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化学进展 2015, Vol. 27 Issue (12): 1764-1773 DOI: 10.7536/PC150621 前一篇   后一篇

• 综述与评论 •

受限空间下的烯烃聚合研究

王魁, 雷金化*, 聂赫然, 周光远*   

  1. 中国科学院长春应用化学研究所 生态高分子材料重点实验室 长春 130022
  • 收稿日期:2015-06-01 修回日期:2015-07-01 出版日期:2015-12-15 发布日期:2015-09-17
  • 通讯作者: 雷金化, 周光远 E-mail:jhlei@ciac.ac.cn;gyzhou@ciac.ac.cn
  • 基金资助:
    国家自然科学基金项目(No.51373163,21104073)资助
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Olefin Polymerization in Confined Space

Wang Kui, Lei Jinhua*, Nie Heran, Zhou Guangyuan*   

  1. Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  • Received:2015-06-01 Revised:2015-07-01 Online:2015-12-15 Published:2015-09-17
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 51373163,21104073).
近些年来,随着纳米技术的发展,出现了很多微纳米反应器,该反应器能够提供具有纳米尺寸的反应环境,使得在该环境下进行的反应受到纳米空间的影响,生成具有纳米效应或特殊结构的产物。在聚烯烃催化聚合中,也出现很多具有受限空间的微纳米反应器载体,这些载体不仅能够负载烯烃催化剂,还能为烯烃聚合反应提供受限空间环境。在纳米尺度效应的影响下,催化烯烃聚合进程发生变化,可以得到一些具有特殊结构与性能(比如高熔点、超高分子量、纤维状)的聚烯烃产物。本文总结现阶段受限空间下烯烃聚合研究的最新成果,主要根据聚合物的不同结构进行分类,分别介绍了受限空间对聚烯烃产物的形貌、反应动力学及活性、初级结构、二级结构和凝聚态结构及性能的影响,并对受限聚合研究的发展趋势进行了展望。
关键词： 受限空间, 烯烃聚合, 载体催化剂, 纳米尺度
With the development of nanotechnology in recent years, there are many micro- and nano-reactors. The micro- and nano-reactor could provide a nano-sized reaction environment, so that reaction occurred in that environment is influenced by nano-confined space. Finally the resulting product with special structure is obtained. There are also many micro- and nano-reactor carriers with confined space for olefin polymerization. The carriers play a double role in the polymerization not only being the catalyst's carrier but also providing a confined geometry in which the polymerization reaction can occur. With the effect of nano scale the process of olefin polymerization changes, so that some polyolefin products with special structure and properties (such as high melting point, high molecular weight, and fibrous) will be obtained. In this paper, we mainly focus on recent research on olefin polymerization in confined space, and classify them according to different types of polymer structure, and then the influence of confined space on the morphology of the polyolefin product, the polymerization kinetic and activity, the primary structure of the product, the secondary structure of the product, the condensed matter structure and the property of the product are relatively introduced. Finally, the researches on olefin polymerization in confined space are also prospected.

Contents
1 Introduction
2 The effect of polymerization in confined space on the morphology of product
3 The effect of polymerization in confined space on the polymerization kinetic and activity
4 The effect of polymerization in confined space on the primary structure of the product
5 The effect of polymerization in confined space on the secondary structure of the product
6 The effect of polymerization in confined space on the condensed matter structure and the property of the product
7 Conclusion

Key words: confined space, olefin polymerization, supported catalyst, nanoscale

中图分类号: 

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摘要

受限空间下的烯烃聚合研究