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化学进展 2015, Vol. 27 Issue (10): 1343-1355 DOI: 10.7536/PC150338 前一篇   后一篇

• 综述与评论 •

全钒氧化还原液流电池碳素类电极的活化

王刚1, 陈金伟1, 朱世富1, 张洁1, 刘效疆2, 王瑞林1*   

  1. 1. 四川大学材料科学与工程学院 成都 610065;
    2. 中国工程物理研究院电子工程研究所 绵阳 621900
  • 收稿日期:2015-03-01 修回日期:2015-04-01 出版日期:2015-10-15 发布日期:2015-09-10
  • 通讯作者: 王瑞林 E-mail:rl.wang@scu.edu.cn
  • 基金资助:
    国家自然科学基金项目(No.21306119),四川省科技支撑计划(No.2013FZ0034,2013JY0150,四川大学优秀青年学者基金(No.2013SCU04A23),东方电气集团有限公司项目(No.13H0844)和中物院超精细加工技术重点实验室开放基金(No.HG2012039,KF13007)资助
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Activation of Carbon Electrodes for All-Vanadium Redox Flow Battery

Wang Gang1, Chen Jinwei1, Zhu Shifu1, Zhang Jie1, Liu Xiaojiang2, Wang Ruilin1*   

  1. 1. College of Materials Science and Engineering, Sichuan University, Chengdu 610065, China;
    2. Institute of Electronics Engineering, China Academy of Engineering Physics, Mianyang 621900, China
  • Received:2015-03-01 Revised:2015-04-01 Online:2015-10-15 Published:2015-09-10
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No.21306119), the Provincial Natural Science Foundation of Sichuan (No.2013FZ0034, 2013JY0150), the Outstanding Young Scientist Foundation of Sichuan University (No.2013SCU04A23), the Financial Support from Dongfang Electric Corporation (No.13H0844), and the China Academy of Engineering Physics Foundation(LPMT,CAEP) (No. HG2012039, KF13007).
近年来,全钒氧化还原液流电池(VRFB)作为一种新型的储能电池备受关注,作为VRFB的核心材料,电极的活化一直都是研究的热点。碳素类材料,如碳毡和石墨毡,以其低成本和高性能被广泛用作钒电池电极。通过活化处理增加碳素类电极表面的含氧、含氮官能团或引入各种催化剂可以显著提高V(Ⅴ)/V(Ⅳ)和V(Ⅲ)/V(Ⅱ)电对氧化还原反应的电化学活性和可逆性,进而提高VRFB的总体性能,最终促进VRFB的商业化进程。本文综述了VRFB碳素类电极的氧化活化法、掺杂活化法和碳纳米催化剂活化法等几种常用活化方法的研究进展,并对VRFB碳素类电极的进一步研究和应用前景进行了展望。
关键词： 全钒氧化还原液流电池, 碳素类电极, 氧化, 掺杂, 碳纳米催化剂, 活化
In recent years, all-vanadium redox flow battery (VRFB) has been paid much attention as a new type of battery for energy storage. Researchers have been focusing much on activation of carbon electrodes used for the key material in VRFB. The carbon electrode, such as carbon felts and graphite felts, are widely used as electrode for VRFB due to their low cost and high performance. The electrochemical activation and reversibility towards V(Ⅴ)/V(Ⅳ) and V(Ⅲ)/V(Ⅱ) redox reactions can be significantly improved after increasing the oxygen and nitrogen functional groups on the surface of carbon electrodes or introducing all kinds of catalysts by activation treatment, which can improve the overall performance of VRFB and further accelerate its commercialization process. The research progress in various common activation methods including oxidation activation, doping activation and carbon nanocatalysts activation, are summarized in this paper. The further research and prospect on carbon electrodes in VRFB are also presented.

Contents
1 Introduction
2 Carbon electrodes
3 Active of carbon electrodes
3.1 Oxidation activation method
3.2 Doping activation method
3.3 Carbon nanocatalysts activation method
3.4 Other activation methods
4 Outlook

Key words: all-vanadium redox flow battery, carbon electrodes, oxidation, doping, carbon nanocatalysts, activation

中图分类号: 

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