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化学进展 2015, Vol. 27 Issue (9): 1302-1312 DOI: 10.7536/PC150162 前一篇   后一篇

• 综述与评论 •

硅纳米晶的制备及其在太阳电池中的应用研究

刘超1, 谭瑞琴1*, 曾俞衡2, 王维燕2, 黄金华2, 宋伟杰2   

  1. 1. 宁波大学信息科学与工程学院 宁波 315211;
    2. 中国科学院宁波材料技术与工程研究所 宁波 315201
  • 收稿日期:2015-01-01 修回日期:2015-05-01 出版日期:2015-09-15 发布日期:2015-06-24
  • 通讯作者: 谭瑞琴 E-mail:tanruiqin@nbu.edu.cn
  • 基金资助:
    国家自然科学基金项目(No. 21377063,61106096,61574145), 浙江省自然科学基金项目(No. LY15F040003), 宁波市自然科学基金项目(No. 2014A610036)和宁波大学王宽诚幸福基金资助
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Preparation of Silicon Nanocrystals and Their Applications in Solar Cells

Liu Chao1, Tan Ruiqin1*, Zeng Yuheng2, Wang Weiyan2, Huang Jinhua2, Song Weijie2   

  1. 1. Faculty of Electrical Engineering and Computer Science, Ningbo University, Ningbo 315211, China;
    2. Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
  • Received:2015-01-01 Revised:2015-05-01 Online:2015-09-15 Published:2015-06-24
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21377063, 61106096, 61574145), the Natural Science Foundation of Zhejiang Province (No. LY15F040003), the Natural Science Foundation of Ningbo (No. 2014A610036 ), and K. C. Wong Magna Fund in Ningbo University.
硅纳米晶由于量子限域效应的作用而产生了多种不同于体硅材料的新特性,如荧光效应显著、光学带隙可调等,因而在微电子、光伏、生物医学等领域受到极大的重视。本文介绍了分立的硅纳米晶颗粒和硅纳米晶薄膜的制备方法,并对比了不同方法制备硅纳米晶体的优缺点。着重介绍了硅纳米晶体在太阳电池中应用的几种方式,包括利用纯硅纳米晶薄膜制备太阳电池、硅纳米晶体与有机薄膜基质结合形成复合结构太阳电池、含有硅纳米晶颗粒的硅墨水在太阳电池中的应用等。
关键词： 硅纳米晶, 硅量子点, 制备, 太阳电池
Because of the quantum confinement effect, silicon nanocrystals exhibit some new features different from bulk silicon, such as enhanced photoluminescence and adjustable optical band gap, etc. Silicon nanocrystals have attracted much attention in the fields of microelectronics, photovoltaic, biomedicine and so on. In this paper, the different preparation methods of freestanding silicon nanocrystals and silicon nanocrystals embedded in thin films are reviewed, the advantages and disadvantages of different preparation methods are analyzed. Furthermore, the applications of silicon nanocrystals are focused on photovoltaic, including solar cells made up of pure silicon-nanocrystal films, organic solar cells combined with silicon nanocrystals, and silicon nanocrystals ink for solar cells.

Contents
1 Introduction
2 Synthesis of Si nanocrystals
2.1 Synthesis of freestanding Si nanocrystals
2.2 Synthesis of Si nanocrystals embedded in films
3 Applications of Si nanocrystals in solar cells
3.1 Si nanocrystal films as the emitter or optical absorb layer in solar cells
3.2 Organic solar cells combined with silicon nanocrystals
3.3 Silicon nanocrystals ink for solar cells
4 Conclusion

Key words: silicon nanocrystals, silicon quantum dot, preparation, solar cells

中图分类号: 

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