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化学进展 2015, Vol. 27 Issue (7): 935-944 DOI: 10.7536/PC141215 前一篇   后一篇

• 综述与评论 •

石墨烯基氧还原催化剂在金属空气电池中的应用

苗鹤*, 薛业建, 周旭峰, 刘兆平*   

  1. 中国科学院宁波材料技术与工程研究所 动力锂离子电池工程实验室 宁波 315201
  • 收稿日期:2014-12-01 修回日期:2015-03-01 出版日期:2015-07-15 发布日期:2015-06-15
  • 通讯作者: 苗鹤, 刘兆平 E-mail:miaohe@nimte.ac.cn;liuzp@nimte.ac.cn
  • 基金资助:
    国家自然科学基金项目(No.21371176, 21103212)资助
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导出 被引次数 ( 8 | 3 )

Graphene-Based Oxygen Reduction Reaction Catalysts for Metal Air Batteries

Miao He*, Xue Yejian, Zhou Xufeng, Liu Zhaoping*   

  1. Advanced Li-ion Battery Engineering Lab, Ningbo Institute of Industrial Technology, Chinese Academy of Sciences, Ningbo 315201, China
  • Received:2014-12-01 Revised:2015-03-01 Online:2015-07-15 Published:2015-06-15
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No.21371176, 21103212).
随着金属空气电池技术的不断发展,氧还原催化剂成为限制其动力化的最主要瓶颈之一。近几年来,石墨烯基氧还原催化剂(GORRC)由于优异的氧还原催化活性而备受关注。本文结合石墨烯基氧还原催化剂的研究现状,将其分为三类:石墨烯作氧还原催化剂载体,氮掺杂石墨烯作为氧还原催化剂,以及氮掺杂石墨烯与其他催化剂形成的复合催化体系,并对这三种石墨烯基氧还原催化剂进行了详细的综述。石墨烯作为一种优良的催化剂载体,能够显著降低活性物质负载量,提高氧还原催化剂的催化活性和长期稳定性。氮掺杂石墨烯显示了优良的氧还原催化性能。氮掺杂石墨烯与其他催化剂复合后,由于两者之间的相互作用,可得到性能更为优异的氧还原催化剂。最后,本文还对石墨烯基氧还原催化剂及其在金属空气电池中的研究前景和发展方向进行了展望,指出了将来的研究重点。
关键词： 石墨烯, 金属空气电池, 氧还原反应, 催化剂
In the past few years, the metal air batteries developed fast due to their remarkably high theoretical energy output. So far, the oxygen reduction reaction catalysts still have been the bottleneck for high power application of metal air batteries because of their sluggish kinetics. Recently, the graphene-based oxygen reduction reaction catalysts (GORRC) with high catalytic activity have been intensively reported. In this review, we focus on the recent progress and current situation of GORRC, and divide them into three categories, graphene as catalyst support, nitrogen doped graphene as the catalyst, and hybrids of nitrogen doped graphene and other catalysts as the catalyst. As an outstanding catalyst support, graphene can not only decrease the application amount of active components but also improve their catalytic activity and long-term stability. After doped by nitrogen, the graphene catalysts exhibit enhanced catalytic activity for the oxygen reduction reaction. In addition, the excellent catalysts can be obtained as the nitrogen doped graphene and other type of catalysts are hybridized. The catalytic activity and long-term stability of the hybrids are even better than that of the commercial Pt/C catalyst. Furthermore, the remarks on the challenges and perspectives of research directions are proposed for further development of GORRC which can be used in the metal air batteries.

Contents
1 Introduction
2 Graphene as catalyst support
2.1 Noble metal supported by graphene
2.2 Transition metal oxide supported by graphene
3 N-doped graphene as catalyst
4 Hybrids of N-doped graphene and other catalysts
4.1 Hybrids of N-doped graphene and noble metal
4.2 Hybrids of N-doped graphene and transition metal oxide
4.3 Hybrids of N-doped graphene and N-doped carbon nanotube
5 Conclusion and outlook

Key words: graphene, metal air battery, oxygen reduction reaction, catalyst

中图分类号: 

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