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化学进展 2015, Vol. 27 Issue (5): 503-510 DOI: 10.7536/PC150112 前一篇   后一篇

• 综述与评价 •

沸石分子筛的绿色合成路线

历阳1, 孙洪满1,2, 王有和*1,2, 许本静1, 阎子峰*1   

  1. 1. 中国石油大学重质油国家重点实验室 中国石油催化重点实验室 青岛 266580;
    2. 中国石油大学(华东)理学院 青岛 266580
  • 收稿日期:2015-01-01 修回日期:2015-01-01 出版日期:2015-05-15 发布日期:2015-03-16
  • 通讯作者: 王有和, 阎子峰 E-mail:yhewang@upc.edu.cn;zfyancat@upc.edu.cn
  • 基金资助:
    国家自然科学基金委员会-中国石油天然气集团公司石油化工联合基金项目(No. U1362202)和中国石油大学(华东)研究生创新工程项目(No.YCX2014037)资助
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Green Routes for Synthesis of Zeolites

Li Yang1, Sun Hongman1,2, Wang Youhe*1,2, Xu Benjing1, Yan Zifeng*1   

  1. 1. State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, CNPC, China University of Petroleum, Qingdao 266580, China;
    2. School of Science, China University of Petroleum(East China), Qingdao 266580, China
  • Received:2015-01-01 Revised:2015-01-01 Online:2015-05-15 Published:2015-03-16
  • Supported by:
    The work was supported by the Petrochemical Joint Funds of NSFC-CNPC (No. U1362202) and Postgraduate Innovation Project of China University of Petroleum (East China) (No. YCX2014037).
沸石分子筛因具有独特的孔道结构、较强的酸性和高的水热稳定性,在吸附分离、催化和离子交换等领域得到了广泛的应用.沸石分子筛的合成方法大多采用水热法,需要使用大量含硅铝的化工产品和有机模板剂,导致沸石分子筛的合成成本较高、效率较低,且环境污染较为严重,因此沸石分子筛高效绿色合成路线的研究具有重大意义.本文主要从沸石分子筛的合成原料绿色化、合成条件绿色化以及合成方法绿色化等三个方面综述了国内外沸石分子筛绿色合成路线的研究新进展,并提出现有沸石分子筛绿色合成路线存在的问题以及将来的发展方向.
关键词： 沸石分子筛, 天然矿物, 无胺法, 无溶剂法, 绿色合成路线
Zeolites have been widely used as adsorbents, heterogeneous catalysts and ion-exchange materials due to their unique pore structure, strong acidity and high hydrothermal stability. At present, most of zeolites are synthesized by hydrothermal method, involving the use of commercial silicon- and aluminum-containing reagents and organic templates, which leads to high cost, low efficiency and seriously environmental pollution. Therefore, the research of highly efficient and green routes for synthesis of zeolites is of great significance. Three aspects including the greenization of the raw materials, synthesis conditions and synthesis methods are reviewed in this paper. The existing problems and future direction of development are also put forward.

Contents
1 Introduction
2 The greenization of raw materials
2.1 Synthesis of zeolite from kaolin
2.2 Synthesis of zeolite from diatomite
3 The greenization of synthesis conditions
3.1 Directed method
3.2 Seed solution-assisted method
3.3 Crystal seed-directed method
4 The greenization of synthesis methods
5 Conclusion

Key words: zeolite, natural mineral, organotemplate-free, solvent-free, green routes

中图分类号: 

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[1] 王聪,刘秀凤,崔瑞利,张宝泉. 沸石分子筛膜缺陷的形成及修复*[J]. 化学进展, 2008, 20(12): 1860-1867.
[2] 翟尚儒,魏莉,杨东江,吴东,孙予罕. 硅铝基微孔/介孔复合分子筛的制备与应用*[J]. 化学进展, 2006, 18(10): 1330-1337.
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摘要

沸石分子筛的绿色合成路线