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化学进展 2015, Vol. 27 Issue (6): 666-674 DOI: 10.7536/PC150103 前一篇   后一篇

• 超分子化学专辑 •

铁咔咯配合物在有机合成中的催化应用

邹怀波1, 汪华华1, 梅光泉2, 刘海洋*1, 张启光*3   

  1. 1. 华南理工大学化学系 广州 510640;
    2. 宜春学院 江西省高校应用化学与化学生物学重点实验室 宜春 336000;
    3. Department of Chemistry, Michigan State University, E. Lansing, MI 48824, USA
  • 收稿日期:2015-01-01 修回日期:2015-04-01 出版日期:2015-06-15 发布日期:2015-04-08
  • 通讯作者: 刘海洋, 张启光 E-mail:chhyliu@scut.edu.cn;changc@msu.edu
  • 基金资助:
    国家自然科学基金项目(No.21171057,21371059,21261024)资助
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Catalytic Application of Iron Corrole Complexes in Organic Synthesis

Zou Huaibo1, Wang Huahua1, Mei Guangquan2, Liu Haiyang*1, Chang Chi-Kwong*3   

  1. 1. Department of Chemistry, South China University of Technology, Guangzhou 510640, China;
    2. Key Laboratory of Jiangxi University for Applied Chemistry and Chemical Biology, Yichun University, Yichun 336000, China;
    3. Department of Chemistry, Michigan State University, E. Lansing, MI 48824, USA
  • Received:2015-01-01 Revised:2015-04-01 Online:2015-06-15 Published:2015-04-08
  • Contact: 10.7536/PC150103 E-mail:chhyliu@scut.edu.cn;changc@msu.edu
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21171057, 21371059, 21261024).
铁咔咯配合物的制备及其催化活性研究是当今卟啉化学的前沿课题之一。本文综述了近年来铁咔咯配合物在有机合成中的催化应用,重点归纳评述了它们在氧化反应,烯烃的环丙烷化、氮杂环丙烷化,N—H键、S—H键和C—H键的插入反应, [4+2]环加成反应及共聚反应中的催化活性,分析了目前铁咔咯配合物在催化研究方面存在的问题并展望了其发展的方向。
关键词： 咔咯, 铁配合物, 催化, 有机合成
Study on the preparation and catalytic activities of iron corrole has become one of the hot topics of porphyrin chemistry. In this paper, the recent progress about catalytic application of iron corrole in organic synthesis has been reviewed, with an emphasis on the oxidation, cyclopropanation and aziridination of olefin, insertion reactions involving N—H, S—H and C—H bonds, [4+2] cycloaddition as well as copolymerization of epoxides with carbon dioxide. The problems of iron corroles in catalysis and several directions have also been addressed.

Contents
1 Introduction
2 Application of iron-corrole complexes in organic synthesis
2.1 Catalytic oxidation
2.2 Catalytic cyclopropanation
2.3 Catalytic aziridination
2.4 Catalytic insertion reactions involving N—H, S—H and C—H bonds
2.5 Catalytic cycloaddition
2.6 Catalytic copolymerization
3 Conclusion

Key words: corrole, iron complexes, catalysis, organic synthesis

中图分类号: 

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