响电池的光伏性能,相关研究工作一直是染料敏化、量子点和钙钛矿等太阳电池方面的重点。本文综述了纳米TiO2作为致密层和骨架层在钙钛矿太阳电池中的应用研究进展,主要讨论了纳米TiO2的不同形貌、制备方法以及结构等对电池光电性能的影响,并针对纳米TiO2在后续对电池性能提升方面进行了展望。
关键词： 二氧化钛, 致密层, 骨架层, 钙钛矿太阳电池
TiO2 is widely used in photovoltaic field like dye-sensitized solar cells, quantum dot-sensitized solar cells and so on because of its proper forbidden band width, good optical and chemical stability, nontoxicity, corrosion resistance and simple manufacturing process etc. Recently, inorganic-organic hybrid perovskite solar cell has attracted great attention as a new class of photovoltaic devices and its rapid development has led the power conversion efficiency up to 20%. TiO2 nanomaterial appears to be a good candidate to be applied in it, which is usually used as compact layer or skeleton layer in perovskite solar cells. As an important part, its crystalline phase, particle size, morphology, preparation methods, film thickness and coverage have great influence on the performance of solar cells. This paper summarizes recent progress of titanium dioxide in the application of perovskite solar cells. We introduce the role TiO2 play in constructing perovskite solar cells and discuss different preparation methods (high/low temperature) and various optimization methods (modulation of structure, size, shape and interface interaction) of TiO2. What's more, we analyze the influence of these differences on the performance of perovskite solar cells. In the end, further optimization of TiO2 materials in the applications of perovskite solar cells is also prospected.

Contents
1 Introduction
2 Recent progress of TiO2 compact layer
2.1 Preparation methods of TiO2 compact layer
2.2 Interface optimization of TiO2 compact layer
2.3 The film thickness of TiO2 compact layer
3 Recent progress of TiO2 scaffold layer
3.1 Particle size, pore size and film thickness of TiO2 scaffold layer
3.2 Crystal phase and morphology of TiO2
3.3 Surface treatment of TiO2 scaffold layer
3.4 The influence of TiO2 on J-V hysteresis
4 Conclusion and prospects

Key words: titanium dioxide, compact layer, scaffold layer, perovskite solar cell

中图分类号: 

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