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化学进展 2015, Vol. 27 Issue (12): 1808-1814 DOI: 10.7536/PC150638 前一篇   后一篇

• 综述与评论 •

CO2化学吸收剂

方梦祥*, 周旭萍, 王涛, 骆仲泱   

  1. 浙江大学能源清洁利用国家重点实验室 杭州 310027
  • 收稿日期:2015-06-01 修回日期:2015-08-01 出版日期:2015-12-15 发布日期:2015-09-17
  • 通讯作者: 方梦祥 E-mail:mxfang@zju.edu.cn
  • 基金资助:
    国家自然科学基金项目(No.51076139,51276161),国际合作项目(No.2013DFR60140)和浙江省自然科学基金项目(No.LY13E060004)资助
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Solvent Development in CO2 Chemical Absorption

Fang Mengxiang*, Zhou Xuping, Wang Tao, Luo Zhongyang   

  1. State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China
  • Received:2015-06-01 Revised:2015-08-01 Online:2015-12-15 Published:2015-09-17
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 51076139,51276161), the International Cooperative Project (No. 2013DFR60140), and the National Natural Science Foundation of Zhejiang Province (No. LY13E060004).
化学吸收法是燃后CO2捕集的主要方法之一,本文介绍了化学吸收法脱除CO2的系统工艺及特点,综述了CO2吸收剂的研究现状,介绍了典型吸收剂:氨水吸收剂、氨基酸盐吸收剂、碳酸钾吸收剂的研究进展,以及新型吸收剂研究方向:混合胺吸收剂、相变吸收剂、离子液体吸收剂、纳米流体吸收剂,CO2开关型吸收剂和新型有机胺吸收剂,并分析比较了各种吸收剂的优缺点。分析表明混合胺和相变吸收剂节能潜力较大,较其他四种新型吸收剂更为成熟,因此具有一定的工业化潜力。
关键词： CO2, 化学吸收, 吸收剂
Chemical absorption is one of the most mature method for post combustion CO2 capture. The current paper gives an overview of the development of solvent for CO2 capture. In addition to ammines, ammonia solutions, amino acid salts, potassium carbonate solutions are typical solvents which have been widely investigated. Many novel solvents have been proposed, for example blended amines, phase change solvents, ionic liquid, nanofluids based absorbent, switchable solvents and designer amines. The advantages and disadvantages of the solvents are introduced and among them blended amine solutions and phase change solvents are the most promising novel solvents which have great potential in decrease energy consumption.

Contents
1 Introduction
2 Technical analysis of CO2 chemical absorption
2.1 System process of CO2 chemical absorption
2.2 Characteristics of CO2 chemical absorption
3 Solvent development
3.1 Typical solvents
3.2 Novel solvents
4 Conclusion and outlook

Key words: CO2, chemical absorption, solvents

中图分类号: 

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摘要

CO2化学吸收剂