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化学进展 2015, Vol. 27 Issue (7): 861-869 DOI: 10.7536/PC141239 前一篇   后一篇

• 综述与评论 •

纳米晶纤维素手性向列型液晶相结构的形成、调控及应用

代林林1, 李伟1,2, 曹军2, 李坚1, 刘守新*1   

  1. 1. 东北林业大学材料科学与工程学院 哈尔滨 150040;
    2. 东北林业大学机电工程学院 哈尔滨 150040
  • 收稿日期:2014-12-01 修回日期:2015-02-01 出版日期:2015-07-15 发布日期:2015-06-15
  • 通讯作者: 刘守新 E-mail:liushouxin@126.com
  • 基金资助:
    国家自然科学基金项目(No. 31170545),中央高校基本科研业务费专项资金项目(No. 2572014EB01)和中国博士后科学基金项目(No. 2014M561313)资助
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Formation, Tuning and Application of Chiral Nematic Liquid Crystal Phase Based on Nanocrystalline Cellulose

Dai Linlin1, Li Wei1,2, Cao Jun2, Li Jian1, Liu Shouxin*1   

  1. 1. College of Material Science and Engineering, Northeast Forestry University, Harbin 150040, China;
    2. College of Mechanical and Electrical Engineering, Northeast Forestry University, Harbin 150040, China
  • Received:2014-12-01 Revised:2015-02-01 Online:2015-07-15 Published:2015-06-15
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 31170545), the Fundamental Research Funds for the Central Universities (No. 2572014EB01), and the China Postdoctoral Science Foundation (No. 2014M561313).
手性材料作为一种新型功能材料,尤其是其特殊的光学性能以及在传感器、对映体分离领域的潜在应用,已经引起众多科学研究者的广泛关注。纳米晶纤维素(NCC)基手性材料以其丰富的来源、简单的合成工艺、独特的光学性质以及良好的稳定性等成为当前手性材料研究的热点。本文综述了NCC及其手性向列型液晶相的形成机制,重点介绍了NCC手性结构的调控方法,包括NCC性质、环境条件以及添加剂对其手性结构的影响。最后,总结了近几年NCC手性结构在光电材料和模板剂方面的应用研究进展。
关键词： 纳米晶纤维素, 手性向列, 自组装, 液晶, 光电材料
Chiral nematic liquid crystals, which consist of mesogens organized into a long-range helical assembly, exhibit unique properties, such as the selective reflection of circularly polarized light. The incorporation of chiral nematic organization into solid-state materials could give rise to novel properties. Chiral assembled materials have received increasing attention in many research areas as new functional composite materials, especially focusing on their potential application in sensors and enantiomeric resolution. Nanocrystalline cellulose (NCC) is a kind of rod-like nanomaterial obtained from inexpensive renewable biomass, which organizes into a chiral nematic liquid crystal phase via self-assembly in certain circumstance. Taking advantage of the chiral nematic order and nanoscale of the NCC templates, new functional materials can be prepared. Chiral assembled materials based on NCC represent a major branch of future research because of their abundance, simple synthesis and other novel properties. In this paper, the formation, tuning and application of NCC chiral nematic structure are reviewed, especially for the tuning method which included the effect of NCC properties, circumstance, additives. Recent efforts to use NCC chiral nematic structure for application in optical and electronic materials and template are also summarized. The examples covered in this account demonstrate that there is a rich diversity of composite materials accessible using NCC templating.

Contents
1 Introduction
2 Formation and characterization of NCC chiral nematic liquid crystal phase
2.1 Formation of NCC chiral nematic liquid crystal phase
2.2 Characterization of NCC chiral nematic liquid crystal phase
3 Tuning of NCC chiral nematic liquid crystal phase
3.1 NCC properties
3.2 Ion strength
3.3 Sonication
3.4 Temperature
3.5 Additives
4 Application of NCC chiral nematic liquid crystal phase
4.1 Optical and electronic materials
4.2 Chiral carbon materials
4.3 Chiral inorganic materials
4.4 Chiral organic materials
5 Conclusion

Key words: nanocrystalline cellulose, chiral nematic, self-assembly, liquid crystal, optical and electronic materials

中图分类号: 

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