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化学进展 2015, Vol. 27 Issue (5): 511-521 DOI: 10.7536/PC141137 前一篇   后一篇

• 综述与评价 •

TM2+: Ⅱ-Ⅵ族中红外激光材料

陈媛芝1,2, 张乐*1,2, 黄存新3, 章健*1,2, 唐定远1,2, 沈德元1,2   

  1. 1. 江苏师范大学物理与电子工程学院 徐州 221116;
    2. 江苏师范大学江苏省先进激光材料与器件重点实验室 徐州 221116;
    3. 北京中材人工晶体研究院有限公司 北京100018
  • 收稿日期:2014-11-01 修回日期:2015-01-01 出版日期:2015-05-15 发布日期:2015-03-16
  • 通讯作者: 张乐, 章健 E-mail:jzhang@jsnu.edu.cn;njutzl@163.com
  • 基金资助:
    国家自然科学基金项目(No. 51402133, 51302115, 61405081)和江苏高校优势学科建设工程(PAPD)项目资助

TM2+:Ⅱ-Ⅵ Mid-Infrared Materials

Chen Yuanzhi1,2, Zhang Le*1,2, Huang Cunxin3, Zhang Jian*1,2, Tang Dingyuan1,2, Shen Deyuan1,2   

  1. 1. School of Physics Electronic Engineering, Jiangsu Normal University, Xuzhou 221116, China;
    2. Jiangsu Key Laboratory of Advanced Laser Materials and Devices, Jiangsu Normal University, Xuzhou 221116, China;
    3. Beijing Sinoma Synthetic Crystal Co. Ltd., Beijing 100018, China
  • Received:2014-11-01 Revised:2015-01-01 Online:2015-05-15 Published:2015-03-16
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 51402133, 51302115, 61405081) and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).
TM2+:Ⅱ-Ⅵ族化合物以其可调谐范围宽、激发态吸收小、吸收和发射截面大以及室温下量子效率高等优点已成为目前最具发展潜力的中红外激光材料.本文回顾了近年来TM2+:Ⅱ-Ⅵ族中红外激光材料在国内外的发展现状,分别从TM2+:Ⅱ-Ⅵ族材料在激光器件上的应用以及该材料的制备方法两方面进行综述.在对该材料结构和分类进行介绍的基础上,对典型TM2+:Ⅱ-Ⅵ族中红外激光材料的激光性能进行了详细概述,系统列举了此类中红外激光单晶和多晶材料的制备方法,指出了该领域目前存在的问题,并对其发展前景及研究趋势做了展望.
TM2+ :Ⅱ-Ⅵ compounds have become the most potential materials used for infrared laser due to the advantage of wide tunable range, small excited state absorption, high absorption and emission cross section and high quantum efficiency at room temperature. The research progress of TM2+:Ⅱ-Ⅵ laser materials are retrospect in this paper. Both the applications of TM2+:Ⅱ-Ⅵ materials in laser devices and their preparation methods are reviewed, respectively. The laser performance of typical TM2+:Ⅱ-Ⅵ mid-infrared materials are summarized in detail, and the preparation methods for monocrystalline and polycrystalline of these materials are listed systematically. At last, the existing problems in this field are pointed out, and the development prospects and research trends are prospected.

Contents
1 Introduction
2 The structure and species of TM2+:Ⅱ-Ⅵ compounds
3 The laser properties of TM2+:Ⅱ-Ⅵ materials
3.1 Cr2+:ZnSe
3.2 Cr2+:ZnS
3.3 Fe2+:Ⅱ-Ⅵ materials
4 Preparation method of TM2+:Ⅱ-Ⅵ material
4.1 Preparation method of TM2+:Ⅱ-Ⅵ single crystal
4.2 Preparation method of TM2+:Ⅱ-Ⅵ poly-crystalline and ceramic materials
5 Conclusion

中图分类号: 

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摘要

TM2+: Ⅱ-Ⅵ族中红外激光材料