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化学进展 2015, Vol. 27 Issue (2/3): 297-309 DOI: 10.7536/PC140932 前一篇   后一篇

所属专题： 锂离子电池

• 综述与评论 •

锂离子电池铌基氧化物负极材料

娄帅锋1, 程新群1, 马玉林1, 杜春雨1, 高云智1, 尹鸽平*1,2   

  1. 1. 哈尔滨工业大学化工学院特种化学电源研究所 哈尔滨 150001;
    2. 哈尔滨工业大学城市水资源与水环境国家重点实验室 哈尔滨 150001
  • 收稿日期:2014-09-01 修回日期:2014-11-01 出版日期:2015-03-15 发布日期:2014-12-22
  • 通讯作者: 尹鸽平 E-mail:yingphit@hit.edu.cn
  • 基金资助:

    国家自然科学基金项目(No.51472065)资助

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Nb-Based Oxides as Anode Materials for Lithium Ion Batteries

Lou Shuaifeng1, Cheng Xinqun1, Ma Yulin1, Du Chunyu1, Gao Yunzhi1, Yin Geping*1,2   

  1. 1. Institute of Advanced Power Sources, School of Chemical Engineering & Technology, Harbin Institute of Technology, Harbin 150001, China;
    2. State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150001, China
  • Received:2014-09-01 Revised:2014-11-01 Online:2015-03-15 Published:2014-12-22
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No. 51472065).

锂离子电池负极材料钛酸锂由于其高功率和优异的循环性能得到了广泛的研究,但是较低的比容量(175 mAh/g)限制了其应用前景。与钛酸锂相比,铌基氧化物具有相似的嵌脱锂电位和更高的比容量,也展现出良好的倍率性能和循环性能,有望成为新型功率型负极材料。本文综述了多种铌基复合金属氧化物(Nb2O5,TiNb2O7,LiNb3O8等)的晶体结构、电化学性能和嵌脱锂机理,讨论了材料的组成、形貌和制备工艺等对其嵌脱锂性能的影响,并概述其作用机制。此外,本文还归纳总结了铌基材料嵌脱锂行为的共性,并比较了它们与钛酸锂的异同,对其作为高功率锂离子电池负极材料的研究趋势和发展前景进行了展望。

关键词： 锂离子电池, 负极材料, 铌基氧化物, 嵌脱锂机理, 电化学性能

Li4Ti5O12 as anode materials for lithium ion batteries has been widely studied because of its excellent rate performance and cycle performance, but the low specific capacity (175 mAh/g) limits its application in the future. Compared with Li4Ti5O12, niobium based oxides have similar lithium ion insertion/extraction potential and higher specific capacity. In addition,they also have good rate performance and promising to be new anode materials with high power performance, that have got increasing researchers' attention in recent years. In this paper,the crystal structure, electrochemical performance and lithium ion insertion/extraction mechanism of various niobium based oxides materials (Nb2O5, TiNb2O7, LiNb3O8, etc.) are reviewed. The effects on lithium ion transfer and storage performance originate from component, particle morphology and preparation technology are discussed. Meanwhile, the influencing mechanism is also summarized. In addition, the generality in electrochemical lithium insertion and extraction behavior of niobium based oxides materials, the differences and similarities compared with Li4Ti5O12 are summarized the tendency and prospect of them as anode materials for high power lithium ion batteries in the end are also discussed.

Contents
1 Introduction
2 Research status of Nb-based oxides anode materials for lithium ion battery
2.1 Niobium oxides
2.2 Titanium niobium oxides
2.3 Lithium niobium oxides
2.4 Potassium niobium oxides
2.5 Vanadium niobium oxides
2.6 Other niobium based oxides
3 Understand of intercalation and deintercalation of lithium ion for niobium based oxide
4 Summary

Key words: lithium ion batteries, anode materials, Nb-based materials, mechanism of lithium insertion and extraction, electrochemical performance

中图分类号: 

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锂离子电池铌基氧化物负极材料